Material Safety Data Sheet
HMIS
NFPA Personal Protective Equipment
Health Hazard
3
0 Fire Hazard
0
3 0
Reactivity
0 See Section 15.
Section 1. Chemical Product and Company Identification Page Number: 1
Catalog
Manganese ICP Standard PM225
Common Name/
Number(s).
Trade Name
Mixture.
CAS#
Manufacturer Not applicable.
RTECS
SPECTRUM QUALITY PRODUCTS INC.
14422 S. SAN PEDRO STREET TSCA 8(b) inventory:
TSCA
Manganese; Nitric acid, 70%;
GARDENA, CA 90248
Water
Not available.
Commercial Name(s) Not available.
CI#
Not available.
Synonym
IN CASE OF EMERGENCY
Manganese ICP Standard
Chemical Name CHEMTREC (24hr) 800-424-9300
Not available. CALL (310) 516-8000
Chemical Family
Not applicable.
Chemical Formula
SPECTRUM QUALITY PRODUCTS INC.
Supplier
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
Section 2.Composition and Information on Ingredients
Exposure Limits
3
STEL (mg/m3) CEIL (mg/m3)
Name CAS # TWA (mg/m ) % by Weight
1) Manganese 7439-96-5 1 3 0.1
2) Water 7732-18-5 95.5
3) Nitric acid, fuming 7697-37-2 5 4 3.5
Manganese:
Toxicological Data
ORAL (LD50): Acute: 9000 mg/kg [Rat].
on Ingredients
Nitric acid, fuming
LD50: Not available.
LC50: Not available.
Section 3. Hazards Identification
Potential Acute Health Effects Very hazardous in case of skin contact (corrosive, permeator), of eye contact (irritant). Hazardous in case of
ingestion, of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of
eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce
severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe
over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching.
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Manganese ICP Standard
Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant), of ingestion, of
Potential Chronic Health
inhalation.
Effects
Non-sensitizer for skin.
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance is toxic to blood, kidneys, lungs, the nervous system, mucous membranes.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged
contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged
exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in
one or many human organs. Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation.
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes
before reuse. Get medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention immediately.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation
when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
Non-flammable.
Flammability of the Product
Not applicable.
Auto-Ignition Temperature
Not applicable.
Flash Points
Not applicable.
Flammable Limits
Not available.
Products of Combustion
Not applicable.
Fire Hazards in Presence of
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
Slightly explosive in presence of reducing materials, of combustible materials, of organic materials.
Not applicable.
Fire Fighting Media
and Instructions
Not available.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
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Manganese ICP Standard
Section 6. Accidental Release Measures
Small Spill Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill Corrosive liquid. Poisonous liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside
container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to reduce
vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at
a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Section 7. Handling and Storage
Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water
Precautions
to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical
advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from
incompatibles such as reducing agents, metals, alkalis.
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Personal Protection Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Boots.
Personal Protection in Case of Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be
a Large Spill used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits Manganese
TWA: 1 STEL: 3 from ACGIH (TLV) [United States] [1995]
Nitric acid, fuming
TWA: 2 CEIL: 4
TWA: 5 CEIL: 10
TWA: 2 STEL: 4 (ppm) [Australia]
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Physical state and appearance Liquid. Not available.
Odor
Not available.
Taste
Not applicable.
Molecular Weight
Colorless.
Color
<2 [Acidic.]
pH (1% soln/water)
105掳C (221掳F)
Boiling Point
May start to solidify at -41.6掳C (-42.9掳F) based on data for: Nitric acid, fuming.
Melting Point
Not available.
Critical Temperature
Weighted average: 1.01 (Water = 1)
Specific Gravity
The highest known value is 6 kPa (@ 20掳C) (Nitric acid, fuming). Weighted average: 2.43 kPa (@ 20掳C)
Vapor Pressure
The highest known value is 2.5 (Air = 1) (Nitric acid, fuming). Weighted average: 0.69 (Air = 1)
Vapor Density
Not available.
Volatility
The highest known value is 0.29 ppm (Nitric acid, fuming)
Odor Threshold
Not available.
Water/Oil Dist. Coeff.
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Page Number: 4
Manganese ICP Standard
Not available.
Ionicity (in Water)
See solubility in water.
Dispersion Properties
Easily soluble in cold water, hot water.
Solubility
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Reactive with reducing agents, metals, alkalis.
Incompatibility with various
Slightly reactive to reactive with combustible materials, organic materials, acids.
substances
Non-corrosive in presence of glass, of aluminum.
Corrosivity
Reacts exlposively with carbides, cyanides, sulfides, alkalies and turpentine (Nitric acid, fuming)
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
Will not occur.
Polymerization
Section 11. Toxicological Information
Routes of Entry Absorbed through skin. Dermal contact. Inhalation. Ingestion.
Toxicity to Animals LD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Other Toxic Effects on Very hazardous in case of skin contact (permeator).
Humans Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on Not available.
Chronic Effects on Humans
Special Remarks on other Not available.
Toxic Effects on Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The products of degradation are more toxic.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
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Manganese ICP Standard
Section 13. Disposal Considerations
Waste Disposal
Section 14. Transport Information
DOT Classification Class 8: Corrosive material
: Nitric acid, solution (Nitric acid, fuming) UNNA: 2031 PG: II
Identification
Marine Pollutant
Special Provisions for
Transport
DOT (Pictograms)
Section 15. Other Regulatory Information and Pictograms
Rhode Island RTK hazardous substances: Nitric acid, fuming
Federal and State
Pennsylvania RTK: Manganese; Nitric acid, 70%
Regulations
Minnesota: Nitric acid, fuming
Massachusetts RTK: Manganese; Nitric acid, 70%
New Jersey: Nitric acid, fuming
TSCA 8(b) inventory: Manganese; Nitric acid, 70%; Water
TSCA 8(d) H and S data reporting: Nitric acid, fuming: June 1999
SARA 302/304/311/312 extremely hazardous substances: Nitric acid, 70%
SARA 313 toxic chemical notification and release reporting: Manganese 0.1%; Nitric acid, 70% 5%
CERCLA: Hazardous substances.: Nitric acid, 70%;
California
Proposition 65
Warnings
Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
Other Classifications WHMIS (Canada)
CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
CLASS E: Corrosive liquid.
DSCL (EEC) R23- Toxic by inhalation.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.
Health Hazard
HMIS (U.S.A.) 3 National Fire Protection Flammability
0
Association (U.S.A.)
Fire Hazard
0
0
3
Health Reactivity
Reactivity
0
Specific hazard
Personal Protection
WHMIS (Canada)
(Pictograms)
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Page Number: 6
Manganese ICP Standard
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment Gloves.
Full suit.
Vapor respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Face shield.
Section 16. Other Information
PMANG
MSDS Code
Not available.
References
Other Special Not available.
Considerations
Validated by Sonia Owen on 8/11/2006. Verified by Sonia Owen.
Printed 9/12/2006.
CALL (310) 516-8000
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
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