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MSDS Material Safety Data Sheet
CAS

110-82-7

File Name: palomar_edu---cyclohexane.asp
 
                         PRODUCT #: 28940        NAME: CYCLOHEXANE

                      MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                          Printed Tuesday, March 11, 1903 1:25PM



Sigma Chemical Co.          Aldrich Chemical Co., Inc.    Fluka Chemical Corp.

P.O. Box 14508              1001 West St. Paul            1001 West St. Paul

St. Louis, MO 63178         Milwaukee, WI 53233           Milwaukee, WI 53233

Phone: 314-771-5765         Phone: 414-273-3850           Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:             28940

    NAME:                  CYCLOHEXANE

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:    110-82-7

    MF: C6H12

    EC NO: 203-806-2

  SYNONYMS

    BENZENE, HEXAHYDRO- * CICLOESANO (ITALIAN) * CYCLOHEXAAN (DUTCH) *

    CYCLOHEXAN (GERMAN) * CYCLOHEXANE (ACGIH:DOT:OSHA) * CYKLOHEKSAN

    (POLISH) * HEXAHYDROBENZENE * HEXAMETHYLENE * HEXANAPHTHENE * RCRA

    WASTE NUMBER U056 * UN1145 (DOT) *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    FLAMMABLE (USA)

    HIGHLY FLAMMABLE (EU)

    HARMFUL

    HARMFUL BY INHALATION AND IF SWALLOWED.

    IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.

    TARGET ORGAN(S):

    LUNGS

    CENTRAL NERVOUS SYSTEM

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.

    KEEP CONTAINER IN A WELL-VENTILATED PLACE.

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS

    AMOUNTS OF WATER.

    CONTAMINATION OF THE EYES SHOULD BE TREATED BY IMMEDIATE AND PROLONGED

    IRRIGATION WITH COPIOUS AMOUNTS OF WATER.

    ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS

    WITH FINGERS.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    WASH CONTAMINATED CLOTHING BEFORE REUSE.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

    WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

    USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    EXTREMELY FLAMMABLE.



                                           Page 1

                        PRODUCT #: 28940        NAME: CYCLOHEXANE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Tuesday, March 11, 1903 1:25PM



    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND

    FLASH BACK.

    CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    EVACUATE AREA.

    SHUT OFF ALL SOURCES OF IGNITION.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    COVER WITH AN ACTIVATED CARBON ADSORBENT, TAKE UP AND PLACE IN CLOSED

    CONTAINERS. TRANSPORT OUTDOORS.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT

    GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.

    MECHANICAL EXHAUST REQUIRED.

    SAFETY SHOWER AND EYE BATH.

    USE NONSPARKING TOOLS.

    DO NOT BREATHE VAPOR.

    DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

    WASH THOROUGHLY AFTER HANDLING.

    IRRITANT.

    HARMFUL LIQUID.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    COLORLESS LIQUID

  PHYSICAL PROPERTIES

    BOILING POINT:          79 TO 81C

    MELTING POINT:       4 TO 7C

    FLASHPOINT                 -.40F

                               -18C

    EXPLOSION LIMITS IN AIR:

      UPPER                                     9%

      LOWER                                     1%

    AUTOIGNITION TEMPERATURE:         500 F           259C

    VAPOR PRESSURE:       77MM 20 C         168.8MM 37.7 C

    SPECIFIC GRAVITY:       0.777

    VAPOR DENSITY:      2.9

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    OXIDIZING AGENTS

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF INHALED OR SWALLOWED.

    MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.

    VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER

    RESPIRATORY TRACT.

    CAUSES SKIN IRRITATION.

    EXPOSURE CAN CAUSE:

    LUNG IRRITATION, CHEST PAIN AND EDEMA WHICH MAY BE FATAL.



                                          Page 2

                        PRODUCT #: 28940        NAME: CYCLOHEXANE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Tuesday, March 11, 1903 1:25PM



    GASTROINTESTINAL DISTURBANCES

    TARGET ORGAN(S):

    LUNGS

    NERVES

    TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND

    TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.

