**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 150-76-5 |4-Methoxyphenol | <.07 | 205-769-8 |
|----------------|--------------------------------------|----------|-----------|
| 868-77-9 |2-Hydroxyethyl methacrylate | >96 | 212-782-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin. May cause sensitization by skin
contact.Light sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful
amounts. May cause skin sensitization, an allergic reaction, which
becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
May cause reproductive and fetal effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Fire or
excessive heat may result in violent rupture of the container due to
bulk polymerization.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid breathing vapor or mist. Pure vapor
will be uninhibited and may polymerize in vents or other confined
spaces.
Storage:
Store in a cool place in the original container and protect from
sunlight. Keep refrigerated. (Store below 4C/39F.) Store in a
tightly closed container. Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 150-76-5:
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Germany: 5 mg/m3 TWA
Malaysia: 5 mg/m3 TWA
Netherlands: 5 mg/m3 MAC
Spain: 5 mg/m3 VLA-ED
CAS# 868-77-9:
Netherlands: 0.05 ppm MAC; 0.24 mg/m3 MAC
Russia: 20 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.01 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 205-208 deg C
Freezing/Melting Point: -12 deg C
Autoignition Temperature: Not applicable.
Flash Point: 101 deg C ( 213.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Miscible with water.
Specific Gravity/Density: 1.073
Molecular Formula: C6H10O3
Molecular Weight: 130.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable only if stored and handled under recommended conditions. The
stability of the product depends upon the availability of both
dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of
oxygen is necessary for the MEHQ to function effectively. The
product should never be stored under an inert gas atmosphere, but
should always be stored under an atmosphere containing 5-21% oxygen
by volume.
Conditions to Avoid:
Light, excess heat, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 150-76-5: SL7700000
CAS# 868-77-9: OZ4725000
LD50/LC50:
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent)
Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 868-77-9: Oral, mouse: LD50 = 3275 mg/kg; Oral, rat: LD50 =
5050 mg/kg.
Carcinogenicity:
4-Methoxyphenol -
Not listed by ACGIH, IARC, or NTP.
2-Hydroxyethyl methacrylate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 150-76-5: 1
CAS# 868-77-9: 1
Canada
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 868-77-9 is listed on Canada's DSL List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
CAS# 868-77-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 150-76-5 is listed on the TSCA inventory.
CAS# 868-77-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/17/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(2r,3r)-(+)-2,3-epoxybutan, 97%
| 1758-32-3 |
|
3-Aminopyridine, 99%
| 462-08-8 |
|
2-Amino-6-Hydroxy-8-Mercaptopurine, 97%
| 28128-40-7 |
|
n-Octyl-tetraoxyethylene, 94%
| 19327-39-0 |
|
Ethyl Fluoroacetate, 97%
| 459-72-3 |
|
d-(-)Arginine hydrochloride
| 627-75-8 |
|
1,2-Dibromo-1,2-diphenylethane, 96%
| 5789-30-0 |
|
Chromotrope 2R
| 4197-07-3 |
|
Gluconic acid, potassium salt, 99%
| 299-27-4 |
|
Thioxanthen-9-One, 98%
| 492-22-8 |
|
2-Hydroxyethyl methacrylate, stabilized with 200-700 ppm MEHQ
| 150-76-5 |
|
Poly(ethylene), high density, average m.w. 125000
| 9002-88-4 |
|
4-Tert.-Amylcyclohexanone, 98+%
| 16587-71-6 |
|
1,8-Dibromooctane, 98%
| 4549-32-0 |
|
Methyl nicotinoylacetate
| 54950-20-8 |
|
3-Ethyl-3-pentanol, 98%
| 597-49-9 |
|
Polysulfone Resin, Sec. Stand., Typical M. W. 67000, Typical M.N.
| 25135-51-7 |
|
1,6-Diisocyanatohexane, 99+% (GC)
| 822-06-0 |
|
3,5-Dimethylthiophenol, 98%
| 38360-81-5 |
|
Indium atomic absorption standard solution, 1 mg/ml In in 2% HNO3
| 7440-74-6 |
|
4-Carboxy-2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl, free
| |
|
Lidoflazine, 98.5%
| 3416-26-0 |
|
N-(3-Aminopropyl)Methacrylamide Hydro-chloride, 99% (Titr.)
| 72607-53-5 |
|
o-Nitrophenyl-beta-D-galactopyranoside, 99+%
| 369-07-3 |
|
2-Benzylaminopyridine, 98%
| 6935-27-9 |
|
Tribromoacetic Acid, 99%
| 75-96-7 |
|
4-Chlorophenol, 99+%
| 106-48-9 |
|
3-Diethylaminopropylamine, 99+%
| 104-78-9 |
|
2,3-Diphenyl-1-Indenone, 97%
| 1801-42-9 |
|
4-Benzoylpiperidine hydrochloride,98%
| 72034-25-4 |
|
2,6-Dimethylanisole, 98.5%
| 1004-66-6 |
|
Xanthen-9-one
| 90-47-1 |
|
(-)-Carveol 98%, mixture of isomers
| 99-48-9 |
|
Isethionic acid, sodium salt, 98%
| 1562-00-1 |
|
Ethyl Caproate, 99+%
| 123-66-0 |
|
Phenyl Chlorothioformate, 98% (Titr.)
| 13464-19-2 |
|
Ethyl Sulfide, 98%
| 352-93-2 |
|
Poly(2-Acrylamido-2-Methyl-1-Propanesulfonic Acid), 10 Wt% Solution
| 7732-18-5 |
|
4-Aminophenylmercuric Acetate, Tech.
| 6283-24-5 |
|
Dimethyl adipate
| 627-93-0 |
|
Triphenylene, 98%
| 217-59-4 |
|
Niobium (V) Chloride, 99.8%
| 10026-12-7 |
|
Sym.-Diformylhydrazine, 97%
| 628-36-4 |
|
Copper Phthalocyanine Tetrasulfonic Acid Tetrasodium Salt, 60%
| 27360-85-6 |
|
(4R,5R)-4,5-Di(Dimethylaminocarbonyl)-2,2-Dimethyldioxolane, 99+%
| 63126-29-4 |
|
Iron (iii) citrate hydrate
| 17217-76-4 |
|
Naphthochrome Green
| 5715-76-4 |
|
Acetylenedicarboxylic acid, monopotassium salt, 98+ %
| 928-04-1 |
|
2-(4-Iodophenyl)-3-(4-nitrophenyl)-5- phenyltetrazolium chloride
| 146-68-9 |
|
2,2'-Dithiobis(1-aminonaphthalene), (dtan)
| 38262-57-6 |
|
|