PRODUCT #: D3679 NAME: DIETHANOLAMINE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 2:52PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: D3679
NAME: DIETHANOLAMINE
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 111-42-2
EC NO: 203-868-0
SYNONYMS
BIS(2-HYDROXYETHYL)AMINE * DEA * DIAETHANOLAMIN (GERMAN) *
DIETHANOLAMIN (CZECH) * DIETHANOLAMINE (ACGIH) * DIETHYLAMINE, 2,2'-
DIHYDROXY- * DIETHYLOLAMINE * 2,2'-DIHYDROXYDIETHYLAMINE * DI(2-
HYDROXYETHYL)AMINE * DIOLAMINE * 2-(2-HYDROXYETHYLAMINO)ETHANOL * 2,
2'-IMINOBISETHANOL * 2,2'-IMINODIETHANOL * NCI-C55174 *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
CORROSIVE
CAUSES BURNS.
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
TARGET ORGAN(S):
LIVER
KIDNEYS
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS
WITH FINGERS.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN IMMEDIATELY.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
SHUT OFF ALL SOURCES OF IGNITION.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
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PRODUCT #: D3679 NAME: DIETHANOLAMINE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 2:52PM
ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR
DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
USE ONLY IN A CHEMICAL FUME HOOD.
SAFETY SHOWER AND EYE BATH.
FACESHIELD (8-INCH MINIMUM).
DO NOT BREATHE VAPOR.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
CORROSIVE.
HARMFUL LIQUID.
KEEP TIGHTLY CLOSED.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
COLORLESS LIQUID/ WHITE SOLID
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
OXIDIZING AGENTS
COPPER, COPPER ALLOYS
ZINC
GALVANIZED IRON
AVOID CONTACT WITH ACID.
ABSORBS CO2 FROM AIR.
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE,
AND NITROGEN OXIDES.
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES
AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY RESULT IN SPASM, INFLAMMATION AND EDEMA OF THE
LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING.
TARGET ORGAN(S):
LIVER
KIDNEYS
RTECS #: KL2975000
ETHANOL, 2,2'-IMINODI-
IRRITATION DATA
SKN-RBT 50 MG OPEN MLD UCDS** 12/29/1971
SKN-RBT 500 MG/24H MLD 85JCAE -,685,1986
EYE-RBT 5500 MG SEV AJOPAA 29,1363,1946
EYE-RBT 750 UG/24H SEV 85JCAE -,685,1986
TOXICITY DATA
ORL-RAT LD50:620 UL/KG NTIS** OTS0516797
IPR-RAT LD50:120 MG/KG EVSSAV 2,289,1968
SCU-RAT LD50:2200 MG/KG EVSSAV 2,289,1968
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PRODUCT #: D3679 NAME: DIETHANOLAMINE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 2:52PM
IVN-RAT LD50:778 MG/KG EVSSAV 2,289,1968
IMS-RAT LD50:1500 MG/KG EVSSAV 2,289,1968
ORL-MUS LD50:3300 MG/KG GISAAA 29(11),25,1964
IPR-MUS LD50:210 MG/KG NTIS** OTS0516742
ORL-RBT LD50:2200 MG/KG EVSSAV 2,289,1968
SKN-RBT LD50:7640 UL/KG NTIS** OTS0516797
ORL-GPG LD50:2 GM/KG 85INA8 5,197,1986
SKN-GPG LD50:11900 UL/KG NTIS** OTS0516742
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
EC INDEX NO: 603-071-00-1
CORROSIVE
R 36/38
IRRITATING TO EYES AND SKIN.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-TWA 2 MG/M3 (0.46 PPM) (SKIN) DTLVS* TLV/BEI,1996
OEL-AUSTRALIA:TWA 3 PPM (15 MG/M3) JAN 1993
OEL-BELGIUM:TWA 3 PPM (13 MG/M3) JAN 1993
OEL-DENMARK:TWA 3 PPM (15 MG/M3) JAN 1993
OEL-FRANCE:TWA 3 PPM (15 MG/M3) JAN 1993
OEL-THE NETHERLANDS:TWA 3 PPM (15 MG/M3) JAN 1993
OEL-RUSSIA:STEL 5 MG/M3;SKIN JAN 1993
OEL-SWITZERLAND:TWA 0.1 MG/M3 JAN 1993
OEL-SWITZERLAND:TWA 3 PPM (13 MG/M3) JAN 1993
OEL-UNITED KINGDOM:TWA 3 PPM (15 MG/M3) JAN 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NIOSH REL TO DIETHANOLAMINE-AIR:10H TWA 3 PPM
NIOSH* DHHS #92-100,1992
NOHS 1974: HZD T0517; NIS 3; TNF 315; NOS 2; TNE 857
NOHS 1974: HZD 24615; NIS 147; TNF 18443; NOS 118; TNE 186455
NOES 1983: HZD 24615; NIS 249; TNF 46466; NOS 171; TNE 828471; TFE
218923
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
EPA TSCA SECTION 8(E) RISK NOTIFICATION, 8EHQ-0293-8736;8EHQ-0293-8746
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
NIOSH ANALYTICAL METHOD, 1994: AMINOETHANOL COMPOUNDS II, 3509
NTP TOXICITY STUDIES, RPT# TOX-20, APRIL 1997
NTP CARCINOGENESIS STUDIES; TEST COMPLETED (PEER REVIEW), APRIL 1997
U.S. INFORMATION
THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.
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PRODUCT #: D3679 NAME: DIETHANOLAMINE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 2:52PM
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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