**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 139353-88-1 |Tetrabutylammonium difluorotriphenyl s| 95 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/24/25 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Very
toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. Ingestion of large amounts of fluoride may
cause salivation, nausea, vomiting, abdominal pain, fever, labored
breathing. Exposure to fluoride compounds can result in systemic
toxic effects on the heart, liver, and kidneys. It may also deplete
calcium levels in the body leading to hypocalcemia and death.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Chronic exposure to fluoride compounds may cause systemic toxicity.
Exposure limits have been recommended for organotin compounds to
minimize the potential for adverse effects on immune function and the
CNS.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 139353-88-1:
United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1
mg/m3 TWA (except cyhexatin, as Sn)
United Kingdom, WEL - STEL: (listed as tin organic compounds): 0.
mg/m3 STEL (except cyhexatin, as Sn)
United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga
compounds).
Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE (
Sn)
Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE
Sn)
France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a
Sn)
France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a
Sn)
Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn)
Germany: (listed as tin organic compounds): Skin absorber
Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn
Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a
Sn)
Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as
Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn
Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: ammonia-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 187 - 193 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C34H51F2NSn
Molecular Weight: 630.48
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride
gas, tin/tin oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 139353-88-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetrabutylammonium difluorotriphenyl stannate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 139353-88-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 139353-88-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 139353-88-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #5 Date: 4/27/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lutetium, powder, ca. 40 mesh, 99.9%
| 7439-94-3 |
|
Platinum, foil, 0.025mm thick, 99.99%
| 7440-06-4 |
|
Platinum, powder, 0.8-2.2 micron, 99.9%
| 7440-06-4 |
|
Platinum, powder, 0.27-0.47 micron, 99.9%
| 7440-06-4 |
|
Scandium, Powder, -40 Mesh, 99.9+%
| 7440-20-2 |
|
Palladium foil, 99.9+%
| 7440-05-3 |
|
Bis(Pentamethylcyclopentadienyl)Ruthenium
| 84821-53-4 |
|
Phenylmagnesium bromide, 3m solution in diethyl ether
| 100-58-3 |
|
Isopropylmagnesium chloride, 2.0 m solutio n in diethyl ether
| 1068-55-9 |
|
Rhodium (III) Nitrate Solution, ca. 10% (wt/ wt) Rh in 20-25 wt% HNO3
| 7697-37-2 |
|
Allylmagnesium bromide, 1m solution in diethylether
| 60-29-7 |
|
Titanium diisopropoxide bis(2,4-pentanedionate), 75 wt% in 2-propanol
| 67-63-0 |
|
Osmium Tetroxide, 4 wt% Solution in Water
| 7732-18-5 |
|
Lithium Cyanide, 0.5M Solution in N,N-Dimethylformamide
| 2408-36-8 |
|
Methylmagnesium bromide, 3M solution in diethyl ether
| 75-16-1 |
|
8-Hydroxy-5-Nitroquinoline, 96%
| 4008-48-4 |
|
Ethylmagnesium bromide, 3m solution in diethyl ether
| 925-90-6 |
|
Polyepichlorohydrin, Average MW ca. 700.000 (GPC)
| 24969-06-0 |
|
(+/-)-2-Phenylcycloheptanone, 99%
| 14996-78-2 |
|
4'-Chloro-2,2':6',2''-Terpyridine, 99%
| 128143-89-5 |
|
(3,5-Dimethoxyphenyl)acetic acid, 98%
| 4670-10-4 |
|
2,4-Dimethylpyrrole, 97%
| 625-82-1 |
|
O-Eugenol, 98%
| 579-60-2 |
|
2-(Bromomethyl)-2-(Hydroxymethyl)-1,3-Propanediol, 99%
| 19184-65-7 |
|
4,4'-Dipyridyl N,N'-Dioxide Dihydrate, 98%
| |
|
2,2'-Dipyridyl N,N'-Dioxide, 98%
| 7275-43-6 |
|
Ethyl Thiooxamate, 95%
| 16982-21-1 |
|
2',4'-Dihydroxy-3'-Methylpropiophenone, 98 %
| 63876-46-0 |
|
Oleylamine, 97% primary amine-value approx . c18-content 80-90%
| 112-90-3 |
|
2-Hydroxy-4-Methyl-3-Nitropyridine, 98%
| 21901-18-8 |
|
2-Hydroxy-4-Methyl-5-Nitropyridine, 98%
| 21901-41-7 |
|
2-Amino-4-Methyl-5-Nitropyridine, 98%
| 21901-40-6 |
|
2-Amino-4-Methyl-3-Nitropyridine, 98%
| 6635-86-5 |
|
Tetrabutylammonium difluorotriphenyl stannate
| 139353-88-1 |
|
Triphenyltin fluoride
| 379-52-2 |
|
(4-Hydroxyphenyl)-2-Propionic Acid
| 938-96-5 |
|
D,l-1-aminoindane-1-carboxylic acid
| |
|
N-Boc-d,l-1-Aminoindane-1-Carboxylic Acid
| |
|
N-fmoc-d,l-1-aminoindane-1-carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydroisoquinoline-3-c arboxylic acid
| |
|
N-fmoc-d-1,2,3,4-tetrahydroisoquinoline-3- carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydro-beta-carboline- 3-carboxylic acid
| |
|
N-Boc-2-Aminoindane-2-Carboxylic Acid
| |
|
N-fmoc-d,l-2-aminotetralin-2-carboxylic acid
| |
|
2-Chloro-4-Hydroxybenzoic Acid Hydrate, 98 % (On the Dried Substance)
| 56363-84-9 |
|
Methyl stearate, mixture of homologs
| 112-39-0 |
|
4-Bromophenol, 97% (GC)
| 106-41-2 |
|
1,1,1,5,5,5-Hexafluoroacetylacetone, 96%
| 1522-22-1 |
|
Methylurea, 97%
| 598-50-5 |
|
2-Methylbutyraldehyde, 95%
| 96-17-3 |
|
|