**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-77-3 |2-(2-Methoxyethoxy)ethanol | 99 | 203-906-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode
when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 111-77-3:
Netherlands: 9 ppm MAC; 45 mg/m3 MAC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: ethereal odor
pH: Not available.
Vapor Pressure: 2.5 mm Hg @ 25C
Viscosity: 3.9 MPA 20.00 deg C
Boiling Point: 194 deg C
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 215 deg C ( 419.00 deg F)
Flash Point: 93.4 deg C ( 200.12 deg F)
Explosion Limits, lower: 1.60 vol %
Explosion Limits, upper: 16.10 vol %
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: 1.0100g/cm3
Molecular Formula: C5H12O3
Molecular Weight: 120.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-77-3: KL6125000
LD50/LC50:
CAS# 111-77-3: Draize test, rabbit, eye: 500 mg Moderate; Draize
test, rabbit, eye: 500 mg/24H Mild; Oral, mouse: LD50 = 8222 mg/kg;
Oral, rabbit: LD50 = 7190 mg/kg; Oral, rat: LD50 = 4 mL/kg; Skin,
rabbit: LD50 = 2500 uL/kg.
Oral, rat: LD50 = 1746-10502 mg/kg
Carcinogenicity:
2-(2-Methoxyethoxy)ethanol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 1000 mg/L; 96 Hr.; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 7500 mg/L; 96 Hr.; Static ConditionWater
flea Daphnia: EC50 = >500 mg/L; 24-48 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 3.7-7.3 mg/L; 30 minutes; Microtox
test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-77-3: 1
Canada
CAS# 111-77-3 is listed on Canada's DSL List.
CAS# 111-77-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-77-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/08/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chloroethyl Methyl Ether, 98%
| 627-42-9 |
|
1-Ethyl-2-benzimidazolinone, 98%
| 10045-45-1 |
|
6-Bromohexanoic Acid, 98%
| 4224-70-8 |
|
(S)-(+)-1-Phenyl-1,2-Ethanediol, 99+%
| 25779-13-9 |
|
Platinum on sulfide carbon,5% pt,contains ca.50% moisture
| 7440-06-4 |
|
Zinc selenide, 99.99%
| 1315-09-9 |
|
2-(2-Methoxyethoxy)-Ethanol 99%
| 111-77-3 |
|
Phenylbutazone, 99+%
| 50-33-9 |
|
4-Amino-2,6-Dihydroxypyrimidine, 98%
| 873-83-6 |
|
Sodium cyanoborohydride, 95+%
| 25895-60-7 |
|
Syringaldazine, 99+%
| 14414-32-5 |
|
1,1,4-Triacetoxy-2,2-dichlorobutane, 98%
| 0-01-1 |
|
l(+)-Gulonic Acid Gamma-Lactone, 97%
| 1128-23-0 |
|
Diethylaminoacetonitrile
| 3010-02-4 |
|
Calcium sulfate dihydrate, p.a.
| 7778-18-9 |
|
Beta-Carotene, 99% (UV-VIS)
| 7235-40-7 |
|
Hoechst 33258, 98%
| 23491-45-4 |
|
4'-Chlorobutyrophenone, 99%
| 4981-63-9 |
|
Brilliant yellow, 98% (uv-vis)
| 3051-11-4 |
|
d-Lysine hydrochloride, 99+%
| 7274-88-6 |
|
Indoxyl Acetate, 97%
| 608-08-2 |
|
Ethyl 3-Phenylglycidate, 98%
| 121-39-1 |
|
Amberlite cg-120 ion-exchange resin
| 37360-75-1 |
|
18-Crown-6, 99%
| 17455-13-9 |
|
1-Chloro-3-phenylpropane, 98+%
| 104-52-9 |
|
L-(+)-Rhamnose Monohydrate, 99%
| 10030-85-0 |
|
5-Chloro-2,3-Dibromo-1-Fluorobenzene, 98%
| 92771-38-5 |
|
1-Methyl-6,7-Dihydroxy-3,4-Dihydroisoquinoline, Monohydrate, 99%
| |
|
Cyclohexyl chloride, 98%
| 542-18-7 |
|
N-Ethyldiethanolamine, 98%
| 139-87-7 |
|
Aluminum Cyclohexanebutyrate
| 38598-34-4 |
|
Benzyltrimethylammonium chloride, 98+%
| 56-93-9 |
|
p-Cresol
| 106-44-5 |
|
1,4-Benzodioxan-6-amine, 99%
| 22013-33-8 |
|
Aza-15-crown-5, 99+%
| 66943-05-3 |
|
Triphenylformazan, 98% (Nitrogen)
| 531-52-2 |
|
p-Dichlorobenzene
| 106-46-7 |
|
2-(Ethylamino)-ethanol, p.a.
| 110-73-6 |
|
Amberlyst ?? A-26 Ion-Exchange Resin
| 39280-09-6 |
|
2,4,4-Trimethyl-1-Pentanol, 98%
| 16325-63-6 |
|
1,4-Dibromo-2,5-Dimethylbenzene, 99%
| 1074-24-4 |
|
p-Dimethylaminobenzaldehyde
| 100-10-7 |
|
3-Methoxyphenol, 97%
| 150-19-6 |
|
2,3-Dichloroaniline, 99%
| 608-27-5 |
|
2,4-Diamino-6-Hydroxypyrimidine, 96%
| 56-06-4 |
|
4-Bromostyrene, 96%, Stab. with ca. 100 ppm 4-Tert.-Butylcatechol
| 2039-82-9 |
|
1-Aminoanthraquinone
| 82-45-1 |
|
Trimethylsilylmethyl Acetate, 99%
| 2917-65-9 |
|
Tetraethyl pyrophosphite, tech., 93%
| 21646-99-1 |
|
4-Phenylpyrocatechol, 98% (Titr.)
| 92-05-7 |
|
|