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MSDS Material Safety Data Sheet
CAS

624-48-6
624-49-7

File Name: palomar_edu---dimethyl_maleate_96%.asp
 
                  PRODUCT #: 238198        NAME: DIMETHYL MALEATE, 96%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 12:51PM



Sigma Chemical Co.         Aldrich Chemical Co., Inc.     Fluka Chemical Corp.

P.O. Box 14508             1001 West St. Paul             1001 West St. Paul

St. Louis, MO 63178        Milwaukee, WI 53233            Milwaukee, WI 53233

Phone: 314-771-5765        Phone: 414-273-3850            Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            238198

    NAME:                 DIMETHYL MALEATE, 96%

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:   624-48-6

    MF: C6H8O4

    EC NO: 210-848-5

  ADDITIONAL INFORMATION

    CONTAINS DIMETHYL FUMARATE, CHEMICAL ABSTRACTS REGISTRY

    NUMBER 624-49-7.

  SYNONYMS

    DIMETHYLESTER KYSELINY MALEINOVE (CZECH) * DIMETHYL MALEATE * MALEIC

    ACID, DIMETHYL ESTER * METHYL MALEATE * SIPOMER DMM *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    TOXIC (USA)

    HARMFUL (EU)

    HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.

    IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.

    COMBUSTIBLE.

    KEEP AWAY FROM HEAT AND OPEN FLAME.

    READILY ABSORBED THROUGH SKIN.

    IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE

    IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE

    PROTECTION.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS

    AMOUNTS OF WATER.

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF

    WATER FOR AT LEAST 15 MINUTES.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

    COMBUSTIBLE.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR



                                          Page 1

                  PRODUCT #: 238198        NAME: DIMETHYL MALEATE, 96%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 12:51PM



    DISPOSAL.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT

    GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.

    USE ONLY IN A CHEMICAL FUME HOOD.

    SAFETY SHOWER AND EYE BATH.

    DO NOT BREATHE VAPOR.

    DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

    AVOID PROLONGED OR REPEATED EXPOSURE.

    READILY ABSORBED THROUGH SKIN.

    WASH THOROUGHLY AFTER HANDLING.

    TOXIC.

    IRRITANT.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    COLORLESS LIQUID

  PHYSICAL PROPERTIES

    BOILING POINT:         204 C TO 205 C

    FLASHPOINT                   196 F

                                  91C

    SPECIFIC GRAVITY:      1.152

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    ACIDS

    BASES

    OXIDIZING AGENTS

    REDUCING AGENTS

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.

    VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER

    RESPIRATORY TRACT.

    CAUSES SKIN IRRITATION.

  RTECS #: EM6300000

    2-BUTENEDIOIC ACID, DIMETHYL ESTER, (Z)-

  IRRITATION DATA

    EYE-RBT 500 MG SEV                            AJOPAA 29,1363,1946

    EYE-RBT 500 MG/24H MLD                        85JCAE -,374,1986

  TOXICITY DATA

    ORL-RAT LD50:1410 MG/KG                       AIHAAP 23,95,1962

    SKN-RBT LD50:530 UL/KG                        AIHAAP 23,95,1962

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL INCINERATOR



                                          Page 2

                  PRODUCT #: 238198        NAME: DIMETHYL MALEATE, 96%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 12:51PM



    EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    HARMFUL

    R 20/21/22

    HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.

    R 36/37/38

    IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.

    S 45

    IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE

    IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).

    S 26

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    S 36/37/39

    WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE

    PROTECTION.

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    NOHS 1974: HZD 81813; NIS 1; TNF 28; NOS 2; TNE 308

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

    EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









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