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Safety Data Sheet Certis
Dimilin 25WP
Prepared 16.08.2000 Page 1 of 3
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1. Substance / preparation and company name
Dimilin 25WP
Certis
1b Mills Way, Boscombe Down Business Park, Amesbury, Wiltshire. SP4 7RX
Telephone: 01980 676500 Fax: 01980 626555
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2. Composition / information on ingredients
Chemical name Concentration CAS number EC number R phrases Symbols
Diflubenzuron 25% 35367-38-5 252-529-3 50 N
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3. Possible hazards
Contact with eyes: may cause irritation
Very toxic to aquatic organisms
Appearance: off-white powder
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4. First aid measures
Skin contact: Wash affected area with plenty of soap and water. Seek medical advice if necessary.
Eye contact: If substance has got into eyes, immediately wash out with plenty of water for at least
15 minutes. Seek medical attention if irritation persists.
Ingestion: Do not induce vomiting . Give water or milk to drink. Seek immediate medical attention.
Inhalation: Remove patient to fresh air. When in doubt or symptoms persist, seek medical attention.
General: In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible)
NOTE TO PHYSICIANS: treat by observation and supportive measures as indicated by the patients
condition.
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5. Fire fighting measures
Auto-ignition point 鈥? not known
Non-explosive
Flash point 鈥? not applicable
Nitrogen and carbon oxides may be formed
Halogen compounds may be formed
In case of fire, do not breathe fumes
Wear Chemical Protection Suit and Positive-Pressure Breathing Apparatus
In case of fire use water, carbon dioxide or dry agent
Use as little water as possible
Prevent run off water from entering drains if possible
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6. Accidental release measures
Cleaning up: Ventilate area. Use vacuum cleaner to collect spilled material. Place in appropriate
container. Remove contaminated material to safe location for subsequent disposal.
Special precautions: Avoid raising dust. If contamination of drainage systems or water courses is
unavoidable, immediately inform appropriate authorities. Seek expert advice for removal and
disposal of all contaminated materials and wastes. Wear protective clothing as per section 8.
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Safety Data Sheet Certis
Dimilin 25WP
Prepared 16.08.2000 Page 2 of 3
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7. Handling and storage
Handling:
Keep away from food, drink and animal feedingstuffs
When using do not eat, drink or smoke
Avoid contact with skin and eyes
Wear suitable protective clothing
Use only in well ventilated areas
Storage:
Keep locked up and out of reach of children
Keep only in the original container in a cool, well ventilated place
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8. Exposure controls / personal protection
Engineering controls:
Engineering controls should be provided which maintain airborne concentrations as low as
practicable
Precautionary measures:
Keep working clothes separately and do not take them home
Use only in well ventilated areas
Personal protection:
When handling this substance e.g. sampling, wear goggles giving complete eye protection
Wear suitable protective clothing, eye/face protection and gloves
In case of insufficient ventilation, wear suitable respiratory equipment
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9. Physical and chemical properties
Appearance: Off-white powder
pH: Not known
Boiling point: Not applicable
Melting point: Not known
Flash point: Not applicable
Explosion limits: Non explosive
Vapour pressure: Not known
3
Bulk density: 0.3 g/cm
Solubility: Dispersible
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10. Stability and reactivity
Stable for storage for at least two years if stored under normal conditions (<25掳C)
No hazardous reactions known if used for its intended purpose
Keep away from heat and sources of ignition
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11. Toxicological information
LD50 (oral, rat) >40000 mg/kg
LD50 (skin, rabbit) >18500 mg/kg
LC50 (inhalation, rat) >3.5 mg/l/4h
Irritation (dermal, rabbit) 0.5 ml/4h test score NA 鈥? non irritant
Irritation (eye, rabbit) 0.1 ml teat score cornea NA 鈥? non irritant
Sensitization (guinea pig) Negative
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Safety Data Sheet Certis
Dimilin 25WP
Prepared 16.08.2000 Page 3 of 3
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12. Ecological information
Ecotoxicology:
Do not contaminate surface waters or ditches with chemical or used container
Very toxic to aquatic organisms
Biodegradable
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13. Disposal considerations
Disposal should be in accordance with local, state or national legislation
Do not reuse empty containers
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14. Transport information
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (contains diflubenzuron
25%)
UN
UN No: 3077 Hazard class: 9, miscellaneous
Packing group: III
Road/Rail (ADR/RID)
ADR UN No: 3077 ADR Hazard class: 9, miscellaneous
ADR Item No: 9,12(c) ADR/RID No:
Tremcard: TEC(R)-90G02
Sea (IMDG)
IMDG UN No: 3077 IMDG Hazard class: 9, miscellaneous
IMDG Page No: IMDG Pack group: III
IMDG EmS:
Air (ICAO/IATA)
ICAO UN No: 3077 ICAO Hazard class: 9. Miscellaneous
ICAO Packing group: III
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15. Regulatory information
R50 鈥? Very toxic to aquatic organisms
S1/2 鈥? Keep locked up and out of the reach of children
S3/9/49 鈥? Keep only in the original container in a cool well ventilated place
S13 鈥? Keep away from food, drink and animal feeding stuffs
S15 鈥? Keep away from heat
S16 鈥? Keep away from sources of ignition 鈥? No smoking
S20/21 鈥? When using do not eat, drink or smoke
S24/25 鈥? Avoid contact with skin and eyes
S36 鈥? Wear suitable protective clothing
S36/37/39 鈥? Wear suitable protective clothing, gloves and eye/face protection
S38 鈥? In case of insufficient ventilation, wear suitable respiratory equipment
S51 鈥? Use only in well ventilated areas
S41 鈥? In case of fire and/or explosion hazard do not breathe fumes
S45 鈥? In case of accident or if you feel unwell, seek medical advice immediately (show label where
possible)
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16. Other information
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