**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 288-94-8 |1H-Tetrazole | 98.0 | 206-023-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O
Risk Phrases: 5 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Heating may cause an explosion. Contact with combustible material
may cause fire.
Potential Health Effects
Eye:
May cause conjunctivitis. May cause permanent corneal
opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea,
vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and
upper airway obstruction caused by edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Contact professional fire-fighters
immediately.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up,
then place into a suitable container for disposal. Remove all
sources of ignition. In case of spill, sweep up solid or absorb
liquid with inert material, then place into a biohazard container.
Wear protective equipment.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid contact with clothing and other combustible
materials. Do not get on skin or in eyes. Avoid ingestion and
inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry place. Keep container
closed when not in use. Keep refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local exhaust ventilation to keep airborne concentrations
below the permissible exposure limits. Use process enclosure, local
exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 288-94-8:
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible. Wear appropriate protective eyeglasses or
chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or
European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate gloves to
prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to minimize contact with skin. Wear
appropriate clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 156.00 - 158.00 deg C
Autoignition Temperature: Not available.
Flash Point: 220 deg C ( 428.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 220 deg C
Solubility in water: 23g/100ml (20 c)
Specific Gravity/Density:
Molecular Formula: CH2N4
Molecular Weight: 70.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation,
combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 288-94-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1H-Tetrazole -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.*
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
IMO
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 5 Heating may cause an explosion.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 288-94-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 288-94-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 288-94-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/04/1999 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zinc, Granular, 20 Mesh, P.A.
| 7440-66-6 |
|
Zinc, Granular, 30 Mesh, P.A.
| 7440-66-6 |
|
Zinc, Dust (Pract)
| 7440-66-6 |
|
Beta-Ionone, Synthetic, 98%
| 14901-07-6 |
|
Beta-Ionone, 96% (Titr.)
| 14901-07-6 |
|
Allyl Alcohol, 99%
| 107-18-6 |
|
3,3'-Dimethoxybenzidine dihydrochloride, 99%
| 20325-40-0 |
|
Pyridoxine Hydrochloride, 99.0-101.0% (Dry Substance)
| 58-56-0 |
|
4-Nitrophenyl Chloroformate, 97%
| 7693-46-1 |
|
Methyl Oleate
| 112-62-9 |
|
Ethyl iodoacetate, 98%
| 623-48-3 |
|
2-Hydroxyisobutyric acid, 98%
| 594-61-6 |
|
Basic Fuchsin (Cert)
| 632-99-5 |
|
Ethylene/vinyl acetate copolymer 14% vinyl acetate
| 24937-78-8 |
|
Methacrolein, 90-95%(GC), stabilized with hydroquinone
| 78-85-3 |
|
Ethylene/vinyl acetate copolymer 25% vinyl acetate, average
| 24937-78-8 |
|
Ethylene/vinyl acetate copolymer 28% vinyl acetate, avge.m.w.285.000
| 24937-78-8 |
|
Ethylene/vinyl acetate copolymer, pellets, avr. m.w.110000, stab.
| 24937-78-8 |
|
Ammonium sulfobetaine - 1
| |
|
2-Aminopyridine
| 504-29-0 |
|
D,L-Buthionine, 97%
| 3343-64-4 |
|
2-Chloroethanol, 99%
| 107-07-3 |
|
Resazurin, sodium salt, high purity biological stain
| 62758-13-8 |
|
Phenyl isocyanate, 99%
| 103-71-9 |
|
Triethanolamine hydrochloride, p.a.
| 637-39-8 |
|
Allyl Chloride, 98%
| 107-05-1 |
|
2-Hydroxyethyl methacrylate, 96%, stabilized with 200-400 ppm MEHQ
| 150-76-5 |
|
Poly(ethylene), low density, average m.w.50000
| 9002-88-4 |
|
Tributylborane, 1M solution in THF
| 109-99-9 |
|
Polysulfone Resin. Nominal M.W. 75000, (GPC) , Pellets
| 25135-51-7 |
|
4-Chlorophenol, 98%
| 106-48-9 |
|
4-Chlorophenol (Pract)
| 106-48-9 |
|
Trichloroacetonitrile, 98%
| 545-06-2 |
|
3-Diethylamino-1-propanol, 97%
| 622-93-5 |
|
1,6-Hexanediol, 99% -Total C6-Diols
| 629-11-8 |
|
Fullerene c60, 99.9+% (hplc)
| 99685-96-8 |
|
Fullerene c-60
| 99685-96-8 |
|
1H-Tetrazole, 98%
| 288-94-8 |
|
1,2,3,4-Tetrahydro-6,7-isoquinolinediol hy drobromide, 98%
| 52768-23-7 |
|
3,4-Dimethylphenylhydrazine Hydrochloride, 98%
| 60481-51-8 |
|
Ethyl p-toluenesulfonate, 98%
| 80-40-0 |
|
Dl-mandelic acid, 98+%
| 611-72-3 |
|
Phenanthrene, 98+%
| 85-01-8 |
|
Phenanthrene, fluorescent grade, 98% (uv-vis)
| 85-01-8 |
|
Dipropyl adipate
| 106-19-4 |
|
Aniline blue, water soluble, high purity biological stain
| 28631-66-5 |
|
L(-)-Malic acid, 99%
| 97-67-6 |
|
Bromothymol blue, water soluble indicator
| 34722-90-2 |
|
Bromocresol Green, Water Soluble, Indicator
| 67763-24-0 |
|
Bromophenol Blue Indicator
| 115-39-9 |
|
|