**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67843-74-7 |(S)-(+)-Epichlorohydrin | 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 10 23/24/25 34 43 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if
swallowed. Causes burns. May cause sensitization by skin contact.
May cause cancer.
Potential Health Effects
Eye:
Causes eye burns. May cause blindness.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Toxic in contact with skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Toxic if inhaled.
Inhalation of vapors will cause coughing or breathing difficulty.
Chronic:
May cause liver and kidney damage. May cause cancer in humans. May
cause lung damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Containers
may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
Use carbon dioxide or dry chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 106-89-8:
United Kingdom, WEL - TWA: 0.5 ppm TWA; 1.9 mg/m3 TWA
United Kingdom, WEL - STEL: 1.5 ppm STEL; 5.8 mg/m3 STEL
United States OSHA: 5 ppm TWA; 19 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 7.7 mg/m3 VLE
France - VLE: 2 ppm VLE; 10 mg/m3 VLE
Germany: 3 ppm TWA; 12 mg/m3 TWA
Germany: Skin absorber
Malaysia: 0.5 ppm TWA; 1.9 mg/m3 TWA
Russia: 1 mg/m3 TWA
Spain: 0.5 ppm VLA-ED; 1.9 mg/m3 VLA-ED
CAS# 67843-74-7:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 12.5 mm Hg @20 deg
Viscosity: Not available.
Boiling Point: 114 deg C @760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: 420 deg C ( 788.00 deg F)
Flash Point: 33 deg C ( 91.40 deg F)
Explosion Limits, lower: 3.8 Vol%
Explosion Limits, upper: 21 Vol%
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.183
Molecular Formula: C3H5ClO
Molecular Weight: 92.4874
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Acids, bases, aluminum, amines, ammonia, magnesium, zinc.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-89-8: TX4900000
CAS# 67843-74-7: RR0427100
LD50/LC50:
CAS# 106-89-8: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, eye: 100 mg/24H Moderate; Inhalation, rat: LC50 = 250 ppm/8H;
Oral, mouse: LD50 = 195 mg/kg; Oral, rabbit: LD50 = 345 mg/kg; Oral,
rat: LD50 = 90 mg/kg; Skin, rabbit: LD50 = 515 mg/kg.
CAS# 67843-74-7.
Carcinogenicity:
Epichlorohydrin -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 10/1/87
NTP: Suspect carcinogen
IARC: Group 2A carcinogen
(S)-(+)-Epichlorohydrin -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 106-89-8: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 106-89-8: 3
CAS# 67843-74-7: No information available.
Canada
CAS# 106-89-8 is listed on Canada's DSL List.
CAS# 106-89-8 is listed on Canada's Ingredient Disclosure List.
CAS# 67843-74-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-89-8 is listed on the TSCA inventory.
CAS# 67843-74-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 5/30/2000 Revision #2 Date: 2/23/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Cyanophenyl isothiocyanate, 98%
| 2719-32-6 |
|
Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)
| 0-01-1 |
|
Chitosan
| 9012-76-4 |
|
Calcium Chloride, Anhydrous Powder, 96%
| 10043-52-4 |
|
1,2-Bis(2-chloroethoxy)ethane, 97%
| 112-26-5 |
|
Bis(pentamethylcyclopentadienyl)chromium
| 74507-61-2 |
|
Bis(benzene)chromium
| 1271-54-1 |
|
1'-Acetonaphthone, 95%
| 941-98-0 |
|
(Ethylcyclopentadienyl)(triphenylphosphine) copper(I)
| 308847-89-4 |
|
1,2,4-Benzenetricarboxylic acid, 98%
| 528-44-9 |
|
[2.2]Paracyclophane, 98%
| 1633-22-3 |
|
Diphenylmethylbismuthine
| 74724-75-7 |
|
P-Tolylacetic Acid, 99%
| 622-47-9 |
|
Tris(2-methoxyphenyl)bismuthine
| 83724-41-8 |
|
Benzophenone
| 119-61-9 |
|
Tris(cyclopentadienyl)cerium
| 1298-53-9 |
|
Tris(cyclopentadienyl)erbium
| 39330-74-0 |
|
Sodium hydroxide, 0.2 N solution
| 1310-73-2 |
|
1-Naphthylacetic acid, 95%
| 86-87-3 |
|
Benzotriazole
| 95-14-7 |
|
Cinnamyl Acetate, 99%
| 103-54-8 |
|
alpha-Ionone, synthetic
| 127-41-3 |
|
4-Aminobenzyl alcohol, 99%
| 623-04-1 |
|
5-Bromo-6-chloro-3-indoxyl-N-acetyl-beta-D-glucosaminide
| 5609-91-6 |
|
5-Bromo-4-chloro-3-indoxyl-N-acetyl-beta-D-glucosaminide
| 4264-82-8 |
|
2,5-Dimethylphenylhydrazine hydrochloride
| 56737-78-1 |
|
2-Bromophenylacetonitrile, 98%
| 19472-74-3 |
|
Hydroethidine
| 38483-26-0 |
|
(R)-(-)-Epichlorohydrin, 99%
| 106-89-8 |
|
(S)-(+)-Epichlorohydrin, 98%
| 106-89-8 |
|
3-Chloro-2-nitrotoluene
| 5367-26-0 |
|
3-Chloro-4-nitrotoluene
| 38939-88-7 |
|
5-Chloro-2-nitrotoluene, 98%
| 5367-28-2 |
|
3,5-Dichlorophenylhydrazine hydrochloride, 93%
| 63352-99-8 |
|
Acriflavine hydrochloride
| 8063-24-9 |
|
Tributylbismuthine
| 3692-81-7 |
|
Dicarbonyl(pentamethylcyclopentadienyl)chromium dimer
| 37299-12-0 |
|
Dicarbonylcyclopentadienylcobalt
| 12078-25-0 |
|
N,N-Dimethyl-p-Phenylenediamine Monohydrochloride, 90-95%
| 2052-46-2 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.4-1.7 mmolCl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.9-2.1 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 2.8-3.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.6-1.8 mmol Cl/g,
| 9036-15-1 |
|
Benzoyl chloride
| 98-88-4 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.8-2.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 2.5-3.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 0.6-0.8 mmol Cl/g,
| 9036-15-1 |
|
Benzyl acetate, 99+%
| 140-11-4 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 1.4-1.6 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 2.0-2.2 mmol Cl/g,
| 9036-15-1 |
|
|