24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
MATERIAL SAFETY DATA SHEET
Section 1 - Product and Company Identification
ISSUED BY: JEEN INTERNATIONAL CORPORATION
24 MADISON ROAD
FAIRFIELD, NJ 07004
Telephone # 973-439-1401
Chemtrec Emergency Telephone No.: 800-424-9300
Chemtrec International Telephone No.: 703-527-3887 (Collect Calls Accepted)
TRADE NAME: JEEMIDE N-1918
CHEMICAL NAME: STEARAMIDE DEA
CAS#: 93-82-3
D.O.T. HAZARD CLASS: NONE
PROPER SHIPPING NAME: NONE HAZARD RATINGS: HEALTH (1) FIRE (0)
REACTIVITY (0)
Section 2 鈥? Composition/Information on Ingredients
INGREDIENTS: OSHA PEL
DIETHANOLAMINE (CAS#: 111-42-2) 0.46 PPM, SKIN
(ACGIH TLV)
STEARAMIDE DEA (CAS#: 93-82-3 ) NOT LISTED
VALUES ARE NOT PRODUCT SPECIFICATIONS.
Section 3 鈥? Hazards Identification
GENERAL: LIMITED TOXICITY DATA ARE AVAILABLE ON THIS SPECIFIC PRODUCT; THIS HEALTH HAZARD
ASSESSMENT IS BASED
ON THE RESULTS OF SCREENING TEST.
EMERGENCY
OVERVIEW: APPEARANCE: OFF-WHITE WAXY SOLID. CAUSES EYE BURNS. MAY CAUSE SKIN IRRITATION.
INHALATION OR INGESTION MAY CAUSE MUCOUS MEMBRANE IRRITATION.
ROUTES OF
EXPOSURE: EYE CONTACT; SKIN CONTACT; INHALATION
SYMPTOMS OF OVEREXPOSURE (ACUTE & CHRONIC):
EYE CONTACT: THIS MATERIAL WILL PROBABLY IRRITATE HUMAN SKIN. EXPOSURE TO DIETHANOLAMINE MAY CAUSE
ALLERGIC CONTACT DERMATITIS. IF ALLERGY DEVELOPS, VERY LOW FUTURE EXPOSURES CAN CAUSE
ITCHING AND A SKIN RASH. SYSTEMICALLY TOXIC CONCENTRATIONS OF THIS PRODUCT WILL
PROBABLY NOT BE ABSORBED THROUGH
HUMAN SKIN. DIETHANOLAMINE HAS THE POTENTIAL FOR POSSIBLY HARMFUL SKIN ABSORPTION.
STUDIES HAVE BEEN PERFORMED BY THE NATIONAL TOXICOLOGY PROGRAM (NTP) ON SKIN
ABOSRPTION OF DIETHANOLAMINE IN MICE AND RATS. THE RESULTS OF THESE STUDIES SHOW NO
EVIDENCE OF CARCINOGENICITY IN RATS OF BOTH SEXES BUT CLEAR EVIDENCE OF CARCINOGENICITY
ON ICE OF BOTH SEXES. THE SIGNIFICANCE OF THESE FINDINGS IS UNCLEAR AND ADDITIONAL
TESTING IS CURRENTLY UNDERWAY.
INHALATION: HIGH CONCENTRATIONS OF MISTS OR AEROSOLS MAY IRRITATE RESPIRATORY PASSAGES. NO TOXIC
EFFECTS ARE KNOWN TO BE ASSOCIATED WITH INHALATION OF THIS MATERIAL.
INGESTION: IN HUMANS, IRRITATION OF THE MOUTH, PHARYNX, ESOPHAGUS AND STOMACH CAN DEVELOP
FOLLOWING INGESTION OF THIS PRODUCT. NO TOXIC EFFECTS ARE EXPECTED FOLLOWING INGESTION
OF THIS PRODUCT. CHRONIC
EFFECTS: OVEREXPOSURE TO DIETHANOLAMINE MAY AFFECT THE LIVER, KIDNEYS AND BLOOD. IN ACUTE AND
SUBACUTE FEEDING STUDIES IN RATS, 0.09 G/KG OF DIETHANOLAMINE CAUSED CHANGES IN LIVER AND
KIDNEY WEIGHTS.
Section 4 鈥? First Aid Measures
EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. HAVE EYES EXAMINED AND
TREATED BY MEDICAL PERSONNEL.
SKIN: WASH MATERIAL OFF OF THE SKIN WITH PLENTY OF SOAP AND WATER. IF REDNESS, ITCHING OR A
BURNING SENSATION DEVELOPS, GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GIVE ONE OR TWO GLASSES OF WATER TO DRINK AND REFER TO MEDICAL
PERSONNEL OR TAKE DIRECTION FROM EITHER A PHYSICIAN OR A POISON CONTROL CENTER. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION: REMOVE VICTIM TO FRESH AIR. IF A COUGH OR OTHER RESPIRATORY SYMPTOMS DEVELOP, CONSULT
MEDICAL PERSONNEL.
