**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1315-09-9 |ZINC SELENIDE | 99.99 | 215-259-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed. Danger of cumulative
effects.The toxicological properties of this material have not been
fully investigated.Moisture sensitive.Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
Chronic exposure to selenium may cause central nervous system
effects, digestive tract disturbances, pallor, garlic breath,
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Rinse area with
large amounts of water for at least 15 minutes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1315-09-9:
United Kingdom, WEL - TWA: (listed as selenium compounds): 0.1 mg
TWA (except hydrogen selenide, as Se)
United Kingdom, WEL - STEL: (listed as selenium compounds): 0.3 m
STEL (except hydrogen selenide, as Se)
United States OSHA: 0.2 mg/m3 TWA (as Se) (listed under Selenium
compounds).
Belgium - TWA: (listed as selenium compounds): 0.2 mg/m3 VLE (as
Japan: (listed as selenium compounds): 0.1 mg/m3 OEL (except SeH2
SeF6, as Se)
Malaysia: (listed as selenium compounds): 0.2 mg/m3 TWA (as Se)
Netherlands: (listed as selenium compounds): 0.1 mg/m3 MAC (as Se
Spain: (listed as selenium compounds): 0.1 mg/m3 VLA-ED (except
hydrogen selenide, as Se)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: not available
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 1100 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: SeZn
Molecular Weight: 144.34
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong acids.
Hazardous Decomposition Products:
Selenium/selenium oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1315-09-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
ZINC SELENIDE -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: SELENIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3283
Packing Group: II
IMO
Shipping Name: SELENIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3283
Packing Group: II
RID/ADR
Shipping Name: SELENIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3283
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1315-09-9: No information available.
Canada
CAS# 1315-09-9 is listed on Canada's NDSL List.
CAS# 1315-09-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1315-09-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chloroethyl Methyl Ether, 98%
| 627-42-9 |
|
1-Ethyl-2-benzimidazolinone, 98%
| 10045-45-1 |
|
6-Bromohexanoic Acid, 98%
| 4224-70-8 |
|
(S)-(+)-1-Phenyl-1,2-Ethanediol, 99+%
| 25779-13-9 |
|
Platinum on sulfide carbon,5% pt,contains ca.50% moisture
| 7440-06-4 |
|
Zinc selenide, 99.99%
| 1315-09-9 |
|
2-(2-Methoxyethoxy)-Ethanol 99%
| 111-77-3 |
|
Phenylbutazone, 99+%
| 50-33-9 |
|
4-Amino-2,6-Dihydroxypyrimidine, 98%
| 873-83-6 |
|
Sodium cyanoborohydride, 95+%
| 25895-60-7 |
|
Syringaldazine, 99+%
| 14414-32-5 |
|
1,1,4-Triacetoxy-2,2-dichlorobutane, 98%
| 0-01-1 |
|
l(+)-Gulonic Acid Gamma-Lactone, 97%
| 1128-23-0 |
|
Diethylaminoacetonitrile
| 3010-02-4 |
|
Calcium sulfate dihydrate, p.a.
| 7778-18-9 |
|
Beta-Carotene, 99% (UV-VIS)
| 7235-40-7 |
|
Hoechst 33258, 98%
| 23491-45-4 |
|
4'-Chlorobutyrophenone, 99%
| 4981-63-9 |
|
Brilliant yellow, 98% (uv-vis)
| 3051-11-4 |
|
d-Lysine hydrochloride, 99+%
| 7274-88-6 |
|
Indoxyl Acetate, 97%
| 608-08-2 |
|
Ethyl 3-Phenylglycidate, 98%
| 121-39-1 |
|
Amberlite cg-120 ion-exchange resin
| 37360-75-1 |
|
18-Crown-6, 99%
| 17455-13-9 |
|
1-Chloro-3-phenylpropane, 98+%
| 104-52-9 |
|
L-(+)-Rhamnose Monohydrate, 99%
| 10030-85-0 |
|
5-Chloro-2,3-Dibromo-1-Fluorobenzene, 98%
| 92771-38-5 |
|
1-Methyl-6,7-Dihydroxy-3,4-Dihydroisoquinoline, Monohydrate, 99%
| |
|
Cyclohexyl chloride, 98%
| 542-18-7 |
|
N-Ethyldiethanolamine, 98%
| 139-87-7 |
|
Aluminum Cyclohexanebutyrate
| 38598-34-4 |
|
Benzyltrimethylammonium chloride, 98+%
| 56-93-9 |
|
p-Cresol
| 106-44-5 |
|
1,4-Benzodioxan-6-amine, 99%
| 22013-33-8 |
|
Aza-15-crown-5, 99+%
| 66943-05-3 |
|
Triphenylformazan, 98% (Nitrogen)
| 531-52-2 |
|
p-Dichlorobenzene
| 106-46-7 |
|
2-(Ethylamino)-ethanol, p.a.
| 110-73-6 |
|
Amberlyst ?? A-26 Ion-Exchange Resin
| 39280-09-6 |
|
2,4,4-Trimethyl-1-Pentanol, 98%
| 16325-63-6 |
|
1,4-Dibromo-2,5-Dimethylbenzene, 99%
| 1074-24-4 |
|
p-Dimethylaminobenzaldehyde
| 100-10-7 |
|
3-Methoxyphenol, 97%
| 150-19-6 |
|
2,3-Dichloroaniline, 99%
| 608-27-5 |
|
2,4-Diamino-6-Hydroxypyrimidine, 96%
| 56-06-4 |
|
4-Bromostyrene, 96%, Stab. with ca. 100 ppm 4-Tert.-Butylcatechol
| 2039-82-9 |
|
1-Aminoanthraquinone
| 82-45-1 |
|
Trimethylsilylmethyl Acetate, 99%
| 2917-65-9 |
|
Tetraethyl pyrophosphite, tech., 93%
| 21646-99-1 |
|
4-Phenylpyrocatechol, 98% (Titr.)
| 92-05-7 |
|
|