MATERIAL SAFETY DATA SHEET
95 鈥斺?? S E C T I O N I 鈥斺??
PRODUCT IDENTIFICATION
THE SHERWIN - WILLIAMS CO. EMERGENCY TELEPHONE NO. DATE OF PREPARATION
(216) 566-2917 1 - DEC - 95
101 PROSPECT AVE. N.W.
CLEVELAND, OH 44115 INFORMATION TELEPHONE NO.
(216) 566-2902 漏1995, The Sherwin-Williams Co.
ACRYLYD PLUS 庐 Polyurethane Enamel POL
37-, P5-, PX-, P10, P11 series
鈥斺?? S E C T I O N I I 鈥斺?? ACGIH OSHA Vapor POL-LF POL-LL V6V440 V6V441
Non-Lead Lead
CAS No. HAZARDOUS INGREDIENT TLV PEL Units Pressure
(percent by weight) Colors Colors Activator Accelerator
(mm Hg)
64742-88-7 Mineral Spirits. 100 100 PPM 2.0 0-1 0-1 8
108-88-3 搂 Toluene. 100
50 PPM (Skin) 22.0 15-25 15-25
<150 >
100-41-4 搂 Ethylbenzene 100 100 PPM 7.1 4-6 4-6 7
<125 > <125 >
1330-20-7 搂 Xylene. 100 100 PPM 5.9 20-30 20-30 41
<150 > <150 >
95-63-6 搂 1,2,4-Trimethylbenzene 25 25 PPM 2.0 1 1
150 150
123-86-4 n-Butyl Acetate. PPM 10.0 3-15 3-15 12 87
<200 > <200 >
112-07-2 搂 2-Butoxyethyl Acetate. Not Established 1.0 2-3 2-3
108-65-6 1-Methoxy-2-Propanol Acetate Not Established 1.8 1 1
0.5 Mg/M3
Proprietary Hexamethylene Diisocyanate Polymer. 40
<1.0 > Supplier Limit
822-06-0 Hexamethylene Diisocyanate (max.) 0.005 PPM 0.05 0.6
Mg/M3 as Dust
13463-67-7 Titanium Dioxide 10 10[5] 0-20 0-20
[Resp. Fraction]
1344-37-2 Lead Chromate 0.05 0.05 Mg/M3 <20
12656-85-8 Molybdate Orange.
搂 Lead Compound (maximum) [% Lead] 20[11.8]
搂 Chromium Compound (maximum) [% Chromium] 20[2.6]
搂 Zinc Compound [% Zinc] 5[1.0]
Weight per Gallon (lbs.) 7.5-9.0 7.5-9.0 7.97 7.37
VOC - Total Volatile Organic Compounds (lbs./gal.) 4.4-5.3 4.4-5.3 4.78 7.03
VOC - Less Water and exempt Solvents (lbs./gal.) 4.4-5.3 4.4-5.3 4.78 7.03
Photochemically Reactive Yes Yes Yes No
Flash Point (掳F) 45-60 45-60 77 72
DOL Storage Category 1B 1B 1C 1B
HMIS (NFPA) Rating (health - flammability - reactivity) 2* 3 0 2* 3 0 2* 3 1 230
PAINT-SAFE庐 Personal Protection K K K K
搂 Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR 372.65 C
猫猫猫 猫猫猫
MSDS Text Page Follows I-9
ACRYLYD PLUS庐 Polyurethane Enamel POL
Section III 鈥? PHYSICAL DATA Section VII 鈥? SPILL OR LEAK PROCEDURES
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? 鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
PRODUCT WEIGHT EVAPORATION RATE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
鈥? See TABLE 鈥? Slower than Ether
SPECIFIC GRAVITY VAPOR DENSITY
鈥? 0.90-1.14 鈥? Heavier than Air Remove all sources of ignition. Ventilate and remove with inert absorbent.
BOILING RANGE MELTING POINT
鈥? 222-395 掳F 鈥? N.A. If activator is spilled, all personnel in the area should be protected as in Section VIII.
