**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methanol | 53.0 | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 108-32-7 |Propylene carbonate | 13.0 | 203-572-1 |
|----------------|--------------------------------------|----------|-----------|
| 111-42-2 |Diethanolamine | 8.0 | 203-868-0 |
|----------------|--------------------------------------|----------|-----------|
| 7446-09-5 |Sulfur dioxide | 5 | 231-195-2 |
|----------------|--------------------------------------|----------|-----------|
| 7553-56-2 |Iodine | 1.0 | 231-442-4 |
|----------------|--------------------------------------|----------|-----------|
| 17252-51-6 |1,3-Di-4-pyridylpropane | 9.0 | 241-284-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T F+
Risk Phrases: 11 23/25 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation and if swallowed. Irritating
to eyes and skin.
Potential Health Effects
Eye:
Vapors may cause eye irritation. May cause painful sensitization
to light. May cause blindness. Causes severe eye irritation and
possible injury.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be absorbed through the skin.
Ingestion:
May be fatal or cause blindness if swallowed. May cause
gastrointestinal irritation with nausea, vomiting and diarrhea. May
cause systemic toxicity with acidosis. May cause liver and kidney
damage. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
May cause liver and kidney damage. May cause visual impairment and
possible permanent blindness. May cause effects similar to those
described for ingestion. May cause drowsiness, unconsciousness, and
central nervous system depression. Vapors may cause dizziness or
suffocation. May cause edema of lungs or glottis and can produce
respiratory paralysis. May cause irritation and burning of the eyes,
tearing, coughing and irritation of nose and throat. May cause
irritation of the upper respiratory tract and bronchi.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation and ingestion may cause effects similar to those of acute
inhalation and ingestion. Chronic exposure can affect thyroid
function.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Effects may be delayed. Ethanol may inhibit methanol metabolism.
Antidote:
Ethanol may inhibit methanol metabolism.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Flammable liquid and vapor. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. May be ignited by heat, sparks, and flame.
Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Do not flush into a sewer. Remove
all sources of ignition. Provide ventilation. A vapor suppressing
foam may be used to reduce vapors. Water spray may reduce vapor but
may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat, sparks
and flame. Do not ingest or inhale. Use only in a chemical fume hood.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Do not store in direct sunlight. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Use only under a chemical fume hood.
Exposure Limits
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 108-32-7:
Russia: 7 mg/m3 TWA
CAS# 111-42-2:
Belgium - TWA: 0.46 ppm VLE; 2 mg/m3 VLE
France - VME: 3 ppm VME; 15 mg/m3 VME
Germany: 15 mg/m3 TWA (inhalable fraction)
Germany: Skin absorber
Malaysia: 0.46 ppm TWA; 2 mg/m3 TWA
Netherlands: 0.46 ppm MAC; 2 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 0.46 ppm VLA-ED; 2 mg/m3 VLA-ED
CAS# 7446-09-5:
United States OSHA: 5 ppm TWA; 13 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE
Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 5 ppm VLE; 10 mg/m3 VLE
Germany: 1 ppm TWA (paper production, chemical and pharmaceutical
industries); 2.5 mg/m3
Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA
Netherlands: 2 ppm MAC; 5 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED
Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC
CAS# 7553-56-2:
United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL
United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling
Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE
France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE
Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA
Germany: Skin absorber
Japan: 0.1 ppm OEL; 1 mg/m3 OEL
Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling
Russia: 1 mg/m3 TWA
Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC
CAS# 17252-51-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: yellowish-clear
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 97 mm Hg @20C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 13.5 deg C ( 56.30 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, excess
heat.
Incompatibilities with Other Materials:
Metals, strong acids, acrolein, active metals, aluminum, chlorates,
chlorine trifluoride, fluorine, halogens, iron oxide, nitric acid,
potassium chlorates, isocyanates, alliphatic amines, cesium
acetylene carbide, rubidium acetylene carbide, sodium acetylene
carbide, acids (mineral, non-oxidizing, e.g. hydrochloric acid,
hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral,
oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid,
sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid,
formic acid, methanoic acid, oxalic acid), alcohols and glycols
(e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes
(e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides
(e.g. butyramide, diethyltoluamide, dimethyl formamide), amines
(aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine,
triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine,
hydrazine, methyl hydrazine), carbamates (e.g. carbanolate,
carbofuran), caustics.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
formaldehyde.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-56-1: PC1400000
CAS# 108-32-7: FF9650000
CAS# 111-42-2: KL2975000
CAS# 7446-09-5: WS4550000
CAS# 7553-56-2: NN1575000
CAS# 17252-51-6 unlisted.
LD50/LC50:
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 108-32-7: Draize test, rabbit, eye: 60 mg Moderate; Draize
test, rabbit, skin: 500 mg Moderate; Inhalation, rat: LC50 = >5
gm/m3; Oral, mouse: LD50 = 20700 mg/kg; Oral, rat: LD50 = 29100
uL/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 111-42-2: Dermal, guinea pig: LD50 = 11900 uL/kg; Draize test,
rabbit, eye: 5500 mg Severe; Draize test, rabbit, eye: 750 ug/24H
Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, mouse:
LD50 = 3300 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 =
620 uL/kg; Skin, rabbit: LD50 = 7640 uL/kg.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild;
Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520
ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 =
1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14
gm/kg.
CAS# 17252-51-6.
Carcinogenicity:
Methanol -
Not listed by ACGIH, IARC, or NTP.
Propylene carbonate -
Not listed by ACGIH, IARC, or NTP.
Diethanolamine -
Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide -
Not listed by ACGIH, IARC, or NTP.
Iodine -
Not listed by ACGIH, IARC, or NTP.
1,3-Di-4-pyridylpropane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 111-42-2: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F+
Risk Phrases:
R 11 Highly flammable.
R 23/25 Toxic by inhalation and if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-56-1: 1
CAS# 108-32-7: 0
CAS# 111-42-2: 1
CAS# 7446-09-5: 1
CAS# 7553-56-2: 1
CAS# 17252-51-6: No information available.
Canada
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 108-32-7 is listed on Canada's DSL List.
CAS# 111-42-2 is listed on Canada's DSL List.
CAS# 7446-09-5 is listed on Canada's DSL List.
CAS# 7553-56-2 is listed on Canada's DSL List.
CAS# 17252-51-6 is listed on Canada's NDSL List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 108-32-7 is listed on Canada's Ingredient Disclosure List.
CAS# 111-42-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7446-09-5 is listed on Canada's Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canada's Ingredient Disclosure List.
CAS# 17252-51-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 108-32-7 is listed on the TSCA inventory.
CAS# 111-42-2 is listed on the TSCA inventory.
CAS# 7446-09-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
CAS# 17252-51-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 6/08/1999 Revision #5 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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