  RTECS #: GU6300000

    CYCLOHEXANE

  IRRITATION DATA

    SKN-RBT 1548 MG/2D-I                          JIHTAB 25,199,1943

  TOXICITY DATA

    ORL-RAT LD50:12705 MG/KG                      TXAPA9 19,699,1971

    ORL-MUS LD50:813 MG/KG                        NPIRI* 1,17,1974

    IHL-MAM LC50:70 GM/M3                         GTPZAB 32(10),25,1988

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND

    SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY

    FLAMMABLE.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    EC INDEX NO:      601-017-00-1

    HIGHLY FLAMMABLE

    HARMFUL

    R 11

    HIGHLY FLAMMABLE.

    S9

    KEEP CONTAINER IN A WELL-VENTILATED PLACE.

    S 16

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    S 33

    TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    ACGIH TLV-TWA 1030 MG/M3 (300 PPM)            DTLVS* TLV/BEI,1996

    MSHA STANDARD-AIR:TWA 300 PPM (1050 MG/M3)

     DTLVS* 3,65,1971

    OSHA PEL (GEN INDU):8H TWA 300 PPM (1050 MG/M3)

     CFRGBR 29,1910.1000,1994

    OSHA PEL (CONSTRUC):8H TWA 300 PPM (1050 MG/M3)

     CFRGBR 29,1926.55,1994

    OSHA PEL (SHIPYARD):8H TWA 300 PPM (1050 MG/M3)

     CFRGBR 29,1915.1000,1993

    OSHA PEL (FED CONT):8H TWA 300 PPM (1050 MG/M3)

     CFRGBR 41,50-204.50,1994

    OEL-AUSTRALIA:TWA 300 PPM (1050 MG/M3) JAN 1993

    OEL-AUSTRIA:TWA 300 PPM (1050 MG/M3) JAN 1993

    OEL-BELGIUM:TWA 300 PPM (1030 MG/M3) JAN 1993

    OEL-DENMARK:TWA 300 PPM (1050 MG/M3) JAN 1993

    OEL-FINLAND:TWA 300 PPM (1050 MG/M3);STEL 375 PPM (1315 MG/M3) JAN 1993



                                          Page 3

                        PRODUCT #: 28940        NAME: CYCLOHEXANE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Tuesday, March 11, 1903 1:25PM



    OEL-FRANCE:TWA 300 PPM (1050 MG/M3);STEL 375 PPM (1300 MG/M3) JAN 1993

    OEL-GERMANY:TWA 300 PPM (1050 MG/M3) JAN 1993

    OEL-HUNGARY:TWA 500 MG/M3;STEL 1000 MG/M3 JAN 1993

    OEL-JAPAN:TWA 150 PPM (520 MG/M3) JAN 1993

    OEL-THE NETHERLANDS:TWA 300 PPM (1050 MG/M3) JAN 1993

    OEL-THE PHILIPPINES:TWA 300 PPM (1050 MG/M3) JAN 1993

    OEL-POLAND:TWA 80 MG/M3 JAN 1993

    OEL-RUSSIA:TWA 150 PPM;STEL 80 MG/M3 JAN 1993

    OEL-SWEDEN:TWA 300 PPM (1000 MG/M3);STEL 370 PPM (1300 MG/M3) JAN 1993

    OEL-SWITZERLAND:TWA 300 PPM (1050 MG/M3);STEL 600 PPM JAN 1993

    OEL-TURKEY:TWA 300 PPM (1050 MG/M3) JAN 1993

    OEL-UNITED KINGDOM:TWA 300 PPM (1050 MG/M3);STEL 375 PPM JAN 1993

    OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV

    OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV

    NIOSH REL TO CYCLOHEXANE-AIR:10H TWA 300 PPM

     NIOSH* DHHS #92-100,1992

    NOHS 1974: HZD 21190; NIS 117; TNF 14841; NOS 74; TNE 125761

    NOES 1983: HZD 21190; NIS 37; TNF 2260; NOS 54; TNE 55077; TFE 14873

    EPA GENETOX PROGRAM 1988, NEGATIVE: CELL TRANSFORM.-SA7/SHE; HISTIDINE

     REVERSION-AMES TEST

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

    EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES

    EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997

    NIOSH ANALYTICAL METHOD, 1994: HYDROCARBONS, BP 36-126 DEGREE C, 1500

  U.S. INFORMATION

    THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









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