Page No. 1 of 4 鈥? MSDS 鈥? JEEMIDE N-1918
24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
PAGE NO. 2 OF 4 鈥? MSDS- JEEMIDE N-1918
Section 5 鈥? Fire Fighting Measures
FLASHPOINT AND METHOD: >200掳F, 93.33掳C (PMCC)
AUTOIGNITION TEMPERATURE: NO DATA
FLAMMABLE LIMITS: NO DATA
EXTINGUISHING MEDIA: WATER FOG, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, HALOGENATED
AGENTS.
SPECIAL FIRE FIGHTING
PROTECTIVE EQUIPMENT: SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE AND PROTECTIVE
CLOTHING. UNUSUAL FIRE AND EXPLOSION
HAZARDS: NONE KNOWN
EXPLOSION DATA: SENSITIVITY TO MECHANICAL IMPACT: NOT APPLICABLE
SENSITIVITY TO STATIC DISCHARGE: NOT APPLICABLE
Section 6 鈥? Accidental Release Measures
REFER TO SECTION 8 FOR PROPER PERSONAL PROTECTIVE EQUIPMENT.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
SWEEP UP AND RECOVER OR MIX MATERIAL WITH A MOIST ABSORBENT AND SHOVEL INTO A CHEMICAL WASTE
CONTAINER.WASH RESIDEU FROM SPILL AREA WITH WATER CONTAINING DETERGENT AND FLUSH TO A SEWER
SERVICED BY A PERMITTED WASTEWATER TREATMENT FACILITY.
Section 7 鈥? Handling and Storage
STORAGE REQUIREMENTS: 50 鈥? 90掳F IN ORIGINAL CLOSED CONTAINER
PRECAUTIONS TO TAKE DURING
HANDLING AND STORAGE: DO NOT GET IN EYES. AVOID BREATHING THIS MATERIAL
DO NOT SWALLOW. NORMAL CHEMICAL HANDLING AND STORAGE
Section 8 鈥? Exposure Controls/Personal Protection
EXPOSURE LIMITS: NO ACGIH TLV OR OSHA PEL IS ASSIGNED TO THIS MIXTURE. CONTROL OF EXPOSURE TO
BELOW THE PEL AND/OR TLV FOR THE INGREDIENTS (SEE SECTION 2 AND/OR BELOW) MAY NOT
BE SUFFICIENT. MINIMIZE
EXPOSURE IN ACCORDANCE WITH GOOD HYGIENE PRACTICE. THE ACGIH TLV FOR
DIETHANOLAMINE IS 0.46 PPM (SKIN).
ENGINEERING CONTROLS: USE VENTILATION ADQUATE TO MAINTAIN SAFE LEVELS.
EYE PROTECTION: CHEMICAL TIGHT GOGGLES AND FULL FACE SHIELD.
PROTECTIVE CLOTHING: IMPERVIOUS GLOVES RESPIRATORY
PROTECTION: IF NEEDED, USE MSHA-NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS.
OTHER PROTECTIVE
EQUIPMENT: EYE WASH STATION AND SAFETY SHOWER IN WORK AREA.
Section 9 鈥? Physical and Chemical Properties
APPEARANCE & ODOR: OFF WHITE WAXY SOLID MELTING POINT: NO
DATA
BOILING POINT: 340掳F, 171.11掳C VAPOR PRESSURE (mm Hg@ 20掳C): NO DATA
VAPOR DENSITY (AIR=1): NO DATA ODOR THRESHOLD: NODATA
pH (10% AQUEOUS): 9.8 SPECIFIC GRAVITY: 0.8625
%VOLATILE BY VOLUME: NO DATA CLOUD POINT: NO DATA
VISCOSITY: NO DATA PARTITION COEFFICIENT: NO DATA
COEFFICIENT OF WATER/OIL DISTRIBUTION: NO DATA FREEZING POINT: NO DATA
24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
PAGE NO. 3 OF 4 鈥? MSDS- JEEMIDE N-1918
Section 10 鈥? Stability and Reactivity
STABILITY: STABLE UNDER NORMAL CONDITIONS
INCOMPATIBILITY: OXIDIZING AGENTS
CONDITIONS TO AVOID: NONE KNOWN
HAZARDOUS DECOMPOSITION PRODUCTS: COMBUSTION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE.
NITROGEN OXIDES AMMONIA.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
Section 11 鈥? Toxicological Information
THE TOXICITY DATA LISTED BELOW ARE BASED ON THE RESULTS OF SCREENING TESTS ON THIS SPECIFIC PRODUCT.
