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                                                                   MATERIAL SAFETY DATA SHEET 
                        Section 1 Company and Product Identi飥乧ation 
Product Name              CD26 PE 100 Tests                                 .. Doc. ID: IM2724-75 AB 
                                                                            . Revised (year/month/day) 2008/01/21 
 
Part Number               IM2724 
Product Use               For Research Use Only. See product literature for details. 
Series Name               IOTest庐 
Manufacturer              Distributed by Beckman Coulter, Inc. for 
                          IMMUNOTECH (A Beckman Coulter Company) 
                          130, av.de Lattre de Tassigny - BP 177 
                          13276 Marseille Cedex 09 - France T猫l. (33) 4 91 17 27 00 
EC REP Address            Beckman Coulter Ireland Inc. 
                          Mervue Business Park 
                          Mervue, Galway, Ireland 353 91 774068 
Distributor and                     Refer to attached list, Document ID: 472050, for local distributor 
                                    and emergency phone numbers. 
Emergency Phone No. 
 
 
                                   Section 2 Hazards Identi飥乧ation 
Emergency Overview 
                                                   Colorless; Transparent; Liquid; Odorless 
                                                        Non飥俛mmable aqueous solution. 
                                                             Harmful if swallowed. 
                                                     Skin, eye and respiratory tract irritant. 
                                                      Contains material of animal origin. 
 
Physical Hazards             Sodium azide forms explosive compounds with heavy metals. Repeated contact 
                             of low concentrations of azide with lead and copper commonly found in plumbing 
                             drains may result in the build up of shock sensitive compounds. 
Potential Health             May cause eye, skin and respiratory tract irritation and central nervous system 
                             depression with headache, dizziness, nausea and unconsciousness. 
Effects Summary 
                             This product contains material of animal origin and should be considered as 
                             potentially capable of transmitting infectious diseases. 
                             See Section 11 Toxicological Information for more detailed health information. 
Potential                    No information available. 
Environmental Effects 
Product Hazard                                 Meets Hazardous Criteria for Preparation/Mixture 
Classi飥乧ations 
                               EU:                                      WHMIS:                              US OSHA: 
                               Xn;R22                                                                       Not applicable 
                                                                        Not applicable 
                               . 
 
 
 
                                              漏2008 Beckman Coulter, Inc. 
                                              Global MSDS 鈥? English 
                                                                  Doc. ID: IM2724-75 AB 
CD26 PE 100 Tests                                                                                                 Page 2 of 7 
 
 
 
                    Section 3 Composition and Information on Ingredients 
Hazardous Ingredients:                                                       Hazard Classi飥乧ation of Pure Ingredients 
                                                                              EU 
   Chemical Name            CAS #         EINECS #       % by wt.                             WHMIS             US OSHA 
 
                          26628-22-8       2478521          0.1                                                Highly Toxic 
     Sodium Azide                                                        N ;R50/53              D1A 
                                                                                                                  Irritant 
                                                                         T+;R28-32 
See Section 15 Regulatory Information for additional information on hazard classi飥乧ations. 
See Section 16 for Risk Phrases and WHMIS Classi飥乧ation Description. 
 
 
                                        Section 4 First Aid Measures 
Inhalation                             If product is inhaled, move exposed individual to fresh air. If individual is not 
                                       breathing, begin arti飥乧ial respiration immediately and obtain medical attention. 
Eye Contact                            If product enters eyes, wash eyes gently under running water for 15 
                                       minutes or longer, making sure that the eyelids are held open. If pain 
                                       or irritation occur, obtain medical attention. 
Skin Contact                           In case of skin contact, 飥倁sh with copious amounts of water for at 
                                       least 15 minutes. Remove contaminated clothing and shoes. If pain 
                                       or irritation occur, obtain medical attention. 
Ingestion                              If ingested, wash mouth out with water. If irritation or discomfort 
                                       occurs, seek medical attention. 
 
 
                                    Section 5 Fire Fighting Measures 
Flammable Properties                   Non飥俛mmable aqueous solution. 
Extinguishing Media                    Use extinguishing media suitable for surrounding 飥乺e. 
                                       No special hazards determined. 
Special Fire and Explosion 
Hazards 
Hazardous Combustion                   Due to the composition and volume of this product, combustion products 
                                       generated from it are not expected to present a signi飥乧ant hazard. 
Products 
Protective Equipment                   Self-contained breathing apparatus is recommended for 飥乺e飥乬hters. 
for Fire飥乬hters 
 
 
                               Section 6 Accidental Release Measures 
Personal Precautions                   This product contains a material of biological origin. Use universal 
                                       precautions during clean up procedures. 
Spill and Leak                         As a precautionary measure, treat spilled material with a 1:10 bleach/water solution. 
                                       Absorb liquid and place in container suitable for disposal. Avoid generation of 
Procedures 
                                       aerosols during clean up. Comply with applicable waste disposal regulations. 
Environmental                          Contain spill to prevent migration. 
Precautions 
                                                           Doc. ID: IM2724-75 AB 
CD26 PE 100 Tests                                                                                          Page 3 of 7 
 
 
 
 
                                Section 7 Handling and Storage 
Handling Precautions             This product should be handled as though capable of transmitting infectious 
                                 diseases. Universal precautions should be followed when using this product. 
                                 Avoid inhaling, ingesting, and contact with eyes and skin. 
Recommended Storage              Keep away from incompatible material (see Section 10). 
Conditions                       To maintain ef飥乧acy, store according to the instructions in the product labeling. 
 
