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MSDS Material Safety Data Sheet
CAS

7758-29-4
68551-12-2
497-19-8
141-43-5
10043-35-3
9014-01-1

File Name: gfs_com---599741.asp
     Material Safety Data Sheet
FORMULA 1

Section 1. Chemical product and company identification
: FORMULA 1
Trade name
: Laundry detergent
Product use
: Ecolab Inc. Institutional Division
Supplier
370 N. Wabasha Street
St. Paul, MN 55102
1-800-352-5326
: 905160
Code
: 29-April-2005
Date of issue
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)

Section 2. Composition, Information on Ingredients
CAS number % by weight
Name
triphosphoric acid, pentasodium salt 7758-29-4 25
alcohols, c12-16, ethoxylated 68551-12-2 20 - 50
sodium carbonate 497-19-8 5 - 20
2-aminoethanol 141-43-5 5 - 20
boric acid 10043-35-3 1-5
subtilisin 9014-01-1 <1

Section 3. Hazards identification
Physical state : Liquid. (slurry)
Emergency : Warning!
overview
Causes severe eye and skin irritation. Untreated contact may cause chemical burns.
CAUSES RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
MAY BE HARMFUL IF SWALLOWED.
Do not ingest. Do not get in eyes, on skin or clothing. Do not breathe vapor or mist. Keep
container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Potential acute health effects
Eyes : Severely irritating to the eyes. Untreated contact may cause chemical burns.
Skin : Severely irritating to the skin. Untreated contact may cause severe irritation or chemical
burns.
: Irritating to respiratory system. May cause sensitization by inhalation.
Inhalation
: Harmful if swallowed. May cause burns to mouth, throat and stomach.
Ingestion
See toxicological Information (section 11)

Section 4. First aid measures
Eye contact : In case of contact, immediately flush eyes with cool running water. Remove contact lenses and
continue flushing with plenty of water for at least 15 minutes. Get medical attention
immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
Skin contact
removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
Ingestion : Rinse mouth; then drink one or two large glasses of water. Do not induce vomiting. Never give
anything by mouth to an unconscious person. Get medical attention immediately.
Page: 2/4
FORMULA 1


Section 5. Fire fighting measures
: > 100掳C
Flash point
Product does not support combustion.
: Use an extinguishing agent suitable for surrounding fires.
Fire fighting media and
instructions
Dike area of fire to prevent product run-off.
No specific hazard.
Special protective equipment : Fire fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full facepiece operated in positive pressure
for fire-fighters
mode.

Section 6. Accidental release measures
Personal : Ventilate area of leak or spill. Do not touch damaged containers or spilled material unless
wearing appropriate protective equipment (Section 8). Stop leak if without risk. Prevent entry
precautions
into sewers, water courses, basements or confined areas.
Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
precautions
Methods for : If emergency personnel are unavailable, contain spilled material. For small spills add
absorbent (soil may be used in the absence of other suitable materials) scoop up material and
cleaning up
place in a sealed, liquid-proof container for disposal. For large spills dike spilled material or
otherwise contain material to ensure runoff does not reach a waterway. Place spilled material
in an appropriate container for disposal.--

Section 7. Handling and storage
Handling : Do not ingest. Do not get in eyes, on skin or on clothing. Keep container closed. Use only with
adequate ventilation. Do not breathe vapor or mist. Wash thoroughly after handling.
Storage : Keep out of the reach of children. Keep container tightly closed. Keep container in a cool, well-
ventilated area.
Store between 40 and 0掳C

Section 8. Exposure Controls, Personal Protection
Engineering : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective occupational exposure limits. When working with conentrate
controls
have eyewash available.
Personal protection
Eyes : Use Chemical splash goggles.
Hands : Use chemical resistant, impervious gloves.
Skin : No special protective clothing is required.
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
Name Exposure limits
ACGIH TLV (United States, 1/2004).
2-aminoethanol
STEL: 15 mg/m 3 15 minute(s). Form: All forms
STEL: 6 ppm 15 minute(s). Form: All forms
TWA: 7.5 mg/m 3 8 hour(s). Form: All forms
TWA: 3 ppm 8 hour(s). Form: All forms
OSHA PEL (United States, 8/1997).
TWA: 6 mg/m 3 8 hour(s). Form: All forms
TWA: 3 ppm 8 hour(s). Form: All forms
NIOSH REL (United States, 12/2001).
STEL: 15 mg/m 3 15 minute(s). Form: All forms
STEL: 6 ppm 15 minute(s). Form: All forms
TWA: 8 mg/m 3 10 hour(s). Form: All forms
TWA: 3 ppm 10 hour(s). Form: All forms
Page: 3/4
FORMULA 1

Section 9. Physical and chemical properties
: Liquid. (slurry)
Physical state
: Tan. (Light.)
Color
: Fragrance like.
Odor
: 10.5 (100%)
pH
: >100 掳C
Boiling/condensation
point
Specific gravity : 1.4 (Water = 1)
: Partially dispersed in cold water, hot water.
Dispersion properties
: Partially soluble in cold water, hot water.
Solubility

Section 10. Stability and reactivity
: The product is stable.
Stability
: Reactive with metals, acids.
Reactivity
Slightly reactive to reactive with organic materials.

Section 11. Toxicological information
Potential acute health effects
: Severely irritating to the eyes. Untreated contact may cause chemical burns.
Eyes
: Severely irritating to the skin. Untreated contact may cause severe irritation or chemical
Skin
burns.
: Irritating to respiratory system. May cause sensitization by inhalation.
Inhalation
: Harmful if swallowed. May cause burns to mouth, throat and stomach.
Ingestion
Potential chronic health effects
: Contains material which causes damage to the following organs: upper respiratory tract,
Chronic effects on
skin, central nervous system (CNS), eye, lens or cornea.
humans


Section 12. Ecological information
: These products are carbon oxides (CO, CO 2) and water, nitrogen oxides (NO, NO 2
Products of degradation
...), phosphates. Some metallic oxides.

Section 13. Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Consult your local or regional authorities.

Section 14. Transport information
Regulatory UN number Proper shipping name Class Packing Additional information
information
group
Limited quantity
DOT UN1759 Corrosive solids, n.o.s. 8 III
Yes.
(Ethanolamine)
Classification


Special provisions
128, IB8, IP3

APPLIES ONLY DURING ROAD TRANSPORT
Any variation of the shipping description based on the packaging is not addressed.
Page: 4/4
FORMULA 1


Section 15. Regulatory information
HCS Classification : Corrosive material
Sensitizing material
Target organ effects
U.S. Federal regulations : SARA 302/304/311/312 extremely hazardous substances: None.
SARA 302/304 emergency planning and notification: None.
TSCA 8(b) inventory : All materials are listed or exempt.
: No products were found.
California prop. 65

Section 16. Other information
Hazardous Material * 2
: Health
Information System (U.S.A.)
0
Fire hazard
0
Reactivity
B
Personal
protection
Date of issue : 29-April-2005.
Responsible name : Regulatory Affairs
Date of previous issue : No Previous Validation.
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product
in the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.

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