**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-21-4 |Isopropyl acetate | 99.0 | 203-561-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Prolonged and/or repeated contact may cause defatting of the skin
and dermatitis. May cause skin burns. Chronic exposure may cause
liver damage.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Inhalation of vapor may cause respiratory tract irritation.
May cause effects similar to those described for ingestion. May cause
narcotic effects in high concentration. Causes irritation of mucous
membrane.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. Prolonged or repeated skin
contact may cause defatting and dermatitis. Chronic exposure may
cause liver damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Combustion
generates toxic fumes. During a fire, irritating and highly toxic
gases may be generated by thermal decomposition or combustion. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use water spray, dry chemical, carbon dioxide, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area
away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 108-21-4:
United Kingdom, WEL - STEL: 200 ppm STEL; 849 mg/m3 STEL
United States OSHA: 250 ppm TWA; 950 mg/m3 TWA
Belgium - TWA: 250 ppm VLE; 1055 mg/m3 VLE
Belgium - STEL: 310 ppm VLE; 1309 mg/m3 VLE
France - VME: 250 ppm VME; 950 mg/m3 VME
France - VLE: 300 ppm VLE; 1140 mg/m3 VLE
Germany: 100 ppm TWA; 420 mg/m3 TWA
Malaysia: 250 ppm TWA; 1040 mg/m3 TWA
Spain: 250 ppm VLA-ED; 1060 mg/m3 VLA-ED
Spain: 310 ppm VLA-EC; 1315 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: acetic odor
pH: Not available.
Vapor Pressure: 47.5 mm Hg @20C
Viscosity: 0.60mPa.s @20c
Boiling Point: 85 deg C
Freezing/Melting Point: -62 deg C
Autoignition Temperature: 479 deg C ( 894.20 deg F)
Flash Point: 2 deg C ( 35.60 deg F)
Explosion Limits, lower: 1.76
Explosion Limits, upper: 7.2
Decomposition Temperature:
Solubility in water: Slightly soluble in water
Specific Gravity/Density: 0.87
Molecular Formula: CH3COOCH(CH3)2
Molecular Weight: 102.0688
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, bases, acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-21-4: AI4930000
LD50/LC50:
CAS# 108-21-4: Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, rat: LC50 = 50600 mg/m3/8H; Oral, rabbit: LD50 = 6946
mg/kg; Oral, rat: LD50 = 6750 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
Carcinogenicity:
Isopropyl acetate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOPROPYL ACETATE
Hazard Class: 3
UN Number: 1220
Packing Group: II
IMO
Shipping Name: ISOPROPYL ACETATE
Hazard Class: 3.2
UN Number: 1220
Packing Group: II
RID/ADR
Shipping Name: ISOPROPYL ACETATE
Hazard Class: 3
UN Number: 1220
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 108-21-4: 1
Canada
CAS# 108-21-4 is listed on Canada's DSL List.
CAS# 108-21-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-21-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-tert.-Butylbenzoic acid, 99%
| 98-73-7 |
|
Sodium bisulfite, powder, p.a.
| 7446-09-5 |
|
1,2-Dibromoethane, 99%
| 106-93-4 |
|
1,2-Dichloroethane, 99.8+% (GC)
| 107-06-2 |
|
1,2-Dichloroethane, laser grade
| 107-06-2 |
|
1,2-Dichloroethane, reagent ACS
| 107-06-2 |
|
1,2-Dichloroethane, reagent ACS, spectro grade, 99+%
| 107-06-2 |
|
HEPES, Sodium Salt, 99%
| 75277-39-3 |
|
n-Butyl Lactate, 99% (GC)
| 138-22-7 |
|
Ethylenediamine
| 107-15-3 |
|
4-Chlorophenyl isocyanate
| 104-12-1 |
|
Iron (III) Chloride, Anhydrous, 98%
| 7705-08-0 |
|
N-(2-Chloroethyl)-Morpholine Hydrochloride, 99%
| 3647-69-6 |
|
Iron(iii) chloride hexahydrate, granulated, c.p.
| 10025-77-1 |
|
Iron(iii) chloride hexahydrate, p.a.
| 10025-77-1 |
|
Iron(iii) chloride hexahydrate, reagent acs
| 10025-77-1 |
|
4-(Trifluoromethyl)Benzophenone, 97%
| 728-86-9 |
|
s-(4-Nitrobenzyl)-6-thioinosine
| 38048-32-7 |
|
2,6-Dichlorobenzyl Alcohol, 99%
| 15258-73-8 |
|
Iron(III) nitrate nonahydrate, p.a.
| 7782-61-8 |
|
Isopropyl Acetate, 99%
| 108-21-4 |
|
Iron(II) sulfate heptahydrate, p.a.
| 7720-78-7 |
|
Florisil, 100-200 mesh
| 1343-88-0 |
|
Tetramethylsilane, 99.9+% ,NMR Grade
| 75-76-3 |
|
Diphosphorus Tetraiodide, 95%
| 13455-00-0 |
|
Epichlorohydrin
| 106-89-8 |
|
Formamide, 99.5+%
| 75-12-7 |
|
Formamide, polarographic and nonaqueous, titration grade
| 75-12-7 |
|
Formamide, spectro grade
| 75-12-7 |
|
Formamide, reagent ACS
| 75-12-7 |
|
Patent blue vf, indicator grade
| 129-17-9 |
|
Acid Fuchsin, High Purity Biological Stain
| 3244-88-0 |
|
Fumaric acid, 99%
| 110-17-8 |
|
Phenyl dichlorophosphate, 99%
| 770-12-7 |
|
2-Furaldehyde, 99%
| 98-01-1 |
|
D-(+)-Galactose, 99+%
| 59-23-4 |
|
1-Tetradecanol, 99+%
| 112-72-1 |
|
Gallic Acid, Monohydrate, C.P.
| 149-91-7 |
|
Metanil yellow, 98% (TLC)
| 587-98-4 |
|
Crystal Violet, Indicator
| 548-62-9 |
|
Sodium triethylborohydride, 1M solution in tetrahydrofuran
| 109-99-9 |
|
Crystal Violet (Cert), Reagent ACS
| 548-62-9 |
|
Glycerol, 99+%
| 56-81-5 |
|
Glycerol, 83.5-88.5 Wt % Aqueous Solution
| 56-81-5 |
|
Glycerol, Reagent ACS
| 56-81-5 |
|
Glycerol, 86-88%, P.A.
| 56-81-5 |
|
Glycine, 98%
| 56-40-6 |
|
Phthalic Anhydride, 99%
| 85-44-9 |
|
Phthalic Anhydride, Reagent acs
| 85-44-9 |
|
n-Decylamine 96%
| 2016-57-1 |
|
|