VOLATILE VOLUME SOLUBILITY IN WATER
鈥? 3-65 % 鈥? N.A. Cover spill with absorbent material. Deactivate spilled material with a 10% ammonium hydroxide
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? solution (household ammonia). After 10 minutes, collect in open containers and add more
Section IV 鈥? FIRE AND EXPLOSION HAZARD DATA ammonia. Cover loosely. Wash spill area with soap and water.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? WASTE DISPOSAL METHOD
FLAMMABILITY CLASSIFICATION FLASH POINT LEL UEL
See TABLE 0.5 13.1 Waste from these products may be hazardous as defined under the Resource Conservation and
RED LABEL 鈥? Flammable, Flash below 100 F Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the
EXTINGUISHING MEDIA applicable EPA hazardous waste numbers. Waste from products containing Lead or Chromium
Carbon Dioxide, Dry Chemical, Foam must be tested for extractability.
UNUSUAL FIRE AND EXPLOSION HAZARDS Incinerate in approved facility. Do not incinerate closed container. Dispose of in
Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open accordance with Federal, State, and Local regulations regarding pollution.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
flame. Closed containers may explode when exposed to extreme heat. Application to hot
Section VIII 鈥? PROTECTION INFORMATION
surfaces requires special precautions. During emergency conditions overexposure to
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
decomposition products may cause a health hazard. Symptoms may not be immediately apparent.
PRECAUTIONS TO BE TAKEN IN USE
Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES NO PERSON SHOULD USE THESE PRODUCTS, OR BE IN THE AREA WHERE IT IS BEING USED, IF THEY HAVE
Full protective equipment including self-contained breathing apparatus should be used. CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS OR IF THEY EVER HAD A REACTION TO ISOCYANATES.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be Certain colors contain Lead (See TABLE and PRODUCT LABEL). Before initial use of
used to cool closed containers to prevent pressure build-up and possible autoignition or Lead-containing colors, consult OSHA's Standard for Occupational Exposure to Lead
explosion when exposed to extreme heat. (29 CFR 1910.1025).
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact
Section V 鈥? HEALTH HAZARD DATA with skin and eyes. Wash hands after using.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? These products may contain materials classified as nuisance particulates (listed 鈥渁s Dust鈥? in
ROUTES OF EXPOSURE Section II) which may be present at hazardous levels only during sanding or abrading of the
Exposure may be by INHALATION and/or SKIN or EYE contact, depending on conditions of use. dried film. If no specific dusts are listed in Section II, the applicable limits for nuisance
To minimize exposure, follow recommendations for proper use, ventilation, and personal dusts are ACGIH TLV 10 mg./m3 (total dust), 3 mg./m3 (respirable fraction), OSHA PEL 15 mg./m3
protective equipment. (total dust), 5 mg./m3(respirable fraction).
ACUTE Health Hazards VENTILATION
EFFECTS OF OVEREXPOSURE Local exhaust preferable. General exhaust acceptable if the exposure to materials in
Irritation of eyes, skin and respiratory system. May cause nervous system depression. Section II is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94,
Extreme overexposure may result in unconsciousness and possibly death. 1910.107, 1910.108.
Certain colors contain Lead (See TABLE and PRODUCT LABEL). Acute occupational exposure to RESPIRATORY PROTECTION
Lead is uncommon, but results in symptoms similar to chronic overexposure described below. Where overspray is present, a positive pressure air supplied respirator (TC19C NIOSH/MSHA
SIGNS AND SYMPTOMS OF OVEREXPOSURE approved) should be worn. If unavailable, a properly fitted organic vapor/particulate
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure respirator approved by NIOSH/MSHA for protection against materials in Section II may be
to vapors or spray mists. effective. Follow respirator manufacturer鈥檚 directions for use. Wear the respirator for the
Redness and itching or burning sensation may indicate eye or excessive skin exposure. whole time of spraying and until all vapors and mists are gone. NO PERSONS SHOULD BE ALLOWED
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE IN THE AREA WHERE THESE PRODUCTS ARE BEING USED UNLESS EQUIPPED WITH THE SAME RESPIRATOR
Activator CONTAINS ISOCYANATES. Isocyanates may cause allergic respiratory and/or skin PROTECTION RECOMMENDED FOR THE PAINTERS.
reaction in susceptible persons or sensitization. This effect may be delayed several hours When sanding, wirebrushing, abrading, burning, or welding the dried film, wear a particulate
after exposure. respirator approved by NIOSH/MSHA for protection against non-volatile materials in Section II.
