**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7697-37-2 |Nitric acid | 20-25 | 231-714-2 |
|----------------|--------------------------------------|----------|-----------|
| 15492-38-3 |Rhodium (III) Nitrate Solution | Balance | 239-521-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: O C
Risk Phrases: 35 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes severe burns. Contact with combustible material may cause
fire.Corrosive.Oxidizer.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible. Oxidizer. Greatly increases the burning rate of
combustible materials. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Contact with metals may evolve flammable hydrogen gas. Containers
may explode when heated.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Do NOT get water inside containers. For
small fires, use dry chemical, carbon dioxide, or water spray. For
large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Discard contaminated
shoes. Keep away from strong bases and metals.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Do not store in metal containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7697-37-2:
United Kingdom, WEL - TWA: 2 ppm TWA; 5.2 mg/m3 TWA
United Kingdom, WEL - STEL: 4 ppm STEL; 10 mg/m3 STEL
United States OSHA: 2 ppm TWA; 5 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE
Belgium - STEL: 4 ppm VLE; 10 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 4 ppm VLE; 10 mg/m3 VLE
Germany: 2 ppm TWA; 5.2 mg/m3 TWA
Japan: 2 ppm OEL; 5.2 mg/m3 OEL
Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA
Netherlands: 0.5 ppm STEL; 1.3 mg/m3 STEL
Russia: 2 mg/m3 TWA
Spain: 2 ppm VLA-ED; 5.2 mg/m3 VLA-ED
Spain: 4 ppm VLA-EC; 10 mg/m3 VLA-EC
CAS# 15492-38-3:
United Kingdom, WEL - TWA: (listed as rhodium): 0.1 mg/m3 TWA (du
and fume)
United Kingdom, WEL - STEL: (listed as rhodium): 0.3 mg/m3 STEL (
and fume)
United States OSHA: 0.1 mg/m3 TWA (listed under Rhodium).
Belgium - TWA: (listed as rhodium): 1 mg/m3 VLE (dust)
France - VME: (listed as rhodium): 1 mg/m3 VME
Germany: (listed as rhodium): 1 mg/m3 VME
Malaysia: (listed as rhodium): 1 mg/m3 TWA
Netherlands: (listed as rhodium): 0.1 mg/m3 MAC (fume and dust, a
Rh)
Spain: (listed as rhodium): 1 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: N3O9Rh
Molecular Weight: 288.92
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, combustible materials.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide, rhodium/rhodium
oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7697-37-2: QU5775000 QU5900000
CAS# 15492-38-3 unlisted.
LD50/LC50:
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation,
rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
CAS# 15492-38-3.
Carcinogenicity:
Nitric acid -
Not listed by ACGIH, IARC, or NTP.
Rhodium (III) Nitrate Solution -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
USA RQ: CAS# 7697-37-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 35 Causes severe burns.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7697-37-2: 1
CAS# 15492-38-3: 0
Canada
CAS# 7697-37-2 is listed on Canada's DSL List.
CAS# 15492-38-3 is listed on Canada's NDSL List.
CAS# 7697-37-2 is listed on Canada's Ingredient Disclosure List.
CAS# 15492-38-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7697-37-2 is listed on the TSCA inventory.
