**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 110-54-3 |Hexane | 74 | 203-777-6 |
|----------------|--------------------------------------|----------|-----------|
| 20717-86-6 |Chlorotitanium triisopropoxide | 26 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F C
Risk Phrases: 11 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Causes burns.Corrosive.Air sensitive.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Vapors may cause
dizziness or suffocation.
Chronic:
Effects may be delayed. Prolonged or repeated exposure affects the
nervous system.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before
reuse. Discard contaminated clothing in a manner which limits further
exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Extremely flammable
liquid and vapor. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Containers may
explode in the heat of a fire. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT get water inside
containers. Do NOT use straight streams of water. Cool containers
with flooding quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
Place under an inert atmosphere. Do not get water inside containers.
A vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Keep away from heat, sparks and
flame. Do not get on skin or in eyes. Do not ingest or inhale. Handle
under an inert atmosphere. Store protected from air. Do not allow
contact with water. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Flammables-area. Do
not expose to air. Store protected from moisture. Store under an
inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 110-54-3:
United Kingdom, WEL - TWA: 20 ppm TWA; 72 mg/m3 TWA
United Kingdom, WEL - STEL: 60 ppm STEL; 216 mg/m3 STEL
United States OSHA: 500 ppm TWA; 1800 mg/m3 TWA
Belgium - TWA: 50 ppm VLE; 179 mg/m3 VLE
France - VME: 50 ppm VME; 170 mg/m3 VME
Germany: 50 ppm TWA; 180 mg/m3 TWA
Japan: 40 ppm OEL; 140 mg/m3 OEL
Malaysia: 50 ppm TWA; 176 mg/m3 TWA
Netherlands: 25 ppm MAC; 90 mg/m3 MAC
Russia: 300 mg/m3 TWA
Spain: 50 ppm VLA-ED; 179 mg/m3 VLA-ED
CAS# 20717-86-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Viscous liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: 240 deg C ( 464.00 deg F)
Flash Point: -22 deg C ( -7.60 deg F)
Explosion Limits, lower: 1.10 vol %
Explosion Limits, upper: 7.40 vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.7750 g/cm3
Molecular Formula: C9H21ClO3Ti
Molecular Weight: 260.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, exposure to air,
excess heat, strong oxidants.
Incompatibilities with Other Materials:
Air, moisture, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, titanium/titanium oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-54-3: MN9275000
CAS# 20717-86-6 unlisted.
LD50/LC50:
CAS# 110-54-3: Draize test, rabbit, eye: 10 mg Mild; Inhalation,
mouse: LC50 = 150000 mg/m3/2H; Inhalation, rat: LC50 = 48000 ppm/4H;
Inhalation, rat: LC50 = 627000 mg/m3/3M; Oral, rat: LD50 = 25 gm/kg.
CAS# 20717-86-6.
Carcinogenicity:
Hexane -
Not listed by ACGIH, IARC, or NTP.
Chlorotitanium triisopropoxide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3.1 (8)
UN Number: 2924
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2924
Packing group: II
USA RQ: CAS# 110-54-3: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 110-54-3: 1
CAS# 20717-86-6: No information available.
Canada
CAS# 110-54-3 is listed on Canada's DSL List.
CAS# 110-54-3 is listed on Canada's Ingredient Disclosure List.
CAS# 20717-86-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-54-3 is listed on the TSCA inventory.
CAS# 20717-86-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 38 Irritating to skin.
R 48/20 Harmful : danger of serious damage to health by
prolonged exposure through inhalation.
R 62 Possible risk of impaired fertility.
