MATERIAL SAFETY DATA SHEET Page 1 of 5
MATERIAL SAFETY DATA SHEET
4-Chlorobenzotrifluoride, 98%
41836
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: 4-Chlorobenzotrifluoride, 98%
Company Identification: Acros Organics N.V.
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 98-56-6 |P-chloro-a,a,a-trifluorotoluene | 98 | 202-681-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Appearance: clear, colorless. Flash Point: 47 deg C.
Not available.
Target Organs: None.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes.
Remove contaminated clothing and shoes.
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MATERIAL SAFETY DATA SHEET Page 2 of 5
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Flammable Liquid.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
Autoignition Temperature: > 650 deg C (> 1,202.00 deg F)
Flash Point: 47 deg C ( 116.60 deg F)
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Avoid contact with heat, sparks and flame. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
+--------------------+-------------------+-------------------+-----------------+
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|--------------------|-------------------|-------------------|-----------------|
| P-chloro-a,a,a-trif|as F: 2.5 mg/m3 |as F: 2.5 mg/m3 |as F: 2.5 mg/m3 |
| luorotoluene |TWA (listed |TWA (listed | TWA (listed |
| | under | under | under |
| | FLUORIDES). | FLUORIDES). | FLUORIDES). |
+--------------------+-------------------+-------------------+-----------------+
OSHA Vacated PELs:
P-chloro-a,a,a-trifluorotoluene:
as F: 2.5 mg/m3 TWA (listed under FLUORIDES)
Personal Protective Equipment
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MATERIAL SAFETY DATA SHEET Page 3 of 5
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 娄1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Not available.
Appearance: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: 0.67 cP 38.00
Boiling Point: 136.0 - 138.0 deg C @ 760.00m
Freezing/Melting Point: - 36.00 - - 0.00 deg
Decomposition Temperature: Not available.
Solubility: 29 ppm (23 c)
Specific Gravity/Density: 1.3530g/cm3
Molecular Formula: C7H4ClF3
Molecular Weight: 180.56
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Not available.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-56-6: XS9145000
LD50/LC50:
CAS# 98-56-6: Inhalation, mouse: LC50 =20 gm/m3; Inhalation, rat:
LC50 =22 gm/m3; Oral, mouse: LD50 = 11500 mg/kg; Oral, rat: LD50 =
13 gm/kg.
Carcinogenicity:
P-chloro-a,a,a-trifluorotoluene -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as FLU
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
RCRA D-Series Maximum Concentration of Contaminants:
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None listed.
RCRA D-Series Chronic Toxicity Reference Levels: None
listed.
RCRA F-Series: None listed.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Not listed as a material banned from land disposal
according to RCRA.
**** SECTION 14 - TRANSPORT INFORMATION ****
US DOT
Shipping Name: CHLOROBENZOTRIFLUORIDES
Hazard Class: 3
UN Number: 2234
Packing Group: III
IMO
Shipping Name: CHLOROBENZOTRIFLUORIDES
Hazard Class: 3.3
UN Number: 2234
Packing Group: III
IATA
Shipping Name: CHLOROBENZOTRIFLUORIDES
Hazard Class: 3
UN Number: 2234
Packing Group: III
RID/ADR
Shipping Name: CHLOROBENZOTRIFLUORIDES
Dangerous Goods Code: 3(31C)
UN Number: 2234
Canadian TDG
Shipping Name: CHLOROBENZOTRIFLUORIDES
Hazard Class: 3
UN Number: UN2234
Other Information: FLASHPOINT 47 C
**** SECTION 15 - REGULATORY INFORMATION ****
US FEDERAL
TSCA
CAS# 98-56-6 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 98-56-6: Effective Date: April 29, 1983; Sunset Date: April 29, 1
993
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
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MATERIAL SAFETY DATA SHEET Page 5 of 5
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
P-chloro-a,a,a-trifluorotoluen can be found on the following state
right to know lists: California, (listed as FLUORIDES),
Pennsylvania, (listed as FLUORIDES), Minnesota, (listed as
FLUORIDES).
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 98-56-6: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
This product does not have a WHMIS classification.
CAS# 98-56-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 98-56-6:. OEL-RUSSIA:STEL 20 mg/m3;Skin
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/28/1995 Revision #3 Date: 9/02/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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