**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107-18-6 |Allyl Alcohol | 99 | 203-470-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F N
Risk Phrases: 10 23/24/25 36/37/38 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if
swallowed. Irritating to eyes, respiratory system and skin. Very
toxic to aquatic organisms.Lachrymator (substance which increases the
flow of tears).
Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which
increases the flow of tears).
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause central nervous system
depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation:
Harmful if inhaled. May cause severe irritation of the respiratory
tract with sore throat, coughing, shortness of breath and delayed
lung edema. May cause pulmonary edema and severe respiratory
disturbances. Vapors may cause dizziness or suffocation.
Chronic:
May cause liver and kidney damage. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors may
be heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep away from heat, sparks and flame. Do not ingest or
inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Pungent odor.
pH: Not available.
Vapor Pressure: 28 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 97 deg C
Freezing/Melting Point: -50 deg C
Autoignition Temperature: 713 deg F ( 378.33 deg C)
Flash Point: 70 deg F ( 21.11 deg C)
Explosion Limits, lower: 2.5%
Explosion Limits, upper: 18.0%
Decomposition Temperature: Not available.
Solubility in water: Miscible with water.
Specific Gravity/Density: 0.85
Molecular Formula: C3H6O
Molecular Weight: 58.0414
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
May form explosive peroxides. May polymerize. Forms explosive
mixture with air (flash point 70 degrees F).
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, acids, alkali metals, aluminum,
amines, coatings, magnesium, plastics, rubber, sodium hydroxide,
isocyanates, sodium, carbontetrachloride, chlorosulfonic acid,
oleum, metallic halides, diallyl phosphide.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107-18-6: BA5075000
LD50/LC50:
CAS# 107-18-6: Draize test, rabbit, eye: 20 mg Severe; Inhalation,
mouse: LC50 = 500 mg/m3/2H; Inhalation, mouse: LC50 = 500 mg/m3/2H;
Inhalation, rat: LC50 = 76 ppm/8H; Oral, mouse: LD50 = 96 mg/kg;
Oral, mouse: LD50 = 75 mg/kg; Oral, rabbit: LD50 = 52 mg/kg; Oral,
rat: LD50 = 64 mg/kg; Skin, rabbit: LD50 = 45 mg/kg.
Carcinogenicity:
Allyl Alcohol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Goldfish: LC50 = 1 mg/L; 24 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 216-608 mg/L; 5,15,30 Minutes;
Microtox test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1
UN Number: 1098
Packing Group:
IMO
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1
UN Number: 1098
Packing Group: I
RID/ADR
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1
UN Number: 1098
Packing group: I
USA RQ:CAS# 107-18-6: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F N
Risk Phrases:
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 107-18-6: 2
United Kingdom Occupational Exposure Limits
CAS# 107-18-6: OES-United Kingdom, TWA 2 ppm TWA; 4.8 mg/m3 TWA
CAS# 107-18-6: OES-United Kingdom, STEL 4 ppm STEL; 9.7 mg/m3 STEL
United Kingdom Maximum Exposure Limits
Canada
CAS# 107-18-6 is listed on Canada's DSL List.
CAS# 107-18-6 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 107-18-6: OEL-ARAB Republic of Egypt:TWA 2 ppm (5 mg/m3);Skin
OEL-AUSTRALIA:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3);Skin
OEL-AUSTRIA:TWA 2 ppm (5 mg/m3);Skin
OEL-BELGIUM:TWA 2 ppm (4.8 mg/m3);STEL 4 ppm (9.5 mg/m3);Skin
OEL-CZECHOSLOVAKIA:TWA 3 mg/m3;STEL 6 mg/m3
OEL-DENMARK:TWA 2 ppm (5 mg/m3);Skin
OEL-FINLAND:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3);Skin
OEL-FRANCE:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3);Skin
OEL-GERMANY:TWA 2 ppm (5 mg/m3);Skin
OEL-HUNGARY:TWA 3 mg/m3;STEL 6 mg/m3;Skin
OEL-JAPAN:TWA 1 ppm (2.4 mg/m3);Skin
OEL-THE NETHERLANDS:TWA 2 ppm (5 mg/m3);Skin JAN9
OEL-THE PHILIPPINES:TWA 2 ppm (5 mg/m3);Skin JAN9
OEL-POLAND:TWA 2 mg/m3;STEL 10 mg/m3;Skin
OEL-RUSSIA:TWA 1 ppm
OEL-SWEDEN:TWA 2 ppm (5 mg/m3);STEL 6 ppm (14 mg/m3);Skin
OEL-SWITZERLAND:TWA 2 ppm (5 mg/m3);STEL 4 ppm (1 mg/m3);Skin
OEL-TURKEY:TWA 2 ppm (5 mg/m3);Skin
OEL-UNITED KINGDOM:TWA 2 ppm (6 mg/m3);STEL 4 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 107-18-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/10/1999 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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