 
                      Section 8 Exposure Controls and Personal Protection 
Exposure Limits 
                                 None established 
US OSHA: 
ACGIH: 
       Sodium Azide              0.29 mg/m3 Ceiling (as NaN3); 0.11 ppm Ceiling (vapor, as hydrazoic acid) 
DFG MAK: 
       Sodium Azide              0.2 mg/m3 MAK (inhalable fraction); 0.4 mg/m3 Peak (inhalable fraction) 
                                 None established 
NIOSH 
Japan                            None established 
                                 No special engineering controls are required. Use with good general ventilation. 
Engineering Controls 
Respiratory Protection           Under normal conditions, the use of this product should not require respiratory 
                                 protection. If aerosols are generated during use, the use of respiratory 
                                 protection should be evaluated by a quali飥乪d professional. 
Eye Protection                   Safety glasses or chemical goggles should be worn to prevent eye contact. 
                                 Impervious gloves, such as Nitrile or equivalent, should be worn 
Skin Protection 
                                 to prevent skin contact. 
 
 
                          Section 9 Physical and Chemical Properties 
                                 Liquid 
Physical State 
Color                            Colorless 
 
Transparency                     Transparent 
 
Odor                             Odorless 
                                 Not applicable 
Odor Threshold 
pH                               7.25 
 
Freezing Point                   Not available 
 
Boiling Point                    Not available 
 
Flash Point                      Not applicable 
 
Evaporation Rate                 Not available 
                                                          Doc. ID: IM2724-75 AB 
CD26 PE 100 Tests                                                                                        Page 4 of 7 
 
 
 
                    Section 9 Physical and Chemical Properties (Continued) 
                                 Not applicable 
Flammability (Solid, Gas) 
Flammable Limits                 Not applicable 
 
Vapor Pressure                   Not available 
 
Vapor Density                    Not available 
 
Speci飥乧 Gravity                  1.005 @20掳C 
 
Solubility 
  Water                          Miscible 
                                 Not available 
  Organic 
                                 Not available 
Coef飥乧ient of Water/Oil 
Distribution 
Autoignition Temp.               Not applicable 
 
Decomposition Temperature        Not available 
 
Percent Volatiles                Not applicable 
 
 
                               Section 10 Stability and Reactivity 
Stability                        Stable under normal temperatures and pressures. 
 
Hazardous Incompatibilities      Metals and metallic compounds 
                                 Strong acids 
                                 Strong bases 
                                 Strong oxidizers 
                                 Sodium azide forms explosive compounds with heavy metals. Repeated contact 
                                 of low concentrations of azide with lead and copper commonly found in plumbing 
                                 drains may result in the build up of shock sensitive compounds. 
Hazardous Decomposition          No decomposition products posing signi飥乧ant hazards would be 
                                 expected from this product. 
Products 
Conditions to Avoid              Keep away from incompatible material. 
 
 
                              Section 11 Toxicological Information 
Toxicity Data 
for Hazardous Ingredients 
     Sodium Azide                Oral LD50 Rat: 27 mg/kg; Dermal LD50 Rabbit: 20 mg/kg 
Primary Routes                   Common routes of entry include inhalation, ingestion and eye/skin contact. Speci飥乧 
                                 paths of concern for potentially infectious materials are skin puncture, contact with 
of Exposure 
                                 broken skin, contact with mucous membranes and inhalation of aerosolized material. 
                                                             Doc. ID: IM2724-75 AB 
CD26 PE 100 Tests                                                                                            Page 5 of 7 
 
 
 
                        Section 11 Toxicological Information (Continued) 
                                    Although its concentration in this product is low, sodium azide is highly toxic 
Potential Effects of 
                                    by ingestion and skin absorption. Overexposure may result in irritation of skin, 
Acute Exposure 
                                    eyes and mucous membranes, lowered blood pressure and irregular heartbeat. 
                                    Sodium azide is a chemical asphyxiant and may effect the cardiovascular, 
                                    respiratory and central nervous systems. Symptoms may include irritation, 
                                    severe, pounding headaches, dizziness, weakness, nausea, vomiting, low blood 
                                    pressure, rapid heartbeat, convulsions, collapse and death. 
                                    This product contains material of animal origin and should be considered as 
                                    potentially capable of transmitting infectious diseases. 
                                    Prolonged or repeated exposure to sodium azide may result in pounding headaches, 
Potential Effects of Chronic 
                                    eye and nose irritation, low blood pressure, fatigue and dizziness. 
Exposure 
Symptoms of Overexposure            Symptoms of overexposure may include: eye, skin, nose and throat 
                                    irritation; headache, weakness, dizziness, confusion, nausea and vomiting. 
                                    Severe cases may exhibit dif飥乧ulty in breathing, irregular heartbeat, reddish 
                                    colored skin, unconsciousness, convulsions, coma and death. Symptoms 
                                    may be delayed for several hours after exposure. 
Carcinogenicity                     No ingredients in this product are listed as carcinogens by ACGIH, 
                                    IARC, NTP, OSHA or 67/548/EEC Annex I. 
Other Effects                       Reproductive effects have been reported in animal studies. 
 
