**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 504-29-0 |2-Aminopyridine | > 99 | 207-988-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. Causes redness and pain.
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
Substance is rapidly absorbed through the skin. Causes symptoms
similar to those of inhalation. Causes redness and pain.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive
tract. Poison by ingestion. May cause effects similar to those for
inhalation exposure.
Inhalation:
Causes respiratory tract irritation. May cause severe headaches,
nausea, increased blood pressure, weakness, convulsions, and a
stuporous state.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Containers may explode in the heat of a fire. Combustible solid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or
on clothing. Keep away from heat, sparks and flame. Do not ingest or
inhale. Use only in a chemical fume hood.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Poison room
locked.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use only under a chemical fume hood.
Exposure Limits
CAS# 504-29-0:
United Kingdom, WEL - TWA: 0.5 ppm TWA; 2 mg/m3 TWA
United Kingdom, WEL - STEL: 2 ppm STEL; 7.8 mg/m3 STEL
United States OSHA: 0.5 ppm TWA; 2 mg/m3 TWA
Belgium - TWA: 0.5 ppm VLE; 1.9 mg/m3 VLE
France - VME: 0.5 ppm VME; 2 mg/m3 VME
Germany: 0.5 ppm TWA; 2 mg/m3 TWA
Malaysia: 0.5 ppm TWA; 1.9 mg/m3 TWA
Netherlands: 0.5 ppm MAC; 2 mg/m3 MAC
Spain: 0.5 ppm VLA-ED; 1.9 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: cream - beige
Odor: Faint, characteristic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 204 - 210 deg C @ 760 mm Hg
Freezing/Melting Point: 59 - 60 deg C
Autoignition Temperature: Not available.
Flash Point: 92 deg C ( 197.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: C5H6N2
Molecular Weight: 94.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 504-29-0: US1575000
LD50/LC50:
CAS# 504-29-0: Dermal, guinea pig: LD50 = 500 mg/kg; Oral, mouse:
LD50 = 145 mg/kg; Oral, rat: LD50 = 200 mg/kg.
TCLo (Inhalation, Human) = 5
Carcinogenicity:
2-Aminopyridine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = 2.82 - 7.56 mg/L; 96 Hr.; 12-22
degrees CBacteria: Phytobacterium phosphoreum: EC50 = 248-284 mg/L;
5, 15, 30 minutes; Microtox test; 15 degrees CBioaccumulation: none
or low
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINOPYRIDINES
Hazard Class: 6.1
UN Number: 2671
Packing Group: II
IMO
Shipping Name: AMINOPYRIDINES
Hazard Class: 6.1
UN Number: 2671
Packing Group: II
RID/ADR
Shipping Name: AMINOPYRIDINES
Hazard Class: 6.1
UN Number: 2671
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 504-29-0: No information available.
Canada
CAS# 504-29-0 is listed on Canada's DSL List.
CAS# 504-29-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 504-29-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/19/1999 Revision #4 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zinc, Granular, 20 Mesh, P.A.
| 7440-66-6 |
|
Zinc, Granular, 30 Mesh, P.A.
| 7440-66-6 |
|
Zinc, Dust (Pract)
| 7440-66-6 |
|
Beta-Ionone, Synthetic, 98%
| 14901-07-6 |
|
Beta-Ionone, 96% (Titr.)
| 14901-07-6 |
|
Allyl Alcohol, 99%
| 107-18-6 |
|
3,3'-Dimethoxybenzidine dihydrochloride, 99%
| 20325-40-0 |
|
Pyridoxine Hydrochloride, 99.0-101.0% (Dry Substance)
| 58-56-0 |
|
4-Nitrophenyl Chloroformate, 97%
| 7693-46-1 |
|
Methyl Oleate
| 112-62-9 |
|
Ethyl iodoacetate, 98%
| 623-48-3 |
|
2-Hydroxyisobutyric acid, 98%
| 594-61-6 |
|
Basic Fuchsin (Cert)
| 632-99-5 |
|
Ethylene/vinyl acetate copolymer 14% vinyl acetate
| 24937-78-8 |
|
Methacrolein, 90-95%(GC), stabilized with hydroquinone
| 78-85-3 |
|
Ethylene/vinyl acetate copolymer 25% vinyl acetate, average
| 24937-78-8 |
|
Ethylene/vinyl acetate copolymer 28% vinyl acetate, avge.m.w.285.000
| 24937-78-8 |
|
Ethylene/vinyl acetate copolymer, pellets, avr. m.w.110000, stab.
| 24937-78-8 |
|
Ammonium sulfobetaine - 1
| |
|
2-Aminopyridine
| 504-29-0 |
|
D,L-Buthionine, 97%
| 3343-64-4 |
|
2-Chloroethanol, 99%
| 107-07-3 |
|
Resazurin, sodium salt, high purity biological stain
| 62758-13-8 |
|
Phenyl isocyanate, 99%
| 103-71-9 |
|
Triethanolamine hydrochloride, p.a.
| 637-39-8 |
|
Allyl Chloride, 98%
| 107-05-1 |
|
2-Hydroxyethyl methacrylate, 96%, stabilized with 200-400 ppm MEHQ
| 150-76-5 |
|
Poly(ethylene), low density, average m.w.50000
| 9002-88-4 |
|
Tributylborane, 1M solution in THF
| 109-99-9 |
|
Polysulfone Resin. Nominal M.W. 75000, (GPC) , Pellets
| 25135-51-7 |
|
4-Chlorophenol, 98%
| 106-48-9 |
|
4-Chlorophenol (Pract)
| 106-48-9 |
|
Trichloroacetonitrile, 98%
| 545-06-2 |
|
3-Diethylamino-1-propanol, 97%
| 622-93-5 |
|
1,6-Hexanediol, 99% -Total C6-Diols
| 629-11-8 |
|
Fullerene c60, 99.9+% (hplc)
| 99685-96-8 |
|
Fullerene c-60
| 99685-96-8 |
|
1H-Tetrazole, 98%
| 288-94-8 |
|
1,2,3,4-Tetrahydro-6,7-isoquinolinediol hy drobromide, 98%
| 52768-23-7 |
|
3,4-Dimethylphenylhydrazine Hydrochloride, 98%
| 60481-51-8 |
|
Ethyl p-toluenesulfonate, 98%
| 80-40-0 |
|
Dl-mandelic acid, 98+%
| 611-72-3 |
|
Phenanthrene, 98+%
| 85-01-8 |
|
Phenanthrene, fluorescent grade, 98% (uv-vis)
| 85-01-8 |
|
Dipropyl adipate
| 106-19-4 |
|
Aniline blue, water soluble, high purity biological stain
| 28631-66-5 |
|
L(-)-Malic acid, 99%
| 97-67-6 |
|
Bromothymol blue, water soluble indicator
| 34722-90-2 |
|
Bromocresol Green, Water Soluble, Indicator
| 67763-24-0 |
|
Bromophenol Blue Indicator
| 115-39-9 |
|
|