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MSDS Material Safety Data Sheet
CAS

102-54-5

File Name: palomar_edu---ferrocene.asp
 
                          PRODUCT #: F3375        NAME: FERROCENE

                      MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Wednesday, March 12, 1903 11:03AM



Sigma Chemical Co.          Aldrich Chemical Co., Inc.    Fluka Chemical Corp.

P.O. Box 14508              1001 West St. Paul            1001 West St. Paul

St. Louis, MO 63178         Milwaukee, WI 53233           Milwaukee, WI 53233

Phone: 314-771-5765         Phone: 414-273-3850           Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            F3375

    NAME:                 FERROCENE

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:   102-54-5

    MF: C10H10FE

    EC NO: 203-039-3

  SYNONYMS

    BISCYCLOPENTADIENYLIRON * DI-2,4-CYCLOPENTADIEN-1-YLIRON *

    DICYCLOPENTADIENYL IRON (ACGIH:OSHA) * IRON BIS(CYCLOPENTADIENE) *

    IRON DICYCLOPENTADIENYL *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    HARMFUL

    HARMFUL IF SWALLOWED.

    TARGET ORGAN(S):

    LIVER

    WEAR SUITABLE PROTECTIVE CLOTHING.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF

    WATER FOR AT LEAST 15 MINUTES.

    IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS

    AMOUNTS OF WATER.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    WASH CONTAMINATED CLOTHING BEFORE REUSE.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    WATER SPRAY.

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.

    AVOID RAISING DUST.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    CHEMICAL SAFETY GOGGLES.

    RUBBER GLOVES.

    NIOSH/MSHA-APPROVED RESPIRATOR.



                                           Page 1

                         PRODUCT #: F3375        NAME: FERROCENE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                       Printed Wednesday, March 12, 1903 11:03AM



    SAFETY SHOWER AND EYE BATH.

    MECHANICAL EXHAUST REQUIRED.

    AVOID INHALATION.

    DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

    AVOID PROLONGED OR REPEATED EXPOSURE.

    WASH THOROUGHLY AFTER HANDLING.

    HARMFUL SOLID.

    KEEP TIGHTLY CLOSED.

    HEAT-SENSITIVE.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    BURNT-ORANGE CRYSTALS

  PHYSICAL PROPERTIES

    BOILING POINT:         249 C

    MELTING POINT:       174 C TO 176 C

    VAPOR PRESSURE:       0.03MM 40 C

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    STRONG OXIDIZING AGENTS

    SENSITIVE TO HEAT

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF SWALLOWED.

    MAY BE HARMFUL IF INHALED.

    MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.

    MAY CAUSE IRRITATION.

  CHRONIC EFFECTS

    DAMAGE TO THE LIVER

    TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND

    TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.

  RTECS #: LK0700000

    FERROCENE

  TOXICITY DATA

    ORL-RAT LD50:1320 MG/KG                       SCCUR* -,5,1961

    IPR-RAT LD50:500 MG/KG                        NCIUS* PH43-64-886

    ORL-MUS LD50:832 MG/KG                        BJPCAL 24,352,1965

    IPR-MUS LD50:335 MG/KG                        NCIUS* PH43-64-886

    IVN-MUS LD50:178 MG/KG                        CSLNX* NX#02382

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A

    CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    HARMFUL

    R 22



                                          Page 2

                         PRODUCT #: F3375        NAME: FERROCENE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                       Printed Wednesday, March 12, 1903 11:03AM



    HARMFUL IF SWALLOWED.

    S 36

    WEAR SUITABLE PROTECTIVE CLOTHING.

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    ACGIH TLV-TWA 10 MG/M3                        DTLVS* TLV/BEI,1996

    OSHA PEL (GEN INDU):8H TWA 15 MG/M3, TOTAL DUST

     CFRGBR 29,1910.1000,1994

    OSHA PEL (GEN INDU):8H TWA 5 MG/M3, RESPIRABLE FRACTION

     CFRGBR 29,1910.1000,1994

    OSHA PEL (CONSTRUC):8H TWA 15 MG/M3, TOTAL DUST

     CFRGBR 29,1926.55,1994

    OSHA PEL (CONSTRUC):8H TWA 5 MG/M3, RESPIRABLE FRACTION

     CFRGBR 29,1926.55,1994

    OSHA PEL (SHIPYARD):8H TWA 15 MG/M3, TOTAL DUST

     CFRGBR 29,1915.1000,1993

    OSHA PEL (SHIPYARD):8H TWA 5 MG/M3, RESPIRABLE FRACTION

     CFRGBR 29,1915.1000,1993

    OEL-AUSTRALIA:TWA 10 MG/M3 JAN 1993

    OEL-BELGIUM:TWA 10 MG/M3 JAN 1993

    OEL-FINLAND:TWA 10 MG/M3;STEL 20 MG/M3;SKIN JAN 1993

    OEL-FRANCE:TWA 10 MG/M3 JAN 1993

    OEL-THE NETHERLANDS:TWA 10 MG/M3 JAN 1993

    OEL-SWITZERLAND:TWA 10 MG/M3 JAN 1993

    OEL-UNITED KINGDOM:TWA 10 MG/M3;STEL 20 MG/M3 JAN 1993

    OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV

    OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV

    NIOSH REL TO DICYCLOPENTADIENYL IRON, TOTAL DUST-AIR:TWA 10 MG/M3

     NIOSH* DHHS #92-100,1992

    NIOSH REL TO DICYCLOPENTADIENYL IRON-AIR:10H TWA 5 MG/M3

     NIOSH* DHHS #92-100,1992

    NOES 1983: HZD T2061; NIS 2; TNF 14; NOS 3; TNE 412; TFE 328

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

    EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES

    EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









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