**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 20816-12-0 |Osmium tetroxide | 4 WT% | 244-058-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T+ C
Risk Phrases: 26/27/28 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May result in corneal injury. May cause
blindness.
Skin:
Causes skin burns.
Ingestion:
Aspiration hazard. Causes gastrointestinal tract burns. May cause
kidney damage. Causes cough, sore throat, chest pain, and
lightheadedness.
Inhalation:
Causes chemical burns to the respiratory tract. May cause
bronchopneumonia and possible death.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Prolonged
or repeated exposure may cause adverse reproductive effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. Use
water spray to keep fire-exposed containers cool. Oxidizer. Greatly
increases the burning rate of combustible materials. Containers may
explode in the heat of a fire. Contact with metals may evolve
flammable hydrogen gas.
Extinguishing Media:
Do NOT get water inside containers. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray. For
small fires, use dry chemical, carbon dioxide, water spray or regular
foam. Cool containers with flooding quantities of water until well
after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Reduce airborne dust and prevent scattering by moistening with
water. Wear a self contained breathing apparatus and appropriate
personal protection. (See Exposure Controls, Personal Protection
section). Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Keep container tightly closed. Do not
get on skin or in eyes. Do not ingest or inhale.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area. Do not store in metal
containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 7732-18-5:
CAS# 20816-12-0:
United Kingdom, WEL - TWA: 0.0002 ppm TWA (as Os); 0.002 mg/m3 TW
(as Os)
United Kingdom, WEL - STEL: 0.0006 ppm STEL (as Os); 0.006 mg/m3
(as Os)
United States OSHA: 0.002 mg/m3 TWA (As Os)
Belgium - TWA: 0.0002 ppm VLE (as Os); 0.0016 mg/m3 VLE (as Os)
Belgium - STEL: 0.0006 ppm VLE (as Os); 0.0048 mg/m3 VLE (as Os)
France - VME: 0.0002 ppm VME (as Os); 0.002 mg/m3 VME (as Os)
Germany: 0.0002 ppm TWA; 0.0021 mg/m3 TWA
Germany: Skin absorber
Malaysia: 0.0002 ppm TWA (as Os); 0.0016 mg/m3 TWA (as Os)
Netherlands: 0.0002 ppm MAC; 0.002 mg/m3 MAC (as Os)
Spain: 0.0002 ppm VLA-ED (as Os); 0.002 mg/m3 VLA-ED (as Os)
Spain: 0.0006 ppm VLA-EC (as Os); 0.006 mg/m3 VLA-EC (as Os)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: pale yellow
Odor: Chlorine-like odor
pH: Not available.
Vapor Pressure: 7 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: 130 deg C @ 760.00mmHg
Freezing/Melting Point: 39.50 - 41.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: 7.24g/100ml (25 c)
Specific Gravity/Density: 4.9
Molecular Formula: O4Os
Molecular Weight: 254.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, acids, metals, excess heat, bases.
Incompatibilities with Other Materials:
Combustible materials, Hydrogen chloride, Reducing agents, Strong
oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 20816-12-0: RN1140000
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 20816-12-0: Oral, mouse: LD50 = 162 mg/kg.
Carcinogenicity:
Water -
Not listed by ACGIH, IARC, or NTP.
