24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
MATERIAL SAFETY DATA SHEET
MANUFACTURER'S NAME: JEEN INTERNATIONAL CORP. CHEMTREC EMERGENCY TEL: 800-424-9300
24 MADISON ROAD CHEMTREC INT'L. EMERGENCY TEL: 703-527-3887
FAIRFIELD, NJ 07004 (COLLECT CALLS ACCEPTED)
Tel#: 973-439-1401 DATE ISSUED: 11/20/2002 - REV.
SECTION 1 - PRODUCT
PRODUCT TRADE NAME: JEEQUAT 868P
SECTION 2- COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Characterization:
Quaternary ammonium compounds, di-C-(12-18) alkyl dimethyl, chlorides
C-12/18 Dialkyl dimethyl ammonium chloride ( ~ 70 %); Isopropanol (~ 20%); Water (~ 10%)
CAS Number: 68 391-05-9
EINECS Number: 269-924-1
Hazardous Ingredients:
Substance % CAS Number Symbols R-Phrases
Isopropylalkohol ~20 000067-63-0 F 11
Quaternare Ammoniumverbindung ~70 C 34
Chlormethan,Methylchlorid <5 ppm 000074-87-3 F,Xn 13-40-48/20
SECTION 3- HAZARDS IDENTIFICATION
Hazards Description: leichtentzundlich Corrosive
Special hazards to health and environment: Highly flammable Causes burns
Highly flammable. In use, may form flammable/explosive vapour-air mixture. Causes burns.
SECTION 4- FIRST AID MEASURES
General Information: Highly flammable. In use, may form flammable/explosive vapour-air mixture. Causes burns.
After Inhalation: Remove the casualty into fresh air and keep him calm. Summon a doctor immediately.
After contact with skin: In case of contact with skin wash off immediately with plenty of water. Take for medical treatment
After contact with eyes: In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
After ingestion: Rinse out the mouth and immediately seek medical attention
Advice to doctor: Detergents or surfactants cause irreversible damage to stomach and intestine lining. Do not
induce vomiting but pump stomach with the addition of preparation containing defoamer.
SECTION 5- FIRE-FIGHTING MEASURES
Suitable extinguishing media: Water, foam, carbon dioxide
Special hazards: In fires, hazardous combustion gases are formed.: Nitrogen oxides (NOx) Carbon
monoxide (CO) Hydrogen chloride (HC1)
Additional information: Cool container at risk with water spray jet. Fire residues and contaminated firefighting
water must be disposed of in accordance with the local regulations.
JEEQUAT 868P PAGE 1 OF 4
24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
SECTION 6- ACCIDENTAL RELEASE MEASURES
Personal Precautions: High risk of slipping due to leakage/spillage of product. Ensure adequate ventilation. Keep away
sources of ignition.
Environmental Precautions: Do not discharge into the drains/surface waters/groundwater.
Methods for Cleaning up/taking up: Take up with absorbent material (e.g. general-purpose binder). Dispose of absorbed material in
accordance with the regulations.
SECTION 7- HANDLING AND STORAGE
Handling
Advice on safe handling: Open container only in presence of local exhaust ventilation. Provide good room ventilation even
at ground level (vapours are heavier than air).
Advice on protection against fire and explosion:
Keep away from sources of ignition. Do not smoke. Traces of flammable substances can collect in
the vapour space of closed systems, therefore keep sources of ignition away. Take precautionary
measures against static discharges.
Storage
Requirements for storage rooms and vessels:
Use corrosion resistant containers.
Further information on storage conditions:
When stored in tank cover with a protective layer of nitrogen gas for protection.
SECTION 8- EXPOSURE CONTROLS / PERSONAL PROTECTION
Additional advice on system design: Loading: Use extra pipe for gas exchange and pay attention to explosion protection!
Don鈥檛 use compressor!
