**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 358-23-6 |Trifluoromethanesulfonic anhydride | 98% | 206-616-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Water-reactive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated.
Extinguishing Media:
Do NOT use water directly on fire. Use dry chemical, carbon dioxide,
or alcohol-resistant foam. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Do not expose spill to water. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin,
or on clothing. Do not allow contact with water. Use only in a
chemical fume hood. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Keep under a nitrogen blanket.
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep away from water. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use
adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 358-23-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless - light brown
Odor: None reported.
pH: Not available.
Vapor Pressure: 8 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 82 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.6770
Molecular Formula: C2 F6 O5 S2
Molecular Weight: 282.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents, acids, alcohols, moist air, or
water.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 358-23-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trifluoromethanesulfonic anhydride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 358-23-6: No information available.
Canada
CAS# 358-23-6 is listed on Canada's NDSL List.
CAS# 358-23-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 358-23-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ligroine (O3386)
| 110-54-3 |
|
Saturated Phenol, pH 6.6/7.9
| 77-86-1 |
|
Saturated Phenol, pH 4.3/4.5
| 108-95-2 |
|
Phenol/Chloroform/Isoamyl Alcohol, pH 4.3
| 67-66-3 |
|
Phenol/Chloroform/Isoamyl Alcohol (pH5.2)
| 67-66-3 |
|
Tris 1 Molar Buffer
| 77-86-1 |
|
Tris 2 Molar Buffer
| 77-86-1 |
|
4-Chloro-alpha-methylstyrene, 96% (GC)
| 1712-70-5 |
|
1,9-Diphenyl-1,3,6,8-nonatetraen-5-one, 98% (uv-vis)
| 622-21-9 |
|
4-Methoxystilbene, 98+%
| 1142-15-0 |
|
Phenoxy resin, average m.w. 85000
| 26402-79-9 |
|
2,3,5-Trimethylanisole, 99%
| 20469-61-8 |
|
4-Methoxybenzylamine, 98%
| 2393-23-9 |
|
4-Nitrophenyl phosphate tris buffer salt, 98% (titr.)
| 52435-04-8 |
|
Picrotoxin, 99%
| 124-87-8 |
|
4-Nitrocatechol, 97%
| 3316-09-4 |
|
Dipentylphthalate, 99%
| 131-18-0 |
|
Ammonium hexachlororuthenate(iv), 99%
| 18746-63-9 |
|
2-Hydroxy-5-Methoxybenzaldehyde, 98%
| 672-13-9 |
|
N-(2-acetamidophenethyl)-1-hydroxy-2-naphthamide
| 5254-41-1 |
|
Anthrone, reagent acs
| 90-44-8 |
|
(-)-cis-Myrtanylamine, 98%
| 38235-68-6 |
|
Tetrakis-(Triphenylphosphine)-Palladium(0), 99%
| 14221-01-3 |
|
N-Phenyl-p-phenylenediamine, 98%
| 101-54-2 |
|
2-Chlorophenothiazine, 97% Contains 3% Mineral Oil
| 92-39-7 |
|
n-Glycyl-l-tyrosine, hydrate, 97%
| 658-79-7 |
|
3,5-Dimethoxybenzoic Acid, 99%
| 1132-21-4 |
|
3-Chlorobenzotrifluoride, 98%
| 98-15-7 |
|
2-Bromo-4'-Phenylacetophenone, Tech.
| 135-73-9 |
|
4-tert-Butyltoluene
| 98-51-1 |
|
2,6-Diformyl-4-Methylphenol, 99%
| 7310-95-4 |
|
3-Acetoxy-2(1h)-pyridone
| 61296-14-8 |
|
N-Formylpiperidine, 99%
| 2591-86-8 |
|
1-Phenyl-1-cyclohexene, 97%
| 771-98-2 |
|
Glycine anhydride, 98%
| 106-57-0 |
|
4-Piperazinoacetophenone, 94%
| 51639-48-6 |
|
Purine, 99%
| 120-73-0 |
|
2,3-Naphthalenedicarboxylic Acid, 95%
| 2169-87-1 |
|
2-Butyl-2-Ethyl-1,3-Propanediol, 97%
| 115-84-4 |
|
4-(2-Iodoacetamido)-TEMPO, free radical
| 25713-24-0 |
|
4-Heptylbenzoyl Chloride, 99+% (Titr.)
| 50606-96-7 |
|
D-Glucosamine Hydrochloride, 98%
| 66-84-2 |
|
2-Amino-5-chlorobenzoic acid, 98%
| 634-95-7 |
|
Cyclopropyl-4-Methoxydiphenylcarbinol, 95%
| 0-00-1 |
|
6,9-Diamino-2-Ethoxyacridine Lactate, 95% (Titr.)
| 1837-57-6 |
|
2,3,5,6-Tetrabromo-4-Methylphenol, 98%
| 37721-75-8 |
|
3-Methylbenzothiazolium Iodide
| 2786-31-4 |
|
P-Tolunitrile, 98%
| 104-85-8 |
|
Trifluoromethanesulfonic Anhydride, 98%
| 358-23-6 |
|
1-Methyl-2-piperidinemethanol, 97+%
| 20845-34-5 |
|
|