**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-46-7 |p-Dichlorobenzene | 97 | 203-400-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 36 40 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes. Limited evidence of a carcinogenic effect. Very
toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation. Exposure to high vapor concentrations may
cause irritation.
Skin:
Solid produces burning sensation when held in contact with the skin,
but irritation is slight.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage.
Inhalation:
Causes respiratory tract irritation. May cause liver and kidney
damage. Inhalation of vapors causes irritation of eyes, throat, and
skin. Exposure may cause anorexia, nausea, vomiting, weight loss and
hepatic necrosis with jaundice. Exposure may cause headache and
rhinitis (inflammation of the mucous membrane of the nose).
Chronic:
Possible cancer hazard based on tests with laboratory animals. May
cause anemia and other blood cell abnormalities. Animal studies
indicate that the product may affect the liver and kidneys.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Use water spray to keep fire-exposed containers cool. Combustible
liquid and vapor. Vapors are heavier than air and may travel to a
source of ignition and flash back. Vapors can spread along the
ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid breathing dust. Avoid breathing vapor. Keep away from
heat and flame.
Storage:
Keep away from heat and flame. Store in a tightly closed container.
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 106-46-7:
United Kingdom, WEL - TWA: 25 ppm TWA; 153 mg/m3 TWA
United Kingdom, WEL - STEL: 50 ppm STEL; 306 mg/m3 STEL
United States OSHA: 75 ppm TWA; 450 mg/m3 TWA
Belgium - TWA: 10 ppm VLE; 61 mg/m3 VLE
Belgium - STEL: 50 ppm VLE; 306 mg/m3 VLE
France - VME: 75 ppm VME; 450 mg/m3 VME
France - VLE: 110 ppm VLE; 675 mg/m3 VLE
Germany: 50 ppm TWA; 300 mg/m3 TWA
Germany: Skin absorber
Japan: 10 ppm OEL; 60 mg/m3 OEL
Malaysia: 10 ppm TWA; 60 mg/m3 TWA
Netherlands: 50 ppm STEL; 300 mg/m3 STEL
Netherlands: 25 ppm MAC; 150 mg/m3 MAC
Spain: 20 ppm VLA-ED; 122 mg/m3 VLA-ED
Spain: 50 ppm VLA-EC; 306 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: mothball-like - penetrating odor
pH: Not available.
Vapor Pressure: 1 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 174 deg C
Freezing/Melting Point: 53 deg C
Autoignition Temperature: 640 deg C ( 1,184.00 deg F)
Flash Point: 65 deg C ( 149.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 1.458 @ 20C
Molecular Formula: C6H4Cl2
Molecular Weight: 147.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, ignition sources, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-46-7: CZ4550000
LD50/LC50:
CAS# 106-46-7: Inhalation, rat: LC50 = 5000 mg/m3/4H; Oral, mouse:
LD50 = 2950 mg/kg; Oral, rabbit: LD50 = 2830 mg/kg; Oral, rat: LD50 =
500 mg/kg; Skin, rabbit: LD50 = >2 gm/kg; Skin, rat: LD50 = 2000
mg/kg.
Oral LD50, rat: 3826 mg/kg.
mg/kg.
on animal inhalation exposure studies with vapor.
rabbit: Moderately irritating.
irritating to rabbit skin in 4 hour test.
Carcinogenicity:
p-Dichlorobenzene -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 1/1/89
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: Daphnia: 7.4 mg/l; 48h; EC50Fish: Rainbow trout: 1.12 mg/l;
96h; LC50Fish: Fathead Minnow: 4.0 mg/l; 96h; LC50Fish:
Bluegill/Sunfish: 4.3 mg/l; 96h; LC50
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
USA RQ: CAS# 106-46-7: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 36 Irritating to eyes.
R 40 Limited evidence of a carcinogenic effect.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
S 46 If swallowed, seek medical advice immediately
and show this container or label.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 106-46-7: 2
Canada
CAS# 106-46-7 is listed on Canada's DSL List.
