**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 101-84-8 |Phenyl ether | 99.0 | 202-981-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause
irritation and/or dermatitis.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage.
Inhalation:
Causes respiratory tract irritation.
Chronic:
May cause liver and kidney damage. Prolonged or repeated exposure
may cause thyroid damage. Repeated exposure may cause damage to the
spleen.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Avoid contact with eyes, skin, and clothing.
Avoid ingestion and inhalation.
Storage:
Keep away from heat and flame. Keep container closed when not in
use. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 101-84-8:
United Kingdom, WEL - TWA: 1 ppm TWA (vapor); 7.1 mg/m3 TWA (vapo
United Kingdom, WEL - STEL: 3 ppm STEL (vapor); 21.3 mg/m3 STEL
(vapor)
United States OSHA: 1 ppm TWA (vapor); 7 mg/m3 TWA (vapor)
Belgium - TWA: 1 ppm VLE (vapor); 7 mg/m3 VLE (vapor)
Belgium - STEL: 2 ppm VLE (vapor); 14 mg/m3 VLE (vapor)
France - VME: 1 ppm VME; 7 mg/m3 VME
Germany: 1 ppm TWA (steam); 7.1 mg/m3 TWA (steam)
Russia: 5 mg/m3 TWA (vapour)
Spain: 1 ppm VLA-ED (vapor); 7.1 mg/m3 VLA-ED (vapor)
Spain: 2 ppm VLA-EC (vapor); 14.2 mg/m3 VLA-EC (vapor)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Geranium odor.
pH: Not available.
Vapor Pressure: < 1 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 257 deg C
Freezing/Melting Point: 28 deg C
Autoignition Temperature: 1148 deg F ( 620.00 deg C)
Flash Point: 239 deg F ( 115.00 deg C)
Explosion Limits, lower: 1.5%
Explosion Limits, upper: 0.8%
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.073
Molecular Formula: C12H10O
Molecular Weight: 170.0694
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 101-84-8: KN8970000
LD50/LC50:
CAS# 101-84-8: Draize test, rabbit, eye: 10 ppm/140H; Draize test,
rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 2450 mg/kg; Oral,
rat: LD50 = 4000 mg/kg; Skin, rabbit: LD50 = >7940 mg/kg.
Carcinogenicity:
Phenyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 4.0 mg/L; 96 hr.; flow-through bioassay
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 101-84-8: 2
Canada
CAS# 101-84-8 is listed on Canada's DSL List.
CAS# 101-84-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 101-84-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/24/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Di-tert-butyl dicarbonate, 97%
| 24424-99-5 |
|
Ethyl 3-Ethoxyacrylate 99%
| 1001-26-9 |
|
p-Toluenesulfonic acid monohydrate, 99%
| 6192-52-5 |
|
p-Toluenesulfonic acid monohydrate, 99% (titr.)
| 6192-52-5 |
|
1-Methylbenzimidazole-2-sulfonic acid, 99%
| 5533-38-0 |
|
2,3-Dimethylphenol, 99%
| 526-75-0 |
|
4-Quaterphenyl
| 135-70-6 |
|
4-Quaterphenyl, scintillation grade
| 135-70-6 |
|
Iodoform, 99+%
| 75-47-8 |
|
Phthalic acid, 99%
| 88-99-3 |
|
2-Methylnaphthalene, 95-97%
| 91-57-6 |
|
Cyclopropyl Phenyl Sulfide, 98%
| 14633-54-6 |
|
1-Butanethiol
| 109-79-5 |
|
Cesium Hydroxide, 99%, 50 wt% Solution In Water
| 7732-18-5 |
|
N-Acetylsulfanilyl Chloride, 99% (Titr.)
| 121-60-8 |
|
Linoleic acid, 99% (gc)
| 60-33-3 |
|
Cacodylic acid, sodium salt hydrate, 98%
| 6131-99-3 |
|
5-Fluorescein Isothiocyanate, Isomer I 90% (UV-VIS)
| 3326-32-7 |
|
7-Hydroxy-4-Methylcoumarin, 97%
| 90-33-5 |
|
Tin (II) Chloride Dihydrate, 97%
| 10025-69-1 |
|
Tin (II) Chloride Dihydrate, Reagent ACS (Crystals)
| 10025-69-1 |
|
Phenylacetaldehyde, 80-90% (GC)
| 122-78-1 |
|
Butyraldehyde, 99%
| 123-72-8 |
|
2-(Dimethylamino)ethyl methacrylate, 99%, stabilized with 0.2% MEHQ
| 150-76-5 |
|
Poly(vinyl alcohol), 88% Hydrolyzed Average M.W. 22000
| 9002-89-5 |
|
Poly(Vinyl Alcohol), 75% Hydrolyzed
| 9002-89-5 |
|
Poly(vinyl alcohol), 95% Hydrolyzed Average M.W.95.000
| 9002-89-5 |
|
Poly(vinyl alcohol), 98% Hydrolyzed
| 9002-89-5 |
|
Poly(vinyl alcohol), 99-100% Hydrolyzed
| 9002-89-5 |
|
1-Methoxynaphthalene, 98+%
| 2216-69-5 |
|
Calcium formate, 98% (titr.)
| 544-17-2 |
|
Poly(butadiene), 98% cis, average m.w. 2- 300.000
| 9003-17-2 |
|
Polybutadiene (m.n. 5000)
| 9003-17-2 |
|
Dichloroisocyanuric acid, sodium salt
| 2893-78-9 |
|
4,7-Dichloroquinoline, 99%
| 86-98-6 |
|
n-Methyl-4-nitroaniline, 97%
| 100-15-2 |
|
Geranyl linalool, tech.,ca.95%, mixture of isomers
| 1113-21-9 |
|
2-Bromonaphthalene, 99% (GC)
| 580-13-2 |
|
Azobenzene, 95%
| 103-33-3 |
|
2-Fluorobenzoic Acid, 99%
| 445-29-4 |
|
Reinecke salt, p.a.
| 13573-16-5 |
|
2-Isobutyl-3-methoxypyrazine, tech., 80% (cont. 20%
| |
|
1-Bromoundecane, 99%
| 693-67-4 |
|
Isobutyric Acid, 99+%
| 79-31-2 |
|
P-Toluenesulfonamide, 98%
| 70-55-3 |
|
Methyl formate, 97%
| 107-31-3 |
|
2-(4-Methylphenyl)malondialdehyde, 95+% (nmr)
| 27956-35-0 |
|
Zinc Iodide, 98+%
| 10139-47-6 |
|
2',7'-Dichlorofluorescein
| 76-54-0 |
|
Phenyl ether, 99%
| 101-84-8 |
|
|