**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 140-11-4 |Benzyl acetate | >99 | 205-399-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. May cause central nervous system effects
and/or neurological effects.
Inhalation:
May cause effects similar to those described for ingestion.
Chronic:
May cause cancer according to animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 140-11-4:
Belgium - TWA: 10 ppm VLE; 62 mg/m3 VLE
Malaysia: 10 ppm TWA; 61 mg/m3 TWA
Russia: 5 mg/m3 TWA
Spain: 10 ppm VLA-ED; 62 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Fruity Odor
pH: Not available.
Vapor Pressure: 0.15 mbar @ 25
Viscosity: Not available.
Boiling Point: 214 deg C @ 760 mm Hg
Freezing/Melting Point: -51 deg C
Autoignition Temperature: 460 deg C ( 860.00 deg F)
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: .90 vol %
Explosion Limits, upper: 8.40 vol %
Decomposition Temperature:
Solubility in water: practically insoluble in water
Specific Gravity/Density: 1.055
Molecular Formula: C9H10O2
Molecular Weight: 150.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 140-11-4: AF5075000
LD50/LC50:
CAS# 140-11-4: Draize test, rabbit, skin: 100 mg/24H Moderate; Oral,
mouse: LD50 = 830 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat:
LD50 = 2490 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
TDLo(Oral,rat) = 355 gm/kg/13W-C; Brain and Coverings - other
degenerative changes, Kidney, Ureter, Bladder - changes in tubules
(including acute renal failure, acute tubular necrosis).
Carcinogenicity:
Benzyl acetate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 3.29-4.54 mg/L; 5,15,30
minutes; 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 140-11-4: No information available.
Canada
CAS# 140-11-4 is listed on Canada's DSL List.
CAS# 140-11-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 140-11-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/22/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Cyanophenyl isothiocyanate, 98%
| 2719-32-6 |
|
Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)
| 0-01-1 |
|
Chitosan
| 9012-76-4 |
|
Calcium Chloride, Anhydrous Powder, 96%
| 10043-52-4 |
|
1,2-Bis(2-chloroethoxy)ethane, 97%
| 112-26-5 |
|
Bis(pentamethylcyclopentadienyl)chromium
| 74507-61-2 |
|
Bis(benzene)chromium
| 1271-54-1 |
|
1'-Acetonaphthone, 95%
| 941-98-0 |
|
(Ethylcyclopentadienyl)(triphenylphosphine) copper(I)
| 308847-89-4 |
|
1,2,4-Benzenetricarboxylic acid, 98%
| 528-44-9 |
|
[2.2]Paracyclophane, 98%
| 1633-22-3 |
|
Diphenylmethylbismuthine
| 74724-75-7 |
|
P-Tolylacetic Acid, 99%
| 622-47-9 |
|
Tris(2-methoxyphenyl)bismuthine
| 83724-41-8 |
|
Benzophenone
| 119-61-9 |
|
Tris(cyclopentadienyl)cerium
| 1298-53-9 |
|
Tris(cyclopentadienyl)erbium
| 39330-74-0 |
|
Sodium hydroxide, 0.2 N solution
| 1310-73-2 |
|
1-Naphthylacetic acid, 95%
| 86-87-3 |
|
Benzotriazole
| 95-14-7 |
|
Cinnamyl Acetate, 99%
| 103-54-8 |
|
alpha-Ionone, synthetic
| 127-41-3 |
|
4-Aminobenzyl alcohol, 99%
| 623-04-1 |
|
5-Bromo-6-chloro-3-indoxyl-N-acetyl-beta-D-glucosaminide
| 5609-91-6 |
|
5-Bromo-4-chloro-3-indoxyl-N-acetyl-beta-D-glucosaminide
| 4264-82-8 |
|
2,5-Dimethylphenylhydrazine hydrochloride
| 56737-78-1 |
|
2-Bromophenylacetonitrile, 98%
| 19472-74-3 |
|
Hydroethidine
| 38483-26-0 |
|
(R)-(-)-Epichlorohydrin, 99%
| 106-89-8 |
|
(S)-(+)-Epichlorohydrin, 98%
| 106-89-8 |
|
3-Chloro-2-nitrotoluene
| 5367-26-0 |
|
3-Chloro-4-nitrotoluene
| 38939-88-7 |
|
5-Chloro-2-nitrotoluene, 98%
| 5367-28-2 |
|
3,5-Dichlorophenylhydrazine hydrochloride, 93%
| 63352-99-8 |
|
Acriflavine hydrochloride
| 8063-24-9 |
|
Tributylbismuthine
| 3692-81-7 |
|
Dicarbonyl(pentamethylcyclopentadienyl)chromium dimer
| 37299-12-0 |
|
Dicarbonylcyclopentadienylcobalt
| 12078-25-0 |
|
N,N-Dimethyl-p-Phenylenediamine Monohydrochloride, 90-95%
| 2052-46-2 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.4-1.7 mmolCl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.9-2.1 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 2.8-3.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.6-1.8 mmol Cl/g,
| 9036-15-1 |
|
Benzoyl chloride
| 98-88-4 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.8-2.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 2.5-3.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 0.6-0.8 mmol Cl/g,
| 9036-15-1 |
|
Benzyl acetate, 99+%
| 140-11-4 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 1.4-1.6 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 2.0-2.2 mmol Cl/g,
| 9036-15-1 |
|
|