**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 85-44-9 |Phthalic anhydride | 99 | 201-607-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI C
Risk Phrases: 34 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Irritating to eyes, respiratory system and
skin.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. Contact with eyes may cause severe irritation,
and possible eye burns. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May cause severe irritation and possible burns. May cause skin rash
(in milder cases), and cold and clammy skin with cyanosis or pale
color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause irritation of the digestive tract and possible
burns. May cause systemic effects.
Inhalation:
May cause asthmatic attacks due to allergic sensitization of the
respiratory tract. Causes chemical burns to the respiratory tract.
May cause severe respiratory tract irritation and possible burns.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Gently lift eyelids and flush continuously with water.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Dust can be an
explosion hazard when exposed to heat or flame. Reacts with water to
form explosive hydrogen gas. Flammable solid. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated or if contaminated
with water.
Extinguishing Media:
Do NOT get water inside containers. For large fires, use water
spray, fog or alcohol-resistant foam. Do NOT use straight streams of
water. For small fires, use carbon dioxide, dry chemical, dry sand,
or alcohol-resistant foam. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Remove all sources of ignition. Use a spark-proof
tool. Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Use with adequate ventilation. Ground and bond containers when
transferring material. Do not breathe dust, vapor, mist, or gas. Do
not get in eyes, on skin, or on clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Do not ingest or inhale. Do not allow
contact with water. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local exhaust ventilation to keep airborne concentrations
below the permissible exposure limits.
Exposure Limits
CAS# 85-44-9:
United Kingdom, WEL - TWA: 4 mg/m3 TWA
United Kingdom, WEL - STEL: 12 mg/m3 STEL
United States OSHA: 2 ppm TWA; 12 mg/m3 TWA
Belgium - TWA: 1 ppm VLE; 6.2 mg/m3 VLE
France - VLE: 6 mg/m3 VLE
Germany: 1 mg/m3 TWA (inhalable fraction)
Japan: 0.33 ppm Ceiling; 0.2 mg/m3 Ceiling
Malaysia: 1 ppm TWA; 6.1 mg/m3 TWA
Netherlands: 2 mg/m3 STEL
Netherlands: 1 mg/m3 MAC
Russia: 1 mg/m3 TWA
Spain: 1 ppm VLA-ED; 6 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: White
Odor: acrid odor
pH: Not available.
Vapor Pressure: 0.01 mbar @ 20
Viscosity: 6.4 MP 97.00 deg C
Boiling Point: 284 deg C @ 760.00mm Hg
Freezing/Melting Point: 131.0 - 133.0 deg C
Autoignition Temperature: 580 deg C ( 1,076.00 deg F)
Flash Point: 152 deg C ( 305.60 deg F)
Explosion Limits, lower: 1.70 vol %
Explosion Limits, upper: 10.50 vol %
Decomposition Temperature:
Solubility in water: in water: 6g/l (forming phthalic acid)
Specific Gravity/Density: 1.5300g/cm3
Molecular Formula: C8H4O3
Molecular Weight: 148.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 85-44-9: TI3150000
LD50/LC50:
CAS# 85-44-9: Draize test, rabbit, eye: 50 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >210
mg/m3/1H; Oral, mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 = 1530
mg/kg; Skin, rabbit: LD50 = >10 gm/kg.
Carcinogenicity:
Phthalic anhydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHTHALIC ANHYDRIDE
Hazard Class: 8
UN Number: 2214
Packing Group: III
IMO
Shipping Name: PHTHALIC ANHYDRIDE
Hazard Class: 8
UN Number: 2214
Packing Group: III
RID/ADR
Shipping Name: PHTHALIC ANHYDRIDE
Hazard Class: 8
UN Number: 2214
Packing group: III
USA RQ: CAS# 85-44-9: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI C
Risk Phrases:
R 34 Causes burns.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 85-44-9: 0
Canada
CAS# 85-44-9 is listed on Canada's DSL List.
CAS# 85-44-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 85-44-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/19/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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| ALL MSDS PAGES IN THIS GROUP
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| 98-73-7 |
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Sodium bisulfite, powder, p.a.
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1,2-Dibromoethane, 99%
| 106-93-4 |
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1,2-Dichloroethane, 99.8+% (GC)
| 107-06-2 |
|
1,2-Dichloroethane, laser grade
| 107-06-2 |
|
1,2-Dichloroethane, reagent ACS
| 107-06-2 |
|
1,2-Dichloroethane, reagent ACS, spectro grade, 99+%
| 107-06-2 |
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HEPES, Sodium Salt, 99%
| 75277-39-3 |
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n-Butyl Lactate, 99% (GC)
| 138-22-7 |
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Ethylenediamine
| 107-15-3 |
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4-Chlorophenyl isocyanate
| 104-12-1 |
|
Iron (III) Chloride, Anhydrous, 98%
| 7705-08-0 |
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N-(2-Chloroethyl)-Morpholine Hydrochloride, 99%
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Iron(iii) chloride hexahydrate, granulated, c.p.
| 10025-77-1 |
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Iron(iii) chloride hexahydrate, p.a.
| 10025-77-1 |
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Iron(iii) chloride hexahydrate, reagent acs
| 10025-77-1 |
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4-(Trifluoromethyl)Benzophenone, 97%
| 728-86-9 |
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s-(4-Nitrobenzyl)-6-thioinosine
| 38048-32-7 |
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2,6-Dichlorobenzyl Alcohol, 99%
| 15258-73-8 |
|
Iron(III) nitrate nonahydrate, p.a.
| 7782-61-8 |
|
Isopropyl Acetate, 99%
| 108-21-4 |
|
Iron(II) sulfate heptahydrate, p.a.
| 7720-78-7 |
|
Florisil, 100-200 mesh
| 1343-88-0 |
|
Tetramethylsilane, 99.9+% ,NMR Grade
| 75-76-3 |
|
Diphosphorus Tetraiodide, 95%
| 13455-00-0 |
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Epichlorohydrin
| 106-89-8 |
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Formamide, 99.5+%
| 75-12-7 |
|
Formamide, polarographic and nonaqueous, titration grade
| 75-12-7 |
|
Formamide, spectro grade
| 75-12-7 |
|
Formamide, reagent ACS
| 75-12-7 |
|
Patent blue vf, indicator grade
| 129-17-9 |
|
Acid Fuchsin, High Purity Biological Stain
| 3244-88-0 |
|
Fumaric acid, 99%
| 110-17-8 |
|
Phenyl dichlorophosphate, 99%
| 770-12-7 |
|
2-Furaldehyde, 99%
| 98-01-1 |
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D-(+)-Galactose, 99+%
| 59-23-4 |
|
1-Tetradecanol, 99+%
| 112-72-1 |
|
Gallic Acid, Monohydrate, C.P.
| 149-91-7 |
|
Metanil yellow, 98% (TLC)
| 587-98-4 |
|
Crystal Violet, Indicator
| 548-62-9 |
|
Sodium triethylborohydride, 1M solution in tetrahydrofuran
| 109-99-9 |
|
Crystal Violet (Cert), Reagent ACS
| 548-62-9 |
|
Glycerol, 99+%
| 56-81-5 |
|
Glycerol, 83.5-88.5 Wt % Aqueous Solution
| 56-81-5 |
|
Glycerol, Reagent ACS
| 56-81-5 |
|
Glycerol, 86-88%, P.A.
| 56-81-5 |
|
Glycine, 98%
| 56-40-6 |
|
Phthalic Anhydride, 99%
| 85-44-9 |
|
Phthalic Anhydride, Reagent acs
| 85-44-9 |
|
n-Decylamine 96%
| 2016-57-1 |
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