Material Safety Data Sheet
HMIS
NFPA Personal Protective Equipment
Health Hazard
2
1 Fire Hazard
1
2 2
Reactivity
2 See Section 15.
Section 1. Chemical Product and Company Identification Page Number: 1
Catalog
Sodium permanganate monohydrate S1385
Common Name/
Number(s).
Trade Name
10101-50-5
CAS#
Manufacturer SD6650000
RTECS
SPECTRUM CHEMICAL MFG. CORP.
14422 S. SAN PEDRO STREET TSCA 8(b) inventory: Sodium
TSCA
permanganate monohydrate
GARDENA, CA 90248
Not available.
Commercial Name(s) Not applicable.
CI#
Permanganic acid, sodium salt
Synonym
IN CASE OF EMERGENCY
Sodium permanganate monohydrate
Chemical Name CHEMTREC (24hr) 800-424-9300
Permanganate salt. (Oxidizing agent.) CALL (310) 516-8000
Chemical Family
NaMnO4.H2O
Chemical Formula
SPECTRUM CHEMICAL MFG. CORP.
Supplier
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
Section 2.Composition and Information on Ingredients
Exposure Limits
3
STEL (mg/m3) CEIL (mg/m3)
Name CAS # TWA (mg/m ) % by Weight
1) Sodium permanganate monohydrate 10101-50-5 100
Sodium permanganate monohydrate:
Toxicological Data
ORAL (LD50): Acute: 9000 mg/kg [Rat].
on Ingredients
Section 3. Hazards Identification
Potential Acute Health Effects Very hazardous in case of skin contact (irritant), of eye contact (irritant). Hazardous in case of skin contact
(permeator), of ingestion, of inhalation. Prolonged exposure may result in skin burns and ulcerations.
Over-exposure by inhalation may cause respiratory irritation. Inflammation of the eye is characterized by redness,
watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally,
blistering.
CARCINOGENIC EFFECTS: Not available.
Potential Chronic Health
MUTAGENIC EFFECTS: Not available.
Effects
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Continued on Next Page
Page Number: 2
Sodium permanganate monohydrate
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.
Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Wash contaminated clothing before reusing.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical
attention.
Inhalation Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek medical attention.
Ingestion Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
May be combustible at high temperature.
Flammability of the Product
Not available.
Auto-Ignition Temperature
Not available.
Flash Points
Not available.
Flammable Limits
Some metallic oxides.
Products of Combustion
Highly flammable in presence of combustible materials.
Fire Hazards in Presence of
Flammable in presence of open flames and sparks, of heat.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
Oxidizing material.
Fire Fighting Media
Do not use water jet. Use flooding quantities of water. Avoid contact with organic materials.
and Instructions
When heated to decomposition it emits toxic fumes.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill Oxidizing material.
Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance
damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;
dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the product is not
present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Continued on Next Page
Page Number: 3
Sodium permanganate monohydrate
Section 7. Handling and Storage
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material Empty
Precautions
containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material.
Do not ingest. Do not breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment If
ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes
Keep away from incompatibles such as reducing agents, organic materials, metals, acids, moisture.
Keep container dry. Keep in a cool place. Ground all equipment containing material. Oxidizing materials should
Storage
be stored in a separate safety storage cabinet or room.
Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spill to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
TWA: 5 (mg/m3) from ACGIH (TLV) [1995]
Exposure Limits
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Powdered solid.) Not available.
Odor
Not available.
Taste
159.94 g/mole
Molecular Weight
Red.
Color
7 [Neutral.]
pH (1% soln/water)
Not available.
Boiling Point
Decomposes.
Melting Point
Not available.
Critical Temperature
2.47 (Water = 1)
Specific Gravity
Not applicable.
Vapor Pressure
Not available.
Vapor Density
Not available.
Volatility
Not available.
Odor Threshold
Not available.
Water/Oil Dist. Coeff.
Not available.
Ionicity (in Water)
See solubility in water.
Dispersion Properties
Soluble in cold water, hot water.
Solubility
Continued on Next Page
Page Number: 4
Sodium permanganate monohydrate
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Highly reactive with reducing agents, organic materials, metals, acids.
Incompatibility with various
Reactive with moisture.
substances
Non-corrosive in presence of glass.
Corrosivity
Not available.
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
No.
Polymerization
Section 11. Toxicological Information
Routes of Entry Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals Acute oral toxicity (LD50): 9000 mg/kg [Rat].
Chronic Effects on Humans Not available.
Other Toxic Effects on Very hazardous in case of skin contact (irritant).
Humans Hazardous in case of skin contact (permeator), of ingestion, of inhalation.
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on Not available.
Chronic Effects on Humans
Special Remarks on other Exposure can cause nausea, headache and vomiting. Material is corrosive to the mucous membranes.
Toxic Effects on Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The product itself and its products of degradation are not toxic.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Continued on Next Page
Page Number: 5
Sodium permanganate monohydrate
Section 13. Disposal Considerations
Waste Disposal
Section 14. Transport Information
DOT Classification CLASS 5.1: Oxidizing material.
: Sodium permanganate : UN1503 PG: II
Identification
Not available.
Special Provisions for
Transport
DOT (Pictograms)
OXIDIZER
5.1
Section 15. Other Regulatory Information and Pictograms
Pennsylvania RTK: Sodium permanganate monohydrate
Federal and State
Massachusetts RTK: Sodium permanganate monohydrate
Regulations
TSCA 8(b) inventory: Sodium permanganate monohydrate
SARA 313 toxic chemical notification and release reporting: Sodium permanganate monohydrate
California
Proposition 65
Warnings
Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
CLASS C: Oxidizing material.
Other Classifications WHMIS (Canada)
CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC) R38- Irritating to skin.
R41- Risk of serious damage to eyes.
Health Hazard
HMIS (U.S.A.) 2 National Fire Protection Flammability
1
Association (U.S.A.)
Fire Hazard
1
2
2
Health Reactivity
Reactivity
2
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
5.1
Continued on Next Page
Page Number: 6
Sodium permanganate monohydrate
ADR (Europe)
(Pictograms)
Protective Equipment Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Splash goggles.
Section 16. Other Information
S4305
MSDS Code
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987.
References
-Material safety data sheet emitted by: la Commission de la Sant茅 et de la S茅curit茅 du Travail du Qu茅bec.
-SAX, N.I. Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984.
-Guide de la loi et du r猫glement sur le transport des marchandises dangeureuses au canada. Centre de conformit茅
internatinal Lt茅e. 1986.
Other Special Not available.
Considerations
Validated by Sonia Owen on 8/11/2006. Verified by Sonia Owen.
Printed 9/13/2006.
CALL (310) 516-8000
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
|