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| **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| | 545-06-2 |Trichloroacetonitrile | 98.0 | 208-885-7 | +----------------+--------------------------------------+----------+-----------+ Hazard Symbols: T Risk Phrases: 23/24/25 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Toxic by inhalation, in contact with skin and if swallowed.Toxic. Potential Health Effects Eye: Causes severe eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes severe skin irritation. Harmful if absorbed through the skin. Effects of contact may be delayed. Ingestion: Harmful if swallowed. Causes digestive tract irritation. Inhalation: May cause respiratory tract irritation. Effects of inhalation may be delayed. Chronic: No information found. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Antidote: None reported. **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. **** SECTION 7 - HANDLING and STORAGE **** Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Keep containers tightly closed. **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION **** Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 545-06-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES **** Physical State: Liquid or Crystals Color: colorless Odor: hydrogen cyanide pH: Not available. Vapor Pressure: 58 mmHg @ 20 C Viscosity: Not available. Boiling Point: 83 - 84 deg C @ 760.00mm Hg Freezing/Melting Point: -42 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: N/A Explosion Limits, upper: N/A Decomposition Temperature: Solubility in water: soluble in acetone, dimethyl sulfoxide, Specific Gravity/Density: 1.4400g/cm3 Molecular Formula: C2Cl3N Molecular Weight: 144.39 **** SECTION 10 - STABILITY AND REACTIVITY **** Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong acids - strong bases - strong oxidizing agents - strong reducing agents. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen, cyanides, chlorine. Hazardous Polymerization: Has not been reported. **** SECTION 11 - TOXICOLOGICAL INFORMATION **** RTECS#: CAS# 545-06-2: AM2450000 LD50/LC50: CAS# 545-06-2: Draize test, rabbit, eye: 50 ug/24H Severe; Draize test, rabbit, skin: 5 mg/24H Severe; Oral, rat: LD50 = 250 mg/kg; Skin, rabbit: LD50 = 900 uL/kg. Not available. Carcinogenicity: Trichloroacetonitrile - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. **** SECTION 12 - ECOLOGICAL INFORMATION **** Other No information available. **** SECTION 13 - DISPOSAL CONSIDERATIONS **** Dispose of in a manner consistent with federal, state, and local regulations. **** SECTION 14 - TRANSPORT INFORMATION **** IATA Shipping Name: NITRILES, LIQUID, TOXIC, N.O.S.* Hazard Class: 6.1 UN Number: 3276 Packing Group: II IMO Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing Group: II RID/ADR Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing group: II **** SECTION 15 - REGULATORY INFORMATION **** European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T Risk Phrases: R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. Safety Phrases: S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 545-06-2: No information available. Canada CAS# 545-06-2 is listed on Canada's DSL List. CAS# 545-06-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 545-06-2 is listed on the TSCA inventory. **** SECTION 16 - ADDITIONAL INFORMATION **** MSDS Creation Date: 2/04/1999 Revision #2 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- |
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