**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 108-32-7 |Propylene carbonate | 45-50 | 203-572-1 |
|----------------|--------------------------------------|----------|-----------|
| 111-90-0 |Diethylene glycol monoethyl ether | 30-35 | 203-919-7 |
|----------------|--------------------------------------|----------|-----------|
| 1122-58-3 |4-Dimethylaminopyridine | 5-10 | 214-353-5 |
|----------------|--------------------------------------|----------|-----------|
| 7446-09-5 |Sulfur dioxide | 1-5 | 231-195-2 |
|----------------|--------------------------------------|----------|-----------|
| 7553-56-2 |Iodine | < 5 | 231-442-4 |
|----------------|--------------------------------------|----------|-----------|
| 17252-51-6 |1,3-di-4-pyridylpropane | 5-10.0 | 241-284-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May produce aplastic anemia with
tremors and marked mental dullness. May produce blood disturbances
with or without neurological signs.
Inhalation:
May be harmful if inhaled. Causes upper respiratory tract
irritation. May cause edema of lungs or glottis and can produce
respiratory paralysis. May cause irritation and burning of the eyes,
tearing, coughing and irritation of nose and throat.
Chronic:
Chronic exposure can affect thyroid function.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases may
be generated by thermal decomposition or combustion. Use water spray
to keep fire-exposed containers cool. Vapors may be heavier than
air. They can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Do not flush into a sewer. Clean up
spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Do not store in direct sunlight. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 108-32-7:
Russia: 7 mg/m3 TWA
CAS# 111-90-0:
Netherlands: 32 ppm MAC; 180 mg/m3 MAC
CAS# 1122-58-3:
CAS# 7446-09-5:
United States OSHA: 5 ppm TWA; 13 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE
Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 5 ppm VLE; 10 mg/m3 VLE
Germany: 1 ppm TWA (paper production, chemical and pharmaceutical
industries); 2.5 mg/m3
Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA
Netherlands: 2 ppm MAC; 5 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED
Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC
CAS# 7553-56-2:
United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL
United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling
Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE
France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE
Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA
Germany: Skin absorber
Japan: 0.1 ppm OEL; 1 mg/m3 OEL
Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling
Russia: 1 mg/m3 TWA
Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC
CAS# 17252-51-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 105 deg C ( 221.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 1.14
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Metals, oxidizing agents, acrolein, aluminum, chlorates, chlorine
trifluoride, fluorine, halogens, iron oxide, potassium chlorates,
cesium acetylene carbide, rubidium acetylene carbide, sodium
acetylene carbide, acids (mineral, non-oxidizing, e.g. hydrochloric
acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids
(organic, e.g. acetic acid, benzoic acid, formic acid, methanoic
acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol,
ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde,
acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide,
diethyltoluamide, dimethyl formamide), amines (aliphatic and
aromatic, e.g. dimethyl amine, propylamine, pyridine,
triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine,
hydrazine, methyl hydrazine), carbamates (e.g. carbanolate,
carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide),
dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g.
butyl acetate, ethyl acetate, propyl fo.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-32-7: FF9650000
CAS# 111-90-0: KK8750000
CAS# 1122-58-3: US9230000
CAS# 7446-09-5: WS4550000
CAS# 7553-56-2: NN1575000
CAS# 17252-51-6 unlisted.
LD50/LC50:
CAS# 108-32-7: Draize test, rabbit, eye: 60 mg Moderate; Draize
test, rabbit, skin: 500 mg Moderate; Inhalation, rat: LC50 = >5
gm/m3; Oral, mouse: LD50 = 20700 mg/kg; Oral, rat: LD50 = 29100
uL/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test,
rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild;
Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 =
>5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 =
7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500
uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg;
Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
CAS# 1122-58-3: Oral, rat: LD50 = 250 mg/kg; Skin, rabbit: LD50 = 13
mg/kg.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild;
Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520
ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 =
1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14
gm/kg.
CAS# 17252-51-6.
Carcinogenicity:
Propylene carbonate -
Not listed by ACGIH, IARC, or NTP.
Diethylene glycol monoethyl ether -
Not listed by ACGIH, IARC, or NTP.
4-Dimethylaminopyridine -
Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide -
Not listed by ACGIH, IARC, or NTP.
Iodine -
Not listed by ACGIH, IARC, or NTP.
1,3-di-4-pyridylpropane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Cas# 111-90-0:
The Koc of diethylene glycol monoethyl ether is
estimated as approximately 12, using a measured log Kow of -0.54 and
a regression-derived equation. According to a recommended
classification scheme, this estimated Koc value suggests that
diethylene glycol monoethyl ether has very high mobility in soil.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 108-32-7: 0
CAS# 111-90-0: 1
CAS# 1122-58-3: No information available.
CAS# 7446-09-5: 1
CAS# 7553-56-2: 1
CAS# 17252-51-6: No information available.
Canada
CAS# 108-32-7 is listed on Canada's DSL List.
CAS# 111-90-0 is listed on Canada's DSL List.
CAS# 1122-58-3 is listed on Canada's DSL List.
CAS# 7446-09-5 is listed on Canada's DSL List.
CAS# 7553-56-2 is listed on Canada's DSL List.
CAS# 17252-51-6 is listed on Canada's NDSL List.
CAS# 108-32-7 is listed on Canada's Ingredient Disclosure List.
CAS# 111-90-0 is listed on Canada's Ingredient Disclosure List.
CAS# 1122-58-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 7446-09-5 is listed on Canada's Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canada's Ingredient Disclosure List.
CAS# 17252-51-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-32-7 is listed on the TSCA inventory.
CAS# 111-90-0 is listed on the TSCA inventory.
CAS# 1122-58-3 is listed on the TSCA inventory.
CAS# 7446-09-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
CAS# 17252-51-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 6/09/1999 Revision #3 Date: 9/06/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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