CAS# 15492-38-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 6/23/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lutetium, powder, ca. 40 mesh, 99.9%
| 7439-94-3 |
|
Platinum, foil, 0.025mm thick, 99.99%
| 7440-06-4 |
|
Platinum, powder, 0.8-2.2 micron, 99.9%
| 7440-06-4 |
|
Platinum, powder, 0.27-0.47 micron, 99.9%
| 7440-06-4 |
|
Scandium, Powder, -40 Mesh, 99.9+%
| 7440-20-2 |
|
Palladium foil, 99.9+%
| 7440-05-3 |
|
Bis(Pentamethylcyclopentadienyl)Ruthenium
| 84821-53-4 |
|
Phenylmagnesium bromide, 3m solution in diethyl ether
| 100-58-3 |
|
Isopropylmagnesium chloride, 2.0 m solutio n in diethyl ether
| 1068-55-9 |
|
Rhodium (III) Nitrate Solution, ca. 10% (wt/ wt) Rh in 20-25 wt% HNO3
| 7697-37-2 |
|
Allylmagnesium bromide, 1m solution in diethylether
| 60-29-7 |
|
Titanium diisopropoxide bis(2,4-pentanedionate), 75 wt% in 2-propanol
| 67-63-0 |
|
Osmium Tetroxide, 4 wt% Solution in Water
| 7732-18-5 |
|
Lithium Cyanide, 0.5M Solution in N,N-Dimethylformamide
| 2408-36-8 |
|
Methylmagnesium bromide, 3M solution in diethyl ether
| 75-16-1 |
|
8-Hydroxy-5-Nitroquinoline, 96%
| 4008-48-4 |
|
Ethylmagnesium bromide, 3m solution in diethyl ether
| 925-90-6 |
|
Polyepichlorohydrin, Average MW ca. 700.000 (GPC)
| 24969-06-0 |
|
(+/-)-2-Phenylcycloheptanone, 99%
| 14996-78-2 |
|
4'-Chloro-2,2':6',2''-Terpyridine, 99%
| 128143-89-5 |
|
(3,5-Dimethoxyphenyl)acetic acid, 98%
| 4670-10-4 |
|
2,4-Dimethylpyrrole, 97%
| 625-82-1 |
|
O-Eugenol, 98%
| 579-60-2 |
|
2-(Bromomethyl)-2-(Hydroxymethyl)-1,3-Propanediol, 99%
| 19184-65-7 |
|
4,4'-Dipyridyl N,N'-Dioxide Dihydrate, 98%
| |
|
2,2'-Dipyridyl N,N'-Dioxide, 98%
| 7275-43-6 |
|
Ethyl Thiooxamate, 95%
| 16982-21-1 |
|
2',4'-Dihydroxy-3'-Methylpropiophenone, 98 %
| 63876-46-0 |
|
Oleylamine, 97% primary amine-value approx . c18-content 80-90%
| 112-90-3 |
|
2-Hydroxy-4-Methyl-3-Nitropyridine, 98%
| 21901-18-8 |
|
2-Hydroxy-4-Methyl-5-Nitropyridine, 98%
| 21901-41-7 |
|
2-Amino-4-Methyl-5-Nitropyridine, 98%
| 21901-40-6 |
|
2-Amino-4-Methyl-3-Nitropyridine, 98%
| 6635-86-5 |
|
Tetrabutylammonium difluorotriphenyl stannate
| 139353-88-1 |
|
Triphenyltin fluoride
| 379-52-2 |
|
(4-Hydroxyphenyl)-2-Propionic Acid
| 938-96-5 |
|
D,l-1-aminoindane-1-carboxylic acid
| |
|
N-Boc-d,l-1-Aminoindane-1-Carboxylic Acid
| |
|
N-fmoc-d,l-1-aminoindane-1-carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydroisoquinoline-3-c arboxylic acid
| |
|
N-fmoc-d-1,2,3,4-tetrahydroisoquinoline-3- carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydro-beta-carboline- 3-carboxylic acid
| |
|
N-Boc-2-Aminoindane-2-Carboxylic Acid
| |
|
N-fmoc-d,l-2-aminotetralin-2-carboxylic acid
| |
|
2-Chloro-4-Hydroxybenzoic Acid Hydrate, 98 % (On the Dried Substance)
| 56363-84-9 |
|
Methyl stearate, mixture of homologs
| 112-39-0 |
|
4-Bromophenol, 97% (GC)
| 106-41-2 |
|
1,1,1,5,5,5-Hexafluoroacetylacetone, 96%
| 1522-22-1 |
|
Methylurea, 97%
| 598-50-5 |
|
2-Methylbutyraldehyde, 95%
| 96-17-3 |
|
|