**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 150-76-5 |4-Methoxyphenol | 0.2 | 205-769-8 |
|----------------|--------------------------------------|----------|-----------|
| 2867-47-2 |2-(Dimethylamino)ethyl methacrylate | 98 | 220-688-8 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | <0.1 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 21/22 36/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Irritating to eyes
and skin. May cause sensitization by skin contact.Moisture
sensitive.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed. Repeated or prolonged exposure may cause
allergic reactions in sensitive individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Use
with adequate ventilation. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 150-76-5:
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Germany: 5 mg/m3 TWA
Malaysia: 5 mg/m3 TWA
Netherlands: 5 mg/m3 MAC
Spain: 5 mg/m3 VLA-ED
CAS# 2867-47-2:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to almost colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 13.3 mbar @ 75
Viscosity: 1.6 MPA 20 deg C
Boiling Point: 182 - 192 deg C
Freezing/Melting Point: -30 deg C
Autoignition Temperature: 255 deg C ( 491.00 deg F)
Flash Point: 70 deg C ( 158.00 deg F)
Explosion Limits, lower: 1.20 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: .9300g/cm3
Molecular Formula: C8H15NO2
Molecular Weight: 157.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable only if stored and handled under recommended conditions. The
stability of the product depends upon the availability of both
dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of
oxygen is necessary for the MEHQ to function effectively. The
product should never be stored under an inert gas atmosphere, but
should always be stored under an atmosphere containing 5-21% oxygen
by volume.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, loss of
inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 150-76-5: SL7700000
CAS# 2867-47-2: OZ4200000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent)
Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 2867-47-2: Inhalation, mouse: LC50 = 1800 mg/m3/2H; Inhalation,
rat: LC50 = 620 mg/m3/4H; Oral, rat: LD50 = 1751 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
4-Methoxyphenol -
Not listed by ACGIH, IARC, or NTP.
2-(Dimethylamino)ethyl methacrylate -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 2-DIMETHYLAMINOETHYL METHACRYLATE
Hazard Class: 6.1
UN Number: 2522
Packing Group: II
IMO
Shipping Name: 2-DIMETHYLAMINOETHYL METHACRYLATE
Hazard Class: 6.1
UN Number: 2522
Packing Group: II
RID/ADR
Shipping Name: 2-DIMETHYLAMINOETHYL METHACRYLATE
Hazard Class: 6.1
UN Number: 2522
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 150-76-5: 1
CAS# 2867-47-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 2867-47-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
CAS# 2867-47-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 150-76-5 is listed on the TSCA inventory.
CAS# 2867-47-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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