R 51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 11/04/1998 Revision #6 Date: 8/11/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
alpha-Acetamidocinnamic acid, 98%
| 5469-45-4 |
|
4-(4-Nitrophenyl)-butyric acid, 99%
| 5600-62-4 |
|
Perinaphthenone
| 548-39-0 |
|
4-Bromo-2-Chloroaniline, 99%
| 38762-41-3 |
|
Malonic-d2 acid-d2, 99+ atom % d
| 813-56-9 |
|
Brefeldin A, Natural
| 20350-15-6 |
|
Thymol blue, sodium salt, indicator
| 81012-93-3 |
|
Tropinone, 99%
| 532-24-1 |
|
1-(4-Methylphenyl)-1-cyclopropanecarbonitrile, 95%
| 71172-78-6 |
|
9-Phenanthrol, Tech.
| 484-17-3 |
|
3,4,5,2',3',4'-Hexahydroxybenzophenone, 99%
| 52479-85-3 |
|
Trifluoroacetic Acid-D, 99 Atom % D
| 599-00-8 |
|
N'-benzyl-N,N-dimethylethylenediamine tech.
| 103-55-9 |
|
2,2,4,5,5-Pentamethyl-3-Imidazoline-1-Oxyl Free Radical, 98%
| 39753-74-7 |
|
Cyanogen iodide
| 506-78-5 |
|
Potassium Cyanate
| 590-28-3 |
|
Polymethylhydrosiloxane, ca.99.5% silicon
| 9004-73-3 |
|
1-(2,4-Dichlorophenyl)-1-Cyclopropyl Cyanide
| 71463-55-3 |
|
4-Pentylbenzoic acid, 99%
| 26311-45-5 |
|
Terbium(iii) nitrate pentahydrate, 99.999%
| 57584-27-7 |
|
Dimethyl Fumarate, 99%
| 624-49-7 |
|
2,6-Dibromophenol, 99+%
| 608-33-3 |
|
Carbostyril 124, Laser Grade
| 19840-99-4 |
|
3-(Hydroxymethyl)pyridine, 98%
| 100-55-0 |
|
Cyanoethyl Cellulose
| 9004-41-5 |
|
Methyl Enanthate, 99%
| 106-73-0 |
|
L-Alanyl-L-Alanine
| 1948-31-8 |
|
Methyl-12-doxyl-stearate, free radical
| 29639-21-2 |
|
4-(4-Fluorobenzoyl)Piperidine P-Toluenesulfonate, Contains HCl Salt,
| 132442-43-4 |
|
4-Hydroxy-3-methoxybenzyl alcohol, 99%
| 498-00-0 |
|
Alpha-Phenylcinnamic Acid, 98%
| 91-48-5 |
|
Methyl methoxyacetate, 99%
| 6290-49-9 |
|
Naringin, 97%
| 10236-47-2 |
|
Chlorotitanium triisopropoxide, 1.0 M solution in hexanes
| 110-54-3 |
|
3-Bromoquinoline, 98%
| 5332-24-1 |
|
Glutaric anhydride, 97%
| 108-55-4 |
|
3-endo-Hydroxymethylbicyclo[2.2.1]hept-5-enyl-2-endo-amine
| 0-01-1 |
|
5-Dimethylamino-1-Naphthalenesulfonic Acid, Monohydrate, 99% (Titr.)
| 4272-77-9 |
|
N-Methylpyrrole, 99+% (gc)
| 96-54-8 |
|
3,4-Dichlorobenzotrifluoride, 97%
| 328-84-7 |
|
1-(1-Naphthyl)-2-thiourea, 97%
| 86-88-4 |
|
2-Nitrobenzyl alcohol, 97%
| 612-25-9 |
|
5-Chloro-2-Pyridinol, 99%
| 4214-79-3 |
|
4-Pyridylacetic Acid Hydrochloride, 98%
| 28356-58-3 |
|
(4s,2rs)-2-phenylthiazolidine-4-carboxylic acid, 98%
| |
|
1,3-Dichloro-4-fluorobenzene, 99%
| 1435-48-9 |
|
Heptanoic anhydride, 99%
| 626-27-7 |
|
Catecholborane, 1m solution in tetrahydrofuran
| 109-99-9 |
|
(+)-beta-Pinene oxide, tech. 75%
| 6931-54-0 |
|
5-Ethyl-3-Hydroxy-4-Methyl-2(5H)-Furanone, 98%
| 698-10-2 |
|
|