**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 25895-60-7 |Sodium cyanoborohydride | >95.0 | 247-317-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 10 15 23/24/25 32 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Contact with water liberates extremely flammable gases.
Toxic by inhalation, in contact with skin and if swallowed. Contact
with acids liberates very toxic gas. Causes burns.Water-reactive.
Potential Health Effects
Eye:
Causes eye irritation and burns. May cause chemical
conjunctivitis.
Skin:
May be absorbed through the skin. May be metabolized to cyanide
which in turn acts by inhibiting cytochrome oxidase impairing
cellular respiration. Causes skin irritation and burns.
Ingestion:
May be fatal if swallowed. Poison by ingestion. Causes
gastrointestinal tract burns. Ingestion may result in symptoms
similar to cyanide poisoning which is characterized by asphyxiation.
Inhalation:
May cause respiratory tract irritation. May be metabolized to
cyanide which in turns act by inhibiting cytochrome oxidase
impairing cellular respiration.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Treat patient as
for inhalation.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask. If inhaled, do NOT induce vomiting, and
seek medical aid immediately. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical
device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas. Flammable solid.
Containers may explode when heated. Substance will react with water
(some violently) releasing flammable, toxic, or corrosive gases and
runoff.
Extinguishing Media:
Use dry chemical to fight fire. Contact professional fire-fighters
immediately. DO NOT USE WATER OR FOAM.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Do not ingest or inhale. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep under a nitrogen
blanket. Store in a cool, dry, well-ventilated area away from
incompatible substances. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 25895-60-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: >242 deg C dec
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density:
Molecular Formula: CH3BNNa
Molecular Weight: 62.84
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, dust
generation, contact with water.
Incompatibilities with Other Materials:
Oxidizing agents, acids, water.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
oxides of boron, borane, hydrogen gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 25895-60-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium cyanoborohydride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.*
Hazard Class: 4.3 (6.1)
UN Number: 3134
Packing Group: I
IMO
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.
Hazard Class: 4.3 (6.1)
UN Number: 3134
Packing Group: I
RID/ADR
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.
Hazard Class: 4.3 (6.1)
UN Number: 3134
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 10 Flammable.
R 15 Contact with water liberates extremely
flammable gases.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 32 Contact with acids liberates very toxic gas.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 25895-60-7: 2
Canada
CAS# 25895-60-7 is listed on Canada's NDSL List.
CAS# 25895-60-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25895-60-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/10/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chloroethyl Methyl Ether, 98%
| 627-42-9 |
|
1-Ethyl-2-benzimidazolinone, 98%
| 10045-45-1 |
|
6-Bromohexanoic Acid, 98%
| 4224-70-8 |
|
(S)-(+)-1-Phenyl-1,2-Ethanediol, 99+%
| 25779-13-9 |
|
Platinum on sulfide carbon,5% pt,contains ca.50% moisture
| 7440-06-4 |
|
Zinc selenide, 99.99%
| 1315-09-9 |
|
2-(2-Methoxyethoxy)-Ethanol 99%
| 111-77-3 |
|
Phenylbutazone, 99+%
| 50-33-9 |
|
4-Amino-2,6-Dihydroxypyrimidine, 98%
| 873-83-6 |
|
Sodium cyanoborohydride, 95+%
| 25895-60-7 |
|
Syringaldazine, 99+%
| 14414-32-5 |
|
1,1,4-Triacetoxy-2,2-dichlorobutane, 98%
| 0-01-1 |
|
l(+)-Gulonic Acid Gamma-Lactone, 97%
| 1128-23-0 |
|
Diethylaminoacetonitrile
| 3010-02-4 |
|
Calcium sulfate dihydrate, p.a.
| 7778-18-9 |
|
Beta-Carotene, 99% (UV-VIS)
| 7235-40-7 |
|
Hoechst 33258, 98%
| 23491-45-4 |
|
4'-Chlorobutyrophenone, 99%
| 4981-63-9 |
|
Brilliant yellow, 98% (uv-vis)
| 3051-11-4 |
|
d-Lysine hydrochloride, 99+%
| 7274-88-6 |
|
Indoxyl Acetate, 97%
| 608-08-2 |
|
Ethyl 3-Phenylglycidate, 98%
| 121-39-1 |
|
Amberlite cg-120 ion-exchange resin
| 37360-75-1 |
|
18-Crown-6, 99%
| 17455-13-9 |
|
1-Chloro-3-phenylpropane, 98+%
| 104-52-9 |
|
L-(+)-Rhamnose Monohydrate, 99%
| 10030-85-0 |
|
5-Chloro-2,3-Dibromo-1-Fluorobenzene, 98%
| 92771-38-5 |
|
1-Methyl-6,7-Dihydroxy-3,4-Dihydroisoquinoline, Monohydrate, 99%
| |
|
Cyclohexyl chloride, 98%
| 542-18-7 |
|
N-Ethyldiethanolamine, 98%
| 139-87-7 |
|
Aluminum Cyclohexanebutyrate
| 38598-34-4 |
|
Benzyltrimethylammonium chloride, 98+%
| 56-93-9 |
|
p-Cresol
| 106-44-5 |
|
1,4-Benzodioxan-6-amine, 99%
| 22013-33-8 |
|
Aza-15-crown-5, 99+%
| 66943-05-3 |
|
Triphenylformazan, 98% (Nitrogen)
| 531-52-2 |
|
p-Dichlorobenzene
| 106-46-7 |
|
2-(Ethylamino)-ethanol, p.a.
| 110-73-6 |
|
Amberlyst ?? A-26 Ion-Exchange Resin
| 39280-09-6 |
|
2,4,4-Trimethyl-1-Pentanol, 98%
| 16325-63-6 |
|
1,4-Dibromo-2,5-Dimethylbenzene, 99%
| 1074-24-4 |
|
p-Dimethylaminobenzaldehyde
| 100-10-7 |
|
3-Methoxyphenol, 97%
| 150-19-6 |
|
2,3-Dichloroaniline, 99%
| 608-27-5 |
|
2,4-Diamino-6-Hydroxypyrimidine, 96%
| 56-06-4 |
|
4-Bromostyrene, 96%, Stab. with ca. 100 ppm 4-Tert.-Butylcatechol
| 2039-82-9 |
|
1-Aminoanthraquinone
| 82-45-1 |
|
Trimethylsilylmethyl Acetate, 99%
| 2917-65-9 |
|
Tetraethyl pyrophosphite, tech., 93%
| 21646-99-1 |
|
4-Phenylpyrocatechol, 98% (Titr.)
| 92-05-7 |
|
|