**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-47-8 |Iodoform | 99+ | 200-874-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May be absorbed through the skin. May cause dermatitis.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam. Use
agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 75-47-8:
United Kingdom, WEL - TWA: 0.6 ppm TWA; 9.8 mg/m3 TWA
United Kingdom, WEL - STEL: 1 ppm STEL; 16 mg/m3 STEL
Belgium - TWA: 0.6 ppm VLE; 10 mg/m3 VLE
France - VME: 0.6 ppm VME; 10 mg/m3 VME
Germany: 3 mg/m3 TWA
Malaysia: 0.6 ppm TWA; 10 mg/m3 TWA
Netherlands: 0.2 ppm MAC; 3 mg/m3 MAC
Spain: 0.6 ppm VLA-ED; 9.8 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: yellow
Odor: pungent odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 120.00 - 123.00 deg C
Autoignition Temperature: Not available.
Flash Point: 204 deg C ( 399.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 204 deg C
Solubility in water: Slightly soluble.
Specific Gravity/Density: 4.0080g/cm3
Molecular Formula: CHI3
Molecular Weight: 393.72
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, temperatures above 200C,
strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, alkali metals, magnesium,
lithium, acetone, silver nitrate, mercuric oxide, calomel, tannin,
balsam peru.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen iodide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-47-8: PB7000000
LD50/LC50:
CAS# 75-47-8: Inhalation, rat: LC50 = 165 ppm/7H; Inhalation, rat:
LC50 = 183 ppm/7H; Oral, mouse: LD50 = 470 mg/kg; Oral, rabbit: LD50
= 450 mg/kg; Oral, rat: LD50 = 355 mg/kg; Skin, rat: LD50 = 1184
mg/kg.
Carcinogenicity:
Iodoform -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50=2.92mg/l; 96 hour; Flow through
bioassay@25.1CWater hardness 42.2mg/l CaCO3, pH 7.7
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 75-47-8: No information available.
Canada
CAS# 75-47-8 is listed on Canada's DSL List.
CAS# 75-47-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-47-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/29/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Di-tert-butyl dicarbonate, 97%
| 24424-99-5 |
|
Ethyl 3-Ethoxyacrylate 99%
| 1001-26-9 |
|
p-Toluenesulfonic acid monohydrate, 99%
| 6192-52-5 |
|
p-Toluenesulfonic acid monohydrate, 99% (titr.)
| 6192-52-5 |
|
1-Methylbenzimidazole-2-sulfonic acid, 99%
| 5533-38-0 |
|
2,3-Dimethylphenol, 99%
| 526-75-0 |
|
4-Quaterphenyl
| 135-70-6 |
|
4-Quaterphenyl, scintillation grade
| 135-70-6 |
|
Iodoform, 99+%
| 75-47-8 |
|
Phthalic acid, 99%
| 88-99-3 |
|
2-Methylnaphthalene, 95-97%
| 91-57-6 |
|
Cyclopropyl Phenyl Sulfide, 98%
| 14633-54-6 |
|
1-Butanethiol
| 109-79-5 |
|
Cesium Hydroxide, 99%, 50 wt% Solution In Water
| 7732-18-5 |
|
N-Acetylsulfanilyl Chloride, 99% (Titr.)
| 121-60-8 |
|
Linoleic acid, 99% (gc)
| 60-33-3 |
|
Cacodylic acid, sodium salt hydrate, 98%
| 6131-99-3 |
|
5-Fluorescein Isothiocyanate, Isomer I 90% (UV-VIS)
| 3326-32-7 |
|
7-Hydroxy-4-Methylcoumarin, 97%
| 90-33-5 |
|
Tin (II) Chloride Dihydrate, 97%
| 10025-69-1 |
|
Tin (II) Chloride Dihydrate, Reagent ACS (Crystals)
| 10025-69-1 |
|
Phenylacetaldehyde, 80-90% (GC)
| 122-78-1 |
|
Butyraldehyde, 99%
| 123-72-8 |
|
2-(Dimethylamino)ethyl methacrylate, 99%, stabilized with 0.2% MEHQ
| 150-76-5 |
|
Poly(vinyl alcohol), 88% Hydrolyzed Average M.W. 22000
| 9002-89-5 |
|
Poly(Vinyl Alcohol), 75% Hydrolyzed
| 9002-89-5 |
|
Poly(vinyl alcohol), 95% Hydrolyzed Average M.W.95.000
| 9002-89-5 |
|
Poly(vinyl alcohol), 98% Hydrolyzed
| 9002-89-5 |
|
Poly(vinyl alcohol), 99-100% Hydrolyzed
| 9002-89-5 |
|
1-Methoxynaphthalene, 98+%
| 2216-69-5 |
|
Calcium formate, 98% (titr.)
| 544-17-2 |
|
Poly(butadiene), 98% cis, average m.w. 2- 300.000
| 9003-17-2 |
|
Polybutadiene (m.n. 5000)
| 9003-17-2 |
|
Dichloroisocyanuric acid, sodium salt
| 2893-78-9 |
|
4,7-Dichloroquinoline, 99%
| 86-98-6 |
|
n-Methyl-4-nitroaniline, 97%
| 100-15-2 |
|
Geranyl linalool, tech.,ca.95%, mixture of isomers
| 1113-21-9 |
|
2-Bromonaphthalene, 99% (GC)
| 580-13-2 |
|
Azobenzene, 95%
| 103-33-3 |
|
2-Fluorobenzoic Acid, 99%
| 445-29-4 |
|
Reinecke salt, p.a.
| 13573-16-5 |
|
2-Isobutyl-3-methoxypyrazine, tech., 80% (cont. 20%
| |
|
1-Bromoundecane, 99%
| 693-67-4 |
|
Isobutyric Acid, 99+%
| 79-31-2 |
|
P-Toluenesulfonamide, 98%
| 70-55-3 |
|
Methyl formate, 97%
| 107-31-3 |
|
2-(4-Methylphenyl)malondialdehyde, 95+% (nmr)
| 27956-35-0 |
|
Zinc Iodide, 98+%
| 10139-47-6 |
|
2',7'-Dichlorofluorescein
| 76-54-0 |
|
Phenyl ether, 99%
| 101-84-8 |
|
|