EYE CONTACT: A 5% SUSPENSION OF THIS MATERIAL WAS TESTED. THIS MATERIAL WAS NON-IRRITATING
RABBIT EYE IRRITATION STUDIES. HOWEVER, DUE TO THE PERCENT DILUTION THAT WAS
TESTED AND THE NATURE OF
THE COMPONENTS, IT IS EXPECTED THAT THIS MATERIAL WILL PROBABLY CAUSE EYE BURNS.
SKIN CONTACT: A 5% SUSPENSION OF THIS MATERIAL WAS TESTED. THIS MATERIAL IS NONIRRITATING IN
RABBIT DERMAL IRRITATION STUDIES. HOWEVER, DUE TO THE PERCENT DILUTION THAT WAS
TESTED THIS MATERIAL IS EXPECTED TO CAUSE SKIN IRRITATION.
CARCINOGENICITY: THIS MATERIAL IS NOT LSITED AS A CARCINOGEN BY OSHA, IARC AND NTP.
REPRODUCTIVE TOXICITY/
TERATOGENICITY: NO AVAILABLE INFORMATION
MUTAGENICITY: NO AVAILABLE INFORMATION
TOXICOLOGICALLY
SYNERGISTIC PRODUCTS: NONE KNOWN
Section 12 鈥? Ecological Information
NO DATA IS AVAILABLE ON THIS PRODUCT.
Section 13 鈥? Disposal Considerations
DISPOSAL METHOD: DISCARDED PRODUCT IS NOT A HAZARDOUS WASTE UNDER RCRA, 40 CFR 261.
CONTAINER DISPOSAL: EMPTY CONTAINER RETAINS PRODUCT RESIDUE. OBSERVE ALL HAZARD PRECAUTIONS. DO
NOT DISTRIBUTE, MAKE AVAILABLE, FURNISH OR REUSE EMPTY CONTAINER EXCEPT FOR
STORAGE AND SHIPMENT OF ORIGINAL PRODUCT. REMOVE ALL PRODUCT RESIDUE FROM
CONTAINER AND PUNCTURE OR OTHERWISE DESTROY EMPTY CONTAINER BEFORE DISPOSAL.
Section 14 鈥? Transport Information
DEPARTMENT OF TRANSPORTATION: REGULATED
PROPER SHIPPING NAME: OTHER REGULATED SUBSTANCES, LIQUID, N.O.S. (CONTAINS
DIETHANOLAMINE) RQ (DIETHANOLAMINE) 鈥? 100 LBS. OR 45.4 KG.
HAZARD CLASS: CLASS 9, PG III, OTHER REGULATED SUBSTANCE
UN/NA ID NUMBER: NA 3082
ERG NUMBER: ERG#171
TDG (TRANSPORTATION OF DANGEROUS GOODS): REGULATED
Section 15 鈥? Regulatory Information
TSCA (TOXIC SUBSTANCES CONTROL ACT) REGULATIONS, 40 CFR 710:
ALL INGREDIENTS ARE ON THE TSCA CHEMICAL SUBSTANCE INVENTORY.
DSL (CANADIAN DOMESTIC SUBSTANCES LIST):
ALL INGREDIENTS ARE LISTED ON THE CANADIAN DSL.
OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200, HAZARD SUMMARY:
PHYSICAL HAZARDS: NONE
HEALTH HAZARDS: CORROSIVE (EYE)
WHMIS CLASSIFICATION: CLASS D, DIVISION 2 鈥? TOX.
CERCLA AND SARA REGULATIONS (40 CFR 255, 370 AND 372):
THIS MATERIAL CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SARA 313:
CAS NUMBER: CHEMICAL NAME
111-42-2 DIETHANOLAMINE
SARA 311/312 HAZARD CATEGORIES: IMMEDIATE:YES DELAYED:NO FIRE:NO PRESSURE:NO REACTIVITY: NO
STATE REGULATIONS: NONE
24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
PAGE NO. 4 OF 4 鈥? MSDS- JEEMIDE N-1918
Section 16 鈥? Other Information
WE ASSIGNED NFPA RATINGS AND HMIS RATINGS TO THIS PRODUCT BASED ON THE HAZARDS OF ITS INGREDIENT(S).
BECAUSE THE CUSTOMER IS MOST AWARE OF THE APPLICATION OF THE PRODUCT, HE MUST ENSURE THAT THE
PROPER PERSONAL PROTECTIVE EQUIPMENT (PPE) IS PROVIDED CONSISTENT WITH INFORMATION CONTAINED IN THE
PRODUCT MSDS.*
HMIS INFORMATION: HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0
NFPA INFORMATION: HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0
*THIS INFORMATION IS INTENDED SOLELY FOR THE USE OF INDIVIDUALS TRAINED IN THE PARTICULAR HAZARD RATING
SYSTEM. THIS
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH BUT NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE.
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