Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 467855
NAME: COPPER(II) NITRATE HEMIPENTAHYDRATE,
REAGENTPLUS, 99.99+%
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 19004-19-4
MF: CUN2O6
SYNONYMS
COPPER DINITRATE * COPPER (II) NITRATE * COPPER(2+) NITRATE *
CUPRIC
DINITRATE * CUPRIC NITRATE *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
OXIDIZING
CORROSIVE
CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
CAUSES BURNS.
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF
SWALLOWED.
TARGET ORGAN(S):
BLOOD
KIDNEYS
KEEP AWAY FROM COMBUSTIBLE MATERIAL.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY
OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED
CLOTHING AND SHOES.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE
EYELIDS
WITH FINGERS.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS
CONSCIOUS.
CALL A PHYSICIAN IMMEDIATELY.
REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE
CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
OXIDIZER.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
MAY ACCELERATE COMBUSTION.
CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND
HEAVY
RUBBER GLOVES.
USE NONSPARKING TOOLS.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-
RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
USE ONLY IN A CHEMICAL FUME HOOD.
FACESHIELD (8-INCH MINIMUM).
SAFETY SHOWER AND EYE BATH.
DO NOT BREATHE DUST.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
WASH THOROUGHLY AFTER HANDLING.
KEEP TIGHTLY CLOSED.
DO NOT STORE NEAR, NOR ALLOW CONTACT WITH, CLOTHING AND
OTHER
COMBUSTIBLE MATERIAL.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
PHYSICAL PROPERTIES
MELTING POINT: 114.5 C
SPECIFIC GRAVITY: 2.320
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
STABILITY
STABLE.
INCOMPATIBILITIES
REDUCING AGENTS
ORGANIC MATERIALS
FINELY POWDERED METALS
HEAT
MOISTURE
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
NITROGEN OXIDES
HAZARDOUS POLYMERIZATION
WILL NOT OCCUR.
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS
MEMBRANES
AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY RESULT IN SPASM, INFLAMMATION AND EDEMA OF
THE
LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY
EDEMA.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION,
COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA
AND
VOMITING.
TARGET ORGAN(S):
BLOOD
KIDNEYS
LIVER
CENTRAL NERVOUS SYSTEM
VASCULAR SYSTEM
ADDITIONAL INFORMATION
CHRONIC COPPER POISONING IS TYPIFIED BY HEPATIC CIRRHOSIS,
BRAIN
DAMAGE AND DEMYELINATION, KIDNEY DEFECTS, AND COPPER
DEPOSITION IN THE
CORNEA AS EXEMPLIFIED BY HUMANS WITH WILSON'S DISEASE. IT HAS
ALSO
BEEN REPORTED THAT COPPER POISONING HAS LEAD TO HEMOLYTIC
ANEMIA AND
ACCELERATES ARTERIOSCLEROSIS.
RTECS #: QU7400000
NITRIC ACID, COPPER(2+) SALT
IRRITATION DATA
SKN-RBT 500 MG SEV FCTOD7 20,563,1982
EYE-RBT 100 MG SEV FCTOD7 20,573,1982
EYE-RBT 100 MG/4S RINSE SEV FCTOD7 20,573,1982
TOXICITY DATA
ORL-RAT LD50:794 MG/KG INJPD2 23,153,1991
IPR-RAT LD50:20 MG/KG INJPD2 23,153,1991
IVN-RAT LD50:14700 UG/KG INJPD2 23,153,1991
ORL-MUS LD50:430 MG/KG INJPD2 23,153,1991
IPR-MUS LD50:17100 UG/KG INJPD2 23,153,1991
IVN-MUS LD50:23300 UG/KG INJPD2 23,153,1991
TARGET ORGAN DATA
BEHAVIORAL (SOMNOLENCE)
BEHAVIORAL (CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL
SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO
DISPOSE OF
THIS MATERIAL.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL
REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
CAUTION: SUBSTANCE NOT YET FULLY TESTED.
OXIDIZING
CORROSIVE
R8
CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R 34
CAUSES BURNS.
R 20/21/22
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF
SWALLOWED.
S 17
KEEP AWAY FROM COMBUSTIBLE MATERIAL.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY
OF
WATER AND SEEK MEDICAL ADVICE.
S 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-
REGISTRATION
FEREAC 54,7740,1989
OEL-ARAB REPUBLIC OF EGYPT:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-AUSTRALIA:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-AUSTRALIA:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-BELGIUM:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-BELGIUM:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-DENMARK:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-DENMARK:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-FINLAND:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-FINLAND:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-FRANCE:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-FRANCE:TWA 1 MG(CU)/M3;STEL 2 MG(CU)/M3 (DUST) JAN 1993
OEL-GERMANY:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-GERMANY:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-HUNGARY:TWA 0.2 MG(CU)/M3;STEL 0.4 MG(CU)/M3 (DUST) JAN 1993
OEL-INDIA:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-THE NETHERLANDS:TWA 02 MG(CU)/M3 (FUME) JAN 1993
OEL-THE NETHERLANDS:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-THE PHILIPPINES:TWA 1.0 MG(CU)/M3 (FUME) JAN 1993
OEL-POLAND:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-RUSSIA:STEL 0.5 PPM (1 MG(CU)/M3) (DUST) JAN 1993
OEL-SWEDEN:TWA 0.2 MG(CU)/M3 (RESP. DUST) JAN 1993
OEL-SWEDEN:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-SWEDEN:TWA 1 MG(CU)/M3 (TOTAL DUST) JAN 1993
OEL-SWITZERLAND:TWA 0.1 MG(CU)/M3;STEL 0.2 MG(CU)/M3 (FUME) JAN
1993
OEL-SWITZERLAND:TWA 1 MG(CU)/M3;STEL 1 MG(CU)/M3 JAN 1993
OEL-THAILAND:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-THAILAND:TWA 1 MG(CU)/M3 JAN 1993
OEL-UNITED KINGDOM:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-UNITED KINGDOM:TWA 1 MG(CU)/M3 JAN 1993
NOHS 1974: HZD 84335; NIS 6; TNF 97; NOS 8; TNE 738
NOES 1983: HZD 84335; NIS 19; TNF 844; NOS 23; TNE 13313; TFE 1746
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT
PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA,
ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING
FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF
INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
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USE ONLY
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