Osmium tetroxide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3287
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3287
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3287
Packing group: III
USA RQ: CAS# 20816-12-0: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ C
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 20816-12-0: 2
Canada
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 20816-12-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 20816-12-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 20816-12-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 3/09/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Lutetium, powder, ca. 40 mesh, 99.9%
| 7439-94-3 |
|
Platinum, foil, 0.025mm thick, 99.99%
| 7440-06-4 |
|
Platinum, powder, 0.8-2.2 micron, 99.9%
| 7440-06-4 |
|
Platinum, powder, 0.27-0.47 micron, 99.9%
| 7440-06-4 |
|
Scandium, Powder, -40 Mesh, 99.9+%
| 7440-20-2 |
|
Palladium foil, 99.9+%
| 7440-05-3 |
|
Bis(Pentamethylcyclopentadienyl)Ruthenium
| 84821-53-4 |
|
Phenylmagnesium bromide, 3m solution in diethyl ether
| 100-58-3 |
|
Isopropylmagnesium chloride, 2.0 m solutio n in diethyl ether
| 1068-55-9 |
|
Rhodium (III) Nitrate Solution, ca. 10% (wt/ wt) Rh in 20-25 wt% HNO3
| 7697-37-2 |
|
Allylmagnesium bromide, 1m solution in diethylether
| 60-29-7 |
|
Titanium diisopropoxide bis(2,4-pentanedionate), 75 wt% in 2-propanol
| 67-63-0 |
|
Osmium Tetroxide, 4 wt% Solution in Water
| 7732-18-5 |
|
Lithium Cyanide, 0.5M Solution in N,N-Dimethylformamide
| 2408-36-8 |
|
Methylmagnesium bromide, 3M solution in diethyl ether
| 75-16-1 |
|
8-Hydroxy-5-Nitroquinoline, 96%
| 4008-48-4 |
|
Ethylmagnesium bromide, 3m solution in diethyl ether
| 925-90-6 |
|
Polyepichlorohydrin, Average MW ca. 700.000 (GPC)
| 24969-06-0 |
|
(+/-)-2-Phenylcycloheptanone, 99%
| 14996-78-2 |
|
4'-Chloro-2,2':6',2''-Terpyridine, 99%
| 128143-89-5 |
|
(3,5-Dimethoxyphenyl)acetic acid, 98%
| 4670-10-4 |
|
2,4-Dimethylpyrrole, 97%
| 625-82-1 |
|
O-Eugenol, 98%
| 579-60-2 |
|
2-(Bromomethyl)-2-(Hydroxymethyl)-1,3-Propanediol, 99%
| 19184-65-7 |
|
4,4'-Dipyridyl N,N'-Dioxide Dihydrate, 98%
| |
|
2,2'-Dipyridyl N,N'-Dioxide, 98%
| 7275-43-6 |
|
Ethyl Thiooxamate, 95%
| 16982-21-1 |
|
2',4'-Dihydroxy-3'-Methylpropiophenone, 98 %
| 63876-46-0 |
|
Oleylamine, 97% primary amine-value approx . c18-content 80-90%
| 112-90-3 |
|
2-Hydroxy-4-Methyl-3-Nitropyridine, 98%
| 21901-18-8 |
|
2-Hydroxy-4-Methyl-5-Nitropyridine, 98%
| 21901-41-7 |
|
2-Amino-4-Methyl-5-Nitropyridine, 98%
| 21901-40-6 |
|
2-Amino-4-Methyl-3-Nitropyridine, 98%
| 6635-86-5 |
|
Tetrabutylammonium difluorotriphenyl stannate
| 139353-88-1 |
|
Triphenyltin fluoride
| 379-52-2 |
|
(4-Hydroxyphenyl)-2-Propionic Acid
| 938-96-5 |
|
D,l-1-aminoindane-1-carboxylic acid
| |
|
N-Boc-d,l-1-Aminoindane-1-Carboxylic Acid
| |
|
N-fmoc-d,l-1-aminoindane-1-carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydroisoquinoline-3-c arboxylic acid
| |
|
N-fmoc-d-1,2,3,4-tetrahydroisoquinoline-3- carboxylic acid
| |
|
N-boc-d-1,2,3,4-tetrahydro-beta-carboline- 3-carboxylic acid
| |
|
N-Boc-2-Aminoindane-2-Carboxylic Acid
| |
|
N-fmoc-d,l-2-aminotetralin-2-carboxylic acid
| |
|
2-Chloro-4-Hydroxybenzoic Acid Hydrate, 98 % (On the Dried Substance)
| 56363-84-9 |
|
Methyl stearate, mixture of homologs
| 112-39-0 |
|
4-Bromophenol, 97% (GC)
| 106-41-2 |
|
1,1,1,5,5,5-Hexafluoroacetylacetone, 96%
| 1522-22-1 |
|
Methylurea, 97%
| 598-50-5 |
|
2-Methylbutyraldehyde, 95%
| 96-17-3 |
|
|