CAS# 106-46-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-46-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #6 Date: 3/14/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chloroethyl Methyl Ether, 98%
| 627-42-9 |
|
1-Ethyl-2-benzimidazolinone, 98%
| 10045-45-1 |
|
6-Bromohexanoic Acid, 98%
| 4224-70-8 |
|
(S)-(+)-1-Phenyl-1,2-Ethanediol, 99+%
| 25779-13-9 |
|
Platinum on sulfide carbon,5% pt,contains ca.50% moisture
| 7440-06-4 |
|
Zinc selenide, 99.99%
| 1315-09-9 |
|
2-(2-Methoxyethoxy)-Ethanol 99%
| 111-77-3 |
|
Phenylbutazone, 99+%
| 50-33-9 |
|
4-Amino-2,6-Dihydroxypyrimidine, 98%
| 873-83-6 |
|
Sodium cyanoborohydride, 95+%
| 25895-60-7 |
|
Syringaldazine, 99+%
| 14414-32-5 |
|
1,1,4-Triacetoxy-2,2-dichlorobutane, 98%
| 0-01-1 |
|
l(+)-Gulonic Acid Gamma-Lactone, 97%
| 1128-23-0 |
|
Diethylaminoacetonitrile
| 3010-02-4 |
|
Calcium sulfate dihydrate, p.a.
| 7778-18-9 |
|
Beta-Carotene, 99% (UV-VIS)
| 7235-40-7 |
|
Hoechst 33258, 98%
| 23491-45-4 |
|
4'-Chlorobutyrophenone, 99%
| 4981-63-9 |
|
Brilliant yellow, 98% (uv-vis)
| 3051-11-4 |
|
d-Lysine hydrochloride, 99+%
| 7274-88-6 |
|
Indoxyl Acetate, 97%
| 608-08-2 |
|
Ethyl 3-Phenylglycidate, 98%
| 121-39-1 |
|
Amberlite cg-120 ion-exchange resin
| 37360-75-1 |
|
18-Crown-6, 99%
| 17455-13-9 |
|
1-Chloro-3-phenylpropane, 98+%
| 104-52-9 |
|
L-(+)-Rhamnose Monohydrate, 99%
| 10030-85-0 |
|
5-Chloro-2,3-Dibromo-1-Fluorobenzene, 98%
| 92771-38-5 |
|
1-Methyl-6,7-Dihydroxy-3,4-Dihydroisoquinoline, Monohydrate, 99%
| |
|
Cyclohexyl chloride, 98%
| 542-18-7 |
|
N-Ethyldiethanolamine, 98%
| 139-87-7 |
|
Aluminum Cyclohexanebutyrate
| 38598-34-4 |
|
Benzyltrimethylammonium chloride, 98+%
| 56-93-9 |
|
p-Cresol
| 106-44-5 |
|
1,4-Benzodioxan-6-amine, 99%
| 22013-33-8 |
|
Aza-15-crown-5, 99+%
| 66943-05-3 |
|
Triphenylformazan, 98% (Nitrogen)
| 531-52-2 |
|
p-Dichlorobenzene
| 106-46-7 |
|
2-(Ethylamino)-ethanol, p.a.
| 110-73-6 |
|
Amberlyst ?? A-26 Ion-Exchange Resin
| 39280-09-6 |
|
2,4,4-Trimethyl-1-Pentanol, 98%
| 16325-63-6 |
|
1,4-Dibromo-2,5-Dimethylbenzene, 99%
| 1074-24-4 |
|
p-Dimethylaminobenzaldehyde
| 100-10-7 |
|
3-Methoxyphenol, 97%
| 150-19-6 |
|
2,3-Dichloroaniline, 99%
| 608-27-5 |
|
2,4-Diamino-6-Hydroxypyrimidine, 96%
| 56-06-4 |
|
4-Bromostyrene, 96%, Stab. with ca. 100 ppm 4-Tert.-Butylcatechol
| 2039-82-9 |
|
1-Aminoanthraquinone
| 82-45-1 |
|
Trimethylsilylmethyl Acetate, 99%
| 2917-65-9 |
|
Tetraethyl pyrophosphite, tech., 93%
| 21646-99-1 |
|
4-Phenylpyrocatechol, 98% (Titr.)
| 92-05-7 |
|
|