**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-55-4 |Glutaric anhydride | 97 | 203-593-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Irritating to eyes,
respiratory system and skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. If absorbed, may cause symptoms similar to
those for ingestion. May be harmful if absorbed through the skin. No
data found on whether or not this chemical would be likely to cause
an allergic skin reaction.
Ingestion:
May cause liver damage. May cause gastrointestinal tract damage. May
be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 108-55-4:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.00598 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 158 deg C @ 15 mm Hg
Freezing/Melting Point: 50-55 deg C
Autoignition Temperature: 320 deg C ( 608.00 deg F)
Flash Point: 173 deg C ( 343.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Hydrolysis.
Specific Gravity/Density: 1.411 g/cm3
Molecular Formula: C5H6O3
Molecular Weight: 114.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Reacts with water to
form corresponding acid.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, bases, alcohols, amines.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-55-4: MA3850000
LD50/LC50:
CAS# 108-55-4: Oral, rat: LD50 = 540 mg/kg; Skin, rabbit: LD50 =
1780 mg/kg.
Not available.
Carcinogenicity:
Glutaric anhydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 108-55-4: 1
Canada
CAS# 108-55-4 is listed on Canada's DSL List.
CAS# 108-55-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-55-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/16/1998 Revision #3 Date: 9/19/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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4-Bromo-2-Chloroaniline, 99%
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Malonic-d2 acid-d2, 99+ atom % d
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Brefeldin A, Natural
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| 532-24-1 |
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| 71172-78-6 |
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| 484-17-3 |
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3,4,5,2',3',4'-Hexahydroxybenzophenone, 99%
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Trifluoroacetic Acid-D, 99 Atom % D
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|
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| 9004-73-3 |
|
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| 71463-55-3 |
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| 26311-45-5 |
|
Terbium(iii) nitrate pentahydrate, 99.999%
| 57584-27-7 |
|
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| 624-49-7 |
|
2,6-Dibromophenol, 99+%
| 608-33-3 |
|
Carbostyril 124, Laser Grade
| 19840-99-4 |
|
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| 100-55-0 |
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| 9004-41-5 |
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| 106-73-0 |
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| 1948-31-8 |
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| 29639-21-2 |
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| 132442-43-4 |
|
4-Hydroxy-3-methoxybenzyl alcohol, 99%
| 498-00-0 |
|
Alpha-Phenylcinnamic Acid, 98%
| 91-48-5 |
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| 6290-49-9 |
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| 10236-47-2 |
|
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| 110-54-3 |
|
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| 5332-24-1 |
|
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| 108-55-4 |
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| 0-01-1 |
|
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| 4272-77-9 |
|
N-Methylpyrrole, 99+% (gc)
| 96-54-8 |
|
3,4-Dichlorobenzotrifluoride, 97%
| 328-84-7 |
|
1-(1-Naphthyl)-2-thiourea, 97%
| 86-88-4 |
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2-Nitrobenzyl alcohol, 97%
| 612-25-9 |
|
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| 4214-79-3 |
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| 28356-58-3 |
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(4s,2rs)-2-phenylthiazolidine-4-carboxylic acid, 98%
| |
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| 1435-48-9 |
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| 626-27-7 |
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| 109-99-9 |
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| 6931-54-0 |
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| 698-10-2 |
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