Conditions Aggravated               None identi飥乪d. 
by Exposure 
 
 
                                 Section 12 Ecological Information 
Ecotoxicity 
     Sodium Azide                   96 Hr LC50 Oncorhynchus mykiss: 0.8 mg/L; 96 Hr LC50 Lepomis macrochirus: 
                                    0.7 mg/L; 96 Hr LC50 Pimephales promelas: 5.46 mg/L [飥俹w-through] 
Biodegradability                    No information available. 
Bioaccumulation                     No information available. 
Mobility                            No information available. 
 
Other Adverse Effects               No information available. 
 
 
 
                                Section 13 Disposal Considerations 
Waste Disposal                      Dispose of waste product, unused product and contaminated packaging in 
                                    compliance with federal, state and local regulations. If unsure of the applicable 
                                    requirements, contact the authorities for information. 
                                    Sodium azide preservative may form explosive compounds in metal drain lines. 
                                    See NIOSH Bulletin: Explosive Azide Hazard (8/16/76). 
 
 
                                  Section 14 Transport Information 
Transportation of this product is not regulated under ICAO, IMDG, US DOT, European ADR or Canadian TDG. 
                                                              Doc. ID: IM2724-75 AB 
CD26 PE 100 Tests                                                                                             Page 6 of 7 
 
 
 
 
                                  Section 15 Regulatory Information 
US Federal and State Regulations 
SARA 313                            Sodium Azide is subject to reporting requirements of Section 313, Title III of SARA. 
 
CERCLA RG鈥檚,                        Sodium Azide is listed. 
40 CFR 302.4 
                                    No ingredients listed. 
California Proposition 65 
Massachusetts MSL                   Sodium Azide is listed. 
 
New Jersey Dept. of                 Sodium Azide is listed. 
Health RTK List 
Pennsylvania RTK                    Sodium Azide is listed. 
EU Labeling Classi飥乧ation 
         Classi飥乧ation             Risk and Safety Phrases 
                                   R22 Harmful if swallowed. 
                                   S28 After contact with skin, wash immediately with plenty of water. 
                 Harmful 
 
 
Canada 
This product does not meet WHMIS criteria for hazardous materials. 
                                 Not applicable 
PIN: 
Ingredients on Ingredient        Sodium Azide 
Disclosure List: 
Ingredients with unknown         None 
toxicological properties: 
Some hazardous ingredients listed in Section 15 are below OSHAs and WHMIS鈥? 1.0% w/w (0.1% for carcinogens) 
or EU鈥檚 ingredient speci飥乧 concentrations required for reporting in Section 3. 
                                                                   Doc. ID: IM2724-75 AB 
CD26 PE 100 Tests                                                                                           Page 7 of 7 
 
 
 
 
                                        Section 16 Other Information 
Beckman Coulter Safety            Flammability (Section V): 0                                  Code 
                                  Health (Section XI): 1                                       0=none 
Rating 
                                  Reactivity with Water (Section X): 0                         1=slight 
                                  Contact (Section VIII): 1                                    2=caution 
                                                                                               3=severe 
Revision Changes                 Reformatted Sections 2, 3, 5, 8, 9, 12, 15, and 16 per ANSI Z400.1-2004 Standard. 
Risk Phrases and                 R28 Very toxic if swallowed. 
WHMIS Classi飥乧ation              R32 Contact with acids liberates very toxic gas. 
Description From                 R50/53 Very toxic to aquatic organisms, may cause long-term adverse 
Section 3                        effects in the aquatic environment. 
                                 D1A - Acute Dermal Toxicity 
                                 D1A - Acute Oral Toxicity 
                                 D1A - Acute Inhalation Toxicity 
 For further information, please contact your local Beckman Coulter representative. 
 
WHILE BECKMAN COULTER, INC. BELIEVES THE INFORMATION CONTAINED HEREIN IS VALID AND ACCURATE, BECKMAN COULTER MAKES NO 
WARRANTY OR REPRESENTATION AS TO ITS VALIDITY, ACCURACY, OR CURRENCY. BECKMAN COULTER SHALL NOT BE LIABLE OR OTHERWISE 
RESPONSIBLE IN ANY WAY FOR USE OF EITHER THIS INFORMATION OR MATERIALS TO WHICH IT APPLIES. DISPOSAL OF HAZARDOUS 
MATERIALS MAY BE SUBJECT TO LOCAL LAWS OR REGULATIONS. 
                                                       Printed in U.S.A. 
 
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