**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 101-54-2 |N-Phenyl-1,4-phenylenediamine | 98 | 202-951-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin. May cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. In rare instances, exposure may
cause sensitization, resulting in inflammation of the mucous
membranes and in eczematous eruptions.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with soap and plenty of
water. Remove contaminated clothing and shoes. Get medical aid if
symptoms occur. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid breathing dust.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 101-54-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: purple - gray brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 354 deg C @ 760 mm Hg
Freezing/Melting Point: 73 - 78 deg C
Autoignition Temperature: > 500 deg C (> 932.00 deg F)
Flash Point: > 250 deg C (> 482.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density:
Molecular Formula: C12H12N2
Molecular Weight: 184.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 101-54-2: ST3150000
LD50/LC50:
CAS# 101-54-2: Draize test, rabbit, eye: 100 mg/24H Moderate; Oral,
mouse: LD50 = 244 mg/kg; Oral, rabbit: LD50 = >5 gm/kg; Oral, rat:
LD50 = 464 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
Found to be a moderate skin sensitizer in a study with guinea pigs in
all animals tested.
Carcinogenicity:
N-Phenyl-1,4-phenylenediamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 0.26-0.33 mg/L; 5,15,30
Minutes; Microtox test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 101-54-2: 3
Canada
CAS# 101-54-2 is listed on Canada's DSL List.
CAS# 101-54-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 101-54-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/04/1999 Revision #3 Date: 10/10/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Ligroine (O3386)
| 110-54-3 |
|
Saturated Phenol, pH 6.6/7.9
| 77-86-1 |
|
Saturated Phenol, pH 4.3/4.5
| 108-95-2 |
|
Phenol/Chloroform/Isoamyl Alcohol, pH 4.3
| 67-66-3 |
|
Phenol/Chloroform/Isoamyl Alcohol (pH5.2)
| 67-66-3 |
|
Tris 1 Molar Buffer
| 77-86-1 |
|
Tris 2 Molar Buffer
| 77-86-1 |
|
4-Chloro-alpha-methylstyrene, 96% (GC)
| 1712-70-5 |
|
1,9-Diphenyl-1,3,6,8-nonatetraen-5-one, 98% (uv-vis)
| 622-21-9 |
|
4-Methoxystilbene, 98+%
| 1142-15-0 |
|
Phenoxy resin, average m.w. 85000
| 26402-79-9 |
|
2,3,5-Trimethylanisole, 99%
| 20469-61-8 |
|
4-Methoxybenzylamine, 98%
| 2393-23-9 |
|
4-Nitrophenyl phosphate tris buffer salt, 98% (titr.)
| 52435-04-8 |
|
Picrotoxin, 99%
| 124-87-8 |
|
4-Nitrocatechol, 97%
| 3316-09-4 |
|
Dipentylphthalate, 99%
| 131-18-0 |
|
Ammonium hexachlororuthenate(iv), 99%
| 18746-63-9 |
|
2-Hydroxy-5-Methoxybenzaldehyde, 98%
| 672-13-9 |
|
N-(2-acetamidophenethyl)-1-hydroxy-2-naphthamide
| 5254-41-1 |
|
Anthrone, reagent acs
| 90-44-8 |
|
(-)-cis-Myrtanylamine, 98%
| 38235-68-6 |
|
Tetrakis-(Triphenylphosphine)-Palladium(0), 99%
| 14221-01-3 |
|
N-Phenyl-p-phenylenediamine, 98%
| 101-54-2 |
|
2-Chlorophenothiazine, 97% Contains 3% Mineral Oil
| 92-39-7 |
|
n-Glycyl-l-tyrosine, hydrate, 97%
| 658-79-7 |
|
3,5-Dimethoxybenzoic Acid, 99%
| 1132-21-4 |
|
3-Chlorobenzotrifluoride, 98%
| 98-15-7 |
|
2-Bromo-4'-Phenylacetophenone, Tech.
| 135-73-9 |
|
4-tert-Butyltoluene
| 98-51-1 |
|
2,6-Diformyl-4-Methylphenol, 99%
| 7310-95-4 |
|
3-Acetoxy-2(1h)-pyridone
| 61296-14-8 |
|
N-Formylpiperidine, 99%
| 2591-86-8 |
|
1-Phenyl-1-cyclohexene, 97%
| 771-98-2 |
|
Glycine anhydride, 98%
| 106-57-0 |
|
4-Piperazinoacetophenone, 94%
| 51639-48-6 |
|
Purine, 99%
| 120-73-0 |
|
2,3-Naphthalenedicarboxylic Acid, 95%
| 2169-87-1 |
|
2-Butyl-2-Ethyl-1,3-Propanediol, 97%
| 115-84-4 |
|
4-(2-Iodoacetamido)-TEMPO, free radical
| 25713-24-0 |
|
4-Heptylbenzoyl Chloride, 99+% (Titr.)
| 50606-96-7 |
|
D-Glucosamine Hydrochloride, 98%
| 66-84-2 |
|
2-Amino-5-chlorobenzoic acid, 98%
| 634-95-7 |
|
Cyclopropyl-4-Methoxydiphenylcarbinol, 95%
| 0-00-1 |
|
6,9-Diamino-2-Ethoxyacridine Lactate, 95% (Titr.)
| 1837-57-6 |
|
2,3,5,6-Tetrabromo-4-Methylphenol, 98%
| 37721-75-8 |
|
3-Methylbenzothiazolium Iodide
| 2786-31-4 |
|
P-Tolunitrile, 98%
| 104-85-8 |
|
Trifluoromethanesulfonic Anhydride, 98%
| 358-23-6 |
|
1-Methyl-2-piperidinemethanol, 97+%
| 20845-34-5 |
|
|