**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2893-78-9 |Dichloroisocyanuric acid, sodium salt | >96 | 220-767-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN O N
Risk Phrases: 22 31 36/37 8 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Contact with acids liberates toxic gas.
Irritating to eyes and respiratory system. Contact with combustible
material may cause fire. Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.Moisture
sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which
increases the flow of tears).
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Systemic effects by ingestion include ulceration or bleeding from the
stomach. Other effects include tearing, dyspnea (labored breathing),
weakness, emaciation, diarrhea, and coma.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Avoid contact with clothing and other combustible
materials. Avoid ingestion and inhalation.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 2893-78-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Granules
Color: white
Odor: chlorine-like
pH: 60-7.0, 1% aq. sol.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 230 deg C ( 446.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 230 deg C
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C3Cl2N3O3Na
Molecular Weight: 219.95
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Reducing agents, strong bases, acids.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2893-78-9: XZ1900000
LD50/LC50:
CAS# 2893-78-9: Draize test, rabbit, eye: 100 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Draize test, rabbit, skin: 500
mg Severe; Oral, rat: LD50 = 1420 mg/kg.
Carcinogenicity:
Dichloroisocyanuric acid, sodium salt -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DICHLOROISOCYANURIC ACID, SALTS
Hazard Class: 5.1
UN Number: 2465
Packing Group: II
IMO
Shipping Name: DICHLOROISOCYANURIC ACID SALTS
Hazard Class: 5.1
UN Number: 2465
Packing Group: II
RID/ADR
Shipping Name: DICHLOROISOCYANURIC ACID SALTS
Hazard Class: 5.1
UN Number: 2465
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O N
Risk Phrases:
R 22 Harmful if swallowed.
R 31 Contact with acids liberates toxic gas.
R 36/37 Irritating to eyes and respiratory system.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 8 Keep container dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 41 In case of fire and/or explosion do not breathe
fumes.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 2893-78-9: 2
Canada
CAS# 2893-78-9 is listed on Canada's DSL List.
CAS# 2893-78-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2893-78-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #7 Date: 12/03/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| 10025-69-1 |
|
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| 123-72-8 |
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| 150-76-5 |
|
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| 9002-89-5 |
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Poly(Vinyl Alcohol), 75% Hydrolyzed
| 9002-89-5 |
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Poly(vinyl alcohol), 95% Hydrolyzed Average M.W.95.000
| 9002-89-5 |
|
Poly(vinyl alcohol), 98% Hydrolyzed
| 9002-89-5 |
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Poly(vinyl alcohol), 99-100% Hydrolyzed
| 9002-89-5 |
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| 2216-69-5 |
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| 544-17-2 |
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n-Methyl-4-nitroaniline, 97%
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|
2-Bromonaphthalene, 99% (GC)
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|
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|
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| 445-29-4 |
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Reinecke salt, p.a.
| 13573-16-5 |
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2-Isobutyl-3-methoxypyrazine, tech., 80% (cont. 20%
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|
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| 79-31-2 |
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| 70-55-3 |
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| 107-31-3 |
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| 27956-35-0 |
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| 10139-47-6 |
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| 101-84-8 |
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