EMERGENCY AND FIRST AID PROCEDURES PROTECTIVE GLOVES
If INHALED: If any breathing problems occur during use, LEAVE THE AREA and get fresh air. Wear gloves which are recommended by glove supplier for protection against materials in
If problems remain or occur later, IMMEDIATELY get medical attention. Section II.
If on SKIN: Wash affected area thoroughly with soap and water. EYE PROTECTION
Remove contaminated clothing and launder before re-use. Wear safety spectacles with unperforated sideshields.
If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. OTHER PROTECTIVE EQUIPMENT
If SWALLOWED: Get medical attention. Use barrier cream on exposed skin.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
CHRONIC Health Hazards
Section IX 鈥? PRECAUTIONS
Certain Colors contain Lead and/or Chromate (See TABLE and PRODUCT LABEL).
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Chronic overexposure to Lead may result in damage to the blood-forming, nervous, urinary,
DOL STORAGE CATEGORY 鈥? See TABLE
and reproductive systems (including embryotoxic effects). Symptoms include abdominal discomfort
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
or pain, constipation, loss of appetite, metallic taste, nausea, insomnia, nervous irritability,
Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until
weakness, muscle and joint pains, headache and dizziness.
all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights,
Chromates are listed by IARC and NTP. Although studies have associated exposure to
and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition.
Chromium VI compounds with an increased risk of respiratory cancer, available evidence
Consult NFPA Code. Use approved Bonding and Grounding procedures.
indicates that Lead Chromate (Chrome Yellow, Molybdate Orange) DOES NOT present this hazard.
Keep container closed when not in use. Transfer only to approved containers with complete
Prolonged overexposure to solvent ingredients in Section II may cause adverse effects to
and appropriate labeling. Do not take internally. Keep out of the reach of children.
the liver, urinary, blood forming, cardio-vascular, and reproductive systems.
OTHER PRECAUTIONS
Activator CONTAINS ISOCYANATES. Persons sensitive to isocyanates will experience increased
Certain colors contain Lead (See TABLE and PRODUCT LABEL). Do not apply Lead-containing
allergic reaction on repeated exposure.
colors on toys or other children's articles, furniture, or any interior surface of a dwelling or
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such
facility which may be occupied or used by children. Do not apply on any exterior surface of
exposure levels are not attainable in the workplace.
dwelling units, such as window sills, porches, stairs, or railings to which children may be
Reports have associated repeated and prolonged overexposure to solvents with permanent brain
commonly exposed.
and nervous system damage.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? These products must be mixed with other components before use. Before opening the packages,
Section VI 鈥? REACTIVITY DATA READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? Intentional misuse by deliberately concentrating and inhaling the contents can be harmful
STABILITY 鈥? Stable or fatal.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
CONDITIONS TO AVOID
Section X 鈥? OTHER REGULATORY INFORMATION
None known.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
INCOMPATIBILITY
Metallics contain Aluminum. Contamination with Water, Acids, or Alkalis can cause evolution CALIFORNIA PROPOSITION 65
of hydrogen, which may result in dangerously increased pressures in closed containers. WARNING: These products, except for V6V441, contain chemicals known to the State of
HAZARDOUS DECOMPOSITION PRODUCTS California to cause cancer and birth defects or other reproductive harm.
By fire: Carbon Dioxide, Carbon Monoxide, Oxides of Metals in Section II The above information pertains to these products as currently formulated, and is based on
HAZARDOUS POLYMERIZATION 鈥? Will Not Occur the information available at this time. Addition of reducers or other additives to these
products may substantially alter the composition and hazards of the product. Since
I-9
conditions of use are outside our control, we make no warranties, express or implied,
and assume no liability in connection with any use of this information.
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