Ingredients with occupational exposure limits to be monitored limits:
Substance CAS Number Method Value Unit
2-Propanol 67-63-0 MAK 400 ml/m3
Chlormethan 74-87-3 MAK 50 ml/m3
Personal Protective Equipment
Hand Protection: Protective Gloves
Eye Protection: Face Shield
Body Protection: Impermeable protective clothing
SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES
Form: Liquid
Colour: Light Yellow, Clear
Odour: Isopropanole
Changes in Physical State Test Method
Boiling Point (deg. C): ~83 Isopropanol
Flash Point (deg. C): 20 DIN 51755
Flammability
Ignition Temp. (deg. C): 425 Isopropanol
Self-ignition
Explosion Limits
Lower (Vol - %): 2,0 Isopropanol
Upper (Vol - %): 12,0
Vapour Pressure:
Density (g/cm3): ~0.87 (26,7 deg.C) (DGF C-IV 2)
Solubility in Water: Dispersible (20 deg. C)
pH Value (20 deg. C): 6,5 鈥? 8,5 (50 g/l) (ISO 6384)
Further Information
Viscosity (mPa.s): <100 (20 deg. C) (Brookfield)
JEEQUAT 868P PAGE 2 OF 4
24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
SECTION 10- STABILITY AND REACTIVITY
----
SECTION 11- TOXICOLOGICAL INFORMATION
*Corrosive to eyes and skin. (undiluted product)
*In 5% dispersion 鈥渟lightly irritant鈥? to rabbit eye
*In 5% solution 鈥渟lightly irritant鈥? to rabbit skin
*No toxicological data are available. Analogous to a product with a similar composition.
Acute toxicity data
LD50 Oral (mg/kg): rat >2.000 *
LC50 inhalation (mg/l):
Acute Toxicity:
SECTION 12- ECOLOGICAL INFORMATION
Information on elimination (persistence / degradability):
Readily eliminable from water
No toxicological data are available; analogous to a product with a similar composition
Dialky (C12) dimethyl ammonium chloride:
90-92 % (7 days) River water dieaway *
99 % (7 days) River water dieaway*
Dialkyl (C18) dimethyl ammonium chloride:
91-93 % ( 3 hours) Continuous-flow activated sludge*
*Swisher, Surfactants Biodegradation 1987, page: 874/875
Further Information: Do not allow product to enter soil or waterways; on storage or before discharging into drainage systems follow the
state of the art technology.
SECTION 13- ADVICE ON DISPOSAL
Disposal: In accordance with the regulations disposure by authorized companies
Description: Detergents/Surfactants.
SECTION 14- TRANSPORT INFORMATION
Land Transport
ADR / RID: 3/26b
Hazard number: 338
UN number: 2924
Hazard label: 3+8
Packaging group II
TVB: 2924 Flammable liquid, corrosive, n.o.s. (contains 2-Propanole) (contains quaternary
ammonium compounds)
JEEQUAT 868P PAGE 3 OF 4
24 Madison Road, Fairfield, New Jersey 07004, USA
Tel: 800-771-JEEN (5336), Tel: 973-439-1401, Fax: 973-439-1402,
email: info@jeen.com , Website: www.jeen.com
SECTION 14- TRANSPORT INFORMATION continued:
Remarks
Marine transport
IMDG-Code: 3.2
UN Number: 2924
Hazard label: 3+8
IMDG page: 3231
IMDG packaging group: II
EmS: 3-02
MFAG: 760 + 305
Marine pollutant: II
TVB:
Remarks: Un 2924, Flammable Liquid, Corrosive, N.O.S (contains 2-Propanole) (contains quaternary
ammonium Compounds)
Air Transport
ICAO: 3
UN number: 2924
Hazard label: 3+8
Packing group: II
Packaging Instruction: 305 / 307
ICAO max. weight: 11 / 51
TVB:
Remarks: Flammable liquid, corrosive, n.o.s. (contains 2-Propanole) (contains quaternary ammonium
compounds)
SECTION 15- REGULATORY INFORMATION
Labeling according to EEC-guidelines
Hazard symbols: F,C Highly flammable Corrosive
R phrases: 11-34 Highly flammable. Causes burns
S phrases: 16-26-28-37/39-45. Keep away from sources of ignition 鈥? No smoking. In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with
plenty of water. Wear suitable protective gloves and eye/face protection. In case of accident or if you feel
unwell, seek medical advice immediately (show label where possible).
SECTION 16- OTHER INFORMATION
HMIS: HEALTH: 1 FIRE: 3 REACTIVITY: 0 PPE CODE: H
NFPA: HEALTH: 1 FIRE: 3 REACTIVITY: 0 ADDITIONAL INFORMATION: NONE
This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of JEEN
International Corporation. The data on this sheet relates only to the specific material designated herein. JEEN International
Corporation assumes no legal responsibility for use or reliance upon these data.
JEEQUAT 868P PAGE 4 OF 4
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