**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 96-54-8 |N-Methylpyrrole | 99+ | 202-513-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 22 37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. Irritating to respiratory
system and skin.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes severe respiratory tract irritation. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. This material is lighter than
water and insoluble in water. The fire could easily be spread by the
use of water in an area where the water cannot be contained. Use
agent most appropriate to extinguish fire. Do NOT use straight
streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep away from heat, sparks and flame. Avoid ingestion
and inhalation. Use with adequate ventilation. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 96-54-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: Clear, Slightly Brownish Liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: 15 mm Hg @ 20.2 C
Viscosity: ca. 0.7 mPas 20
Boiling Point: 112 - 113 deg C @ 760.00mm Hg
Freezing/Melting Point: -57 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 15 deg C ( 59.00 deg F)
Explosion Limits, lower: 1.40 vol %
Explosion Limits, upper: 8.50 vol %
Decomposition Temperature: >300 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: .9140g/cm3
Molecular Formula: C5H7N
Molecular Weight: 81.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, carbon dioxide, strong
oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 96-54-8: UX9640000
LD50/LC50:
Not available.
Carcinogenicity:
N-Methylpyrrole -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 37/38 Irritating to respiratory system and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 25 Avoid contact with eyes.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 96-54-8: No information available.
Canada
CAS# 96-54-8 is listed on Canada's DSL List.
CAS# 96-54-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96-54-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/22/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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4-Bromo-2-Chloroaniline, 99%
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Malonic-d2 acid-d2, 99+ atom % d
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Brefeldin A, Natural
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| 532-24-1 |
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| 71172-78-6 |
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Trifluoroacetic Acid-D, 99 Atom % D
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| 506-78-5 |
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Potassium Cyanate
| 590-28-3 |
|
Polymethylhydrosiloxane, ca.99.5% silicon
| 9004-73-3 |
|
1-(2,4-Dichlorophenyl)-1-Cyclopropyl Cyanide
| 71463-55-3 |
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4-Pentylbenzoic acid, 99%
| 26311-45-5 |
|
Terbium(iii) nitrate pentahydrate, 99.999%
| 57584-27-7 |
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| 624-49-7 |
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2,6-Dibromophenol, 99+%
| 608-33-3 |
|
Carbostyril 124, Laser Grade
| 19840-99-4 |
|
3-(Hydroxymethyl)pyridine, 98%
| 100-55-0 |
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| 9004-41-5 |
|
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| 106-73-0 |
|
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| 1948-31-8 |
|
Methyl-12-doxyl-stearate, free radical
| 29639-21-2 |
|
4-(4-Fluorobenzoyl)Piperidine P-Toluenesulfonate, Contains HCl Salt,
| 132442-43-4 |
|
4-Hydroxy-3-methoxybenzyl alcohol, 99%
| 498-00-0 |
|
Alpha-Phenylcinnamic Acid, 98%
| 91-48-5 |
|
Methyl methoxyacetate, 99%
| 6290-49-9 |
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Naringin, 97%
| 10236-47-2 |
|
Chlorotitanium triisopropoxide, 1.0 M solution in hexanes
| 110-54-3 |
|
3-Bromoquinoline, 98%
| 5332-24-1 |
|
Glutaric anhydride, 97%
| 108-55-4 |
|
3-endo-Hydroxymethylbicyclo[2.2.1]hept-5-enyl-2-endo-amine
| 0-01-1 |
|
5-Dimethylamino-1-Naphthalenesulfonic Acid, Monohydrate, 99% (Titr.)
| 4272-77-9 |
|
N-Methylpyrrole, 99+% (gc)
| 96-54-8 |
|
3,4-Dichlorobenzotrifluoride, 97%
| 328-84-7 |
|
1-(1-Naphthyl)-2-thiourea, 97%
| 86-88-4 |
|
2-Nitrobenzyl alcohol, 97%
| 612-25-9 |
|
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| 4214-79-3 |
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| 28356-58-3 |
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(4s,2rs)-2-phenylthiazolidine-4-carboxylic acid, 98%
| |
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| 1435-48-9 |
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| 626-27-7 |
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| 109-99-9 |
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(+)-beta-Pinene oxide, tech. 75%
| 6931-54-0 |
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| 698-10-2 |
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|