**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 1310-73-2 |Sodium hydroxide | 0.8 | 215-185-5 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 99.2 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal tract irritation.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid contact with skin and eyes. Avoid breathing spray or mist.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1310-73-2:
United Kingdom, WEL - STEL: 2 mg/m3 STEL
United States OSHA: 2 mg/m3 TWA
Belgium - TWA: 2 mg/m3 VLE
France - VME: 2 mg/m3 VME
Germany: 2 mg/m3 TWA (inhalable fraction)
Japan: 2 mg/m3 Ceiling
Malaysia: 2 mg/m3 Ceiling
Spain: 2 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: odorless
pH: 13 - 20C
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.01
Molecular Formula: NaOH
Molecular Weight: 39.9962
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Prolonged exposure to air.
Incompatibilities with Other Materials:
Metals, acids.
Hazardous Decomposition Products:
Toxic fumes of sodium oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1310-73-2: WB4900000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 1310-73-2: Draize test, rabbit, eye: 400 ug Mild; Draize test,
rabbit, eye: 1% Severe; Draize test, rabbit, eye: 50 ug/24H Severe;
Draize test, rabbit, eye: 1 mg/24H Severe; Draize test, rabbit,
skin: 500 mg/24H Severe.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Sodium hydroxide -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Sodium Hydroxide Solution
Hazard Class: 8
UN Number: UN18
Packing Group: III
IMO
Shipping Name: Sodium Hydroxide Solution
Hazard Class: 8
UN Number: UN18
Packing Group: III
RID/ADR
Shipping Name: Sodium Hydroxide Solution
Hazard Class: 8
UN Number: UN18
Packing group:
USA RQ: CAS# 1310-73-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1310-73-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 1310-73-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 1310-73-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1310-73-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 35 Causes severe burns.
MSDS Creation Date: 5/30/2000 Revision #1 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Cyanophenyl isothiocyanate, 98%
| 2719-32-6 |
|
Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)
| 0-01-1 |
|
Chitosan
| 9012-76-4 |
|
Calcium Chloride, Anhydrous Powder, 96%
| 10043-52-4 |
|
1,2-Bis(2-chloroethoxy)ethane, 97%
| 112-26-5 |
|
Bis(pentamethylcyclopentadienyl)chromium
| 74507-61-2 |
|
Bis(benzene)chromium
| 1271-54-1 |
|
1'-Acetonaphthone, 95%
| 941-98-0 |
|
(Ethylcyclopentadienyl)(triphenylphosphine) copper(I)
| 308847-89-4 |
|
1,2,4-Benzenetricarboxylic acid, 98%
| 528-44-9 |
|
[2.2]Paracyclophane, 98%
| 1633-22-3 |
|
Diphenylmethylbismuthine
| 74724-75-7 |
|
P-Tolylacetic Acid, 99%
| 622-47-9 |
|
Tris(2-methoxyphenyl)bismuthine
| 83724-41-8 |
|
Benzophenone
| 119-61-9 |
|
Tris(cyclopentadienyl)cerium
| 1298-53-9 |
|
Tris(cyclopentadienyl)erbium
| 39330-74-0 |
|
Sodium hydroxide, 0.2 N solution
| 1310-73-2 |
|
1-Naphthylacetic acid, 95%
| 86-87-3 |
|
Benzotriazole
| 95-14-7 |
|
Cinnamyl Acetate, 99%
| 103-54-8 |
|
alpha-Ionone, synthetic
| 127-41-3 |
|
4-Aminobenzyl alcohol, 99%
| 623-04-1 |
|
5-Bromo-6-chloro-3-indoxyl-N-acetyl-beta-D-glucosaminide
| 5609-91-6 |
|
5-Bromo-4-chloro-3-indoxyl-N-acetyl-beta-D-glucosaminide
| 4264-82-8 |
|
2,5-Dimethylphenylhydrazine hydrochloride
| 56737-78-1 |
|
2-Bromophenylacetonitrile, 98%
| 19472-74-3 |
|
Hydroethidine
| 38483-26-0 |
|
(R)-(-)-Epichlorohydrin, 99%
| 106-89-8 |
|
(S)-(+)-Epichlorohydrin, 98%
| 106-89-8 |
|
3-Chloro-2-nitrotoluene
| 5367-26-0 |
|
3-Chloro-4-nitrotoluene
| 38939-88-7 |
|
5-Chloro-2-nitrotoluene, 98%
| 5367-28-2 |
|
3,5-Dichlorophenylhydrazine hydrochloride, 93%
| 63352-99-8 |
|
Acriflavine hydrochloride
| 8063-24-9 |
|
Tributylbismuthine
| 3692-81-7 |
|
Dicarbonyl(pentamethylcyclopentadienyl)chromium dimer
| 37299-12-0 |
|
Dicarbonylcyclopentadienylcobalt
| 12078-25-0 |
|
N,N-Dimethyl-p-Phenylenediamine Monohydrochloride, 90-95%
| 2052-46-2 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.4-1.7 mmolCl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.9-2.1 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 2.8-3.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.6-1.8 mmol Cl/g,
| 9036-15-1 |
|
Benzoyl chloride
| 98-88-4 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 1.8-2.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 1% crosslinked with DVB, 2.5-3.0 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 0.6-0.8 mmol Cl/g,
| 9036-15-1 |
|
Benzyl acetate, 99+%
| 140-11-4 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 1.4-1.6 mmol Cl/g,
| 9036-15-1 |
|
Merrifield polymer resin, 2% crosslinked with DVB, 2.0-2.2 mmol Cl/g,
| 9036-15-1 |
|
|