**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 104-78-9 |3-Diethylaminopropylamine | 99 | 203-236-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 21/22 34 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin and if swallowed. Causes
burns. May cause sensitization by skin contact.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Harmful if absorbed through the skin. May cause severe irritation
and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Flammable
liquid and vapor. Vapors from liquefied gas are initially heavier
than air and spread along ground.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Do not get in eyes, on
skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Do not ingest or inhale.
Discard contaminated shoes. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 104-78-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 2.5 hPa @ 20.0
Viscosity: 1.3 mPas 20 deg C
Boiling Point: 159 deg C @ 760.00mm Hg
Freezing/Melting Point: -60 deg C
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 53 deg C ( 127.40 deg F)
Explosion Limits, lower: 1.40 vol %
Explosion Limits, upper: 11.60 vol %
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: .8260g/cm3
Molecular Formula: C7H18N2
Molecular Weight: 130.23
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Acid chlorides, carbon dioxide, acid anhydrides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 104-78-9: TX7350000
LD50/LC50:
CAS# 104-78-9: Oral, mouse: LD50 = 425 mg/kg; Oral, rat: LD50 = 550
mg/kg; Skin, rabbit: LD50 = 750 uL/kg.
Carcinogenicity:
3-Diethylaminopropylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIETHYLAMINOPROPYLAMINE
Hazard Class: 3 (8)
UN Number: 2684
Packing Group: III
IMO
Shipping Name: 3-(DIETHYLAMINO)PROPYLAMINE
Hazard Class: 3.3 (8)
UN Number: 2684
Packing Group: III
RID/ADR
Shipping Name: DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN Number: 2684
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 104-78-9: 1
Canada
CAS# 104-78-9 is listed on Canada's DSL List.
CAS# 104-78-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-78-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/26/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(2r,3r)-(+)-2,3-epoxybutan, 97%
| 1758-32-3 |
|
3-Aminopyridine, 99%
| 462-08-8 |
|
2-Amino-6-Hydroxy-8-Mercaptopurine, 97%
| 28128-40-7 |
|
n-Octyl-tetraoxyethylene, 94%
| 19327-39-0 |
|
Ethyl Fluoroacetate, 97%
| 459-72-3 |
|
d-(-)Arginine hydrochloride
| 627-75-8 |
|
1,2-Dibromo-1,2-diphenylethane, 96%
| 5789-30-0 |
|
Chromotrope 2R
| 4197-07-3 |
|
Gluconic acid, potassium salt, 99%
| 299-27-4 |
|
Thioxanthen-9-One, 98%
| 492-22-8 |
|
2-Hydroxyethyl methacrylate, stabilized with 200-700 ppm MEHQ
| 150-76-5 |
|
Poly(ethylene), high density, average m.w. 125000
| 9002-88-4 |
|
4-Tert.-Amylcyclohexanone, 98+%
| 16587-71-6 |
|
1,8-Dibromooctane, 98%
| 4549-32-0 |
|
Methyl nicotinoylacetate
| 54950-20-8 |
|
3-Ethyl-3-pentanol, 98%
| 597-49-9 |
|
Polysulfone Resin, Sec. Stand., Typical M. W. 67000, Typical M.N.
| 25135-51-7 |
|
1,6-Diisocyanatohexane, 99+% (GC)
| 822-06-0 |
|
3,5-Dimethylthiophenol, 98%
| 38360-81-5 |
|
Indium atomic absorption standard solution, 1 mg/ml In in 2% HNO3
| 7440-74-6 |
|
4-Carboxy-2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl, free
| |
|
Lidoflazine, 98.5%
| 3416-26-0 |
|
N-(3-Aminopropyl)Methacrylamide Hydro-chloride, 99% (Titr.)
| 72607-53-5 |
|
o-Nitrophenyl-beta-D-galactopyranoside, 99+%
| 369-07-3 |
|
2-Benzylaminopyridine, 98%
| 6935-27-9 |
|
Tribromoacetic Acid, 99%
| 75-96-7 |
|
4-Chlorophenol, 99+%
| 106-48-9 |
|
3-Diethylaminopropylamine, 99+%
| 104-78-9 |
|
2,3-Diphenyl-1-Indenone, 97%
| 1801-42-9 |
|
4-Benzoylpiperidine hydrochloride,98%
| 72034-25-4 |
|
2,6-Dimethylanisole, 98.5%
| 1004-66-6 |
|
Xanthen-9-one
| 90-47-1 |
|
(-)-Carveol 98%, mixture of isomers
| 99-48-9 |
|
Isethionic acid, sodium salt, 98%
| 1562-00-1 |
|
Ethyl Caproate, 99+%
| 123-66-0 |
|
Phenyl Chlorothioformate, 98% (Titr.)
| 13464-19-2 |
|
Ethyl Sulfide, 98%
| 352-93-2 |
|
Poly(2-Acrylamido-2-Methyl-1-Propanesulfonic Acid), 10 Wt% Solution
| 7732-18-5 |
|
4-Aminophenylmercuric Acetate, Tech.
| 6283-24-5 |
|
Dimethyl adipate
| 627-93-0 |
|
Triphenylene, 98%
| 217-59-4 |
|
Niobium (V) Chloride, 99.8%
| 10026-12-7 |
|
Sym.-Diformylhydrazine, 97%
| 628-36-4 |
|
Copper Phthalocyanine Tetrasulfonic Acid Tetrasodium Salt, 60%
| 27360-85-6 |
|
(4R,5R)-4,5-Di(Dimethylaminocarbonyl)-2,2-Dimethyldioxolane, 99+%
| 63126-29-4 |
|
Iron (iii) citrate hydrate
| 17217-76-4 |
|
Naphthochrome Green
| 5715-76-4 |
|
Acetylenedicarboxylic acid, monopotassium salt, 98+ %
| 928-04-1 |
|
2-(4-Iodophenyl)-3-(4-nitrophenyl)-5- phenyltetrazolium chloride
| 146-68-9 |
|
2,2'-Dithiobis(1-aminonaphthalene), (dtan)
| 38262-57-6 |
|
|