**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-41-2 |4-Bromophenol | 97.0 | 203-394-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Effects of contact may be delayed. The
toxicological properties of this material have not been fully
investigated.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Effects of
inhalation may be delayed.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 106-41-2:
Russia: 0.3 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 235 - 236 deg C @ 760.00mm Hg
Freezing/Melting Point: 64 - 68 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: freely soluble in alcohol, chloroform an
Specific Gravity/Density:
Molecular Formula: C6H5BrO
Molecular Weight: 173.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-41-2: SJ7960000
LD50/LC50:
CAS# 106-41-2: Oral, mouse: LD50 = 523 mg/kg.
Carcinogenicity:
4-Bromophenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 0.41-0.47 mg/L; 5,15,30
Minutes; Microtox test, 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 106-41-2: No information available.
Canada
CAS# 106-41-2 is listed on Canada's NDSL List.
CAS# 106-41-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-41-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/05/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lutetium, powder, ca. 40 mesh, 99.9%
| 7439-94-3 |
|
Platinum, foil, 0.025mm thick, 99.99%
| 7440-06-4 |
|
Platinum, powder, 0.8-2.2 micron, 99.9%
| 7440-06-4 |
|
Platinum, powder, 0.27-0.47 micron, 99.9%
| 7440-06-4 |
|
Scandium, Powder, -40 Mesh, 99.9+%
| 7440-20-2 |
|
Palladium foil, 99.9+%
| 7440-05-3 |
|
Bis(Pentamethylcyclopentadienyl)Ruthenium
| 84821-53-4 |
|
Phenylmagnesium bromide, 3m solution in diethyl ether
| 100-58-3 |
|
Isopropylmagnesium chloride, 2.0 m solutio n in diethyl ether
| 1068-55-9 |
|
Rhodium (III) Nitrate Solution, ca. 10% (wt/ wt) Rh in 20-25 wt% HNO3
| 7697-37-2 |
|
Allylmagnesium bromide, 1m solution in diethylether
| 60-29-7 |
|
Titanium diisopropoxide bis(2,4-pentanedionate), 75 wt% in 2-propanol
| 67-63-0 |
|
Osmium Tetroxide, 4 wt% Solution in Water
| 7732-18-5 |
|
Lithium Cyanide, 0.5M Solution in N,N-Dimethylformamide
| 2408-36-8 |
|
Methylmagnesium bromide, 3M solution in diethyl ether
| 75-16-1 |
|
8-Hydroxy-5-Nitroquinoline, 96%
| 4008-48-4 |
|
Ethylmagnesium bromide, 3m solution in diethyl ether
| 925-90-6 |
|
Polyepichlorohydrin, Average MW ca. 700.000 (GPC)
| 24969-06-0 |
|
(+/-)-2-Phenylcycloheptanone, 99%
| 14996-78-2 |
|
4'-Chloro-2,2':6',2''-Terpyridine, 99%
| 128143-89-5 |
|
(3,5-Dimethoxyphenyl)acetic acid, 98%
| 4670-10-4 |
|
2,4-Dimethylpyrrole, 97%
| 625-82-1 |
|
O-Eugenol, 98%
| 579-60-2 |
|
2-(Bromomethyl)-2-(Hydroxymethyl)-1,3-Propanediol, 99%
| 19184-65-7 |
|
4,4'-Dipyridyl N,N'-Dioxide Dihydrate, 98%
| |
|
2,2'-Dipyridyl N,N'-Dioxide, 98%
| 7275-43-6 |
|
Ethyl Thiooxamate, 95%
| 16982-21-1 |
|
2',4'-Dihydroxy-3'-Methylpropiophenone, 98 %
| 63876-46-0 |
|
Oleylamine, 97% primary amine-value approx . c18-content 80-90%
| 112-90-3 |
|
2-Hydroxy-4-Methyl-3-Nitropyridine, 98%
| 21901-18-8 |
|
2-Hydroxy-4-Methyl-5-Nitropyridine, 98%
| 21901-41-7 |
|
2-Amino-4-Methyl-5-Nitropyridine, 98%
| 21901-40-6 |
|
2-Amino-4-Methyl-3-Nitropyridine, 98%
| 6635-86-5 |
|
Tetrabutylammonium difluorotriphenyl stannate
| 139353-88-1 |
|
Triphenyltin fluoride
| 379-52-2 |
|
(4-Hydroxyphenyl)-2-Propionic Acid
| 938-96-5 |
|
D,l-1-aminoindane-1-carboxylic acid
| |
|
N-Boc-d,l-1-Aminoindane-1-Carboxylic Acid
| |
|
N-fmoc-d,l-1-aminoindane-1-carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydroisoquinoline-3-c arboxylic acid
| |
|
N-fmoc-d-1,2,3,4-tetrahydroisoquinoline-3- carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydro-beta-carboline- 3-carboxylic acid
| |
|
N-Boc-2-Aminoindane-2-Carboxylic Acid
| |
|
N-fmoc-d,l-2-aminotetralin-2-carboxylic acid
| |
|
2-Chloro-4-Hydroxybenzoic Acid Hydrate, 98 % (On the Dried Substance)
| 56363-84-9 |
|
Methyl stearate, mixture of homologs
| 112-39-0 |
|
4-Bromophenol, 97% (GC)
| 106-41-2 |
|
1,1,1,5,5,5-Hexafluoroacetylacetone, 96%
| 1522-22-1 |
|
Methylurea, 97%
| 598-50-5 |
|
2-Methylbutyraldehyde, 95%
| 96-17-3 |
|
|