**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 71172-78-6 |1-(4-Methylphenyl)-1-cyclopropanecarbo| 95 | 275-240-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be metabolized to cyanide which in
turn acts by inhibiting cytochrome oxidase impairing cellular
respiration.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Metabolism may release cyanide, which may result in headache,
dizziness, weakness, collapse, unconsciousness and possible death.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May be
metabolized to cyanide which in turns act by inhibiting cytochrome
oxidase impairing cellular respiration. Inhalation may result in
symptoms similar to cyanide poisoning which include tachypnea,
hyperpnea (abnormally rapid or deep breathing), and dyspnea (labored
breathing) followed rapidly by respiratory depression. Pulmonary
edema may occur.
Chronic:
No information found. May be metabolized to cyanide which in turn
acts by inhibiting cytochrome oxidase impairing cellular
respiration. Chronic exposure to cyanide solutions may lead to the
development of a "cyanide" rash, characterized by itching, and by
macular, papular, and vesicular eruptions, and may be accompanied by
secondary infections. Exposure to small amounts of cyanide compounds
over long periods of time is reported to cause loss of appetite,
headache, weakness, nausea, dizziness, and symptoms of irritation of
the upper respiratory tract and eyes.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 71172-78-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .990 g/ml
Molecular Formula: C11H11N
Molecular Weight: 157.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 71172-78-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(4-Methylphenyl)-1-cyclopropanecarbonitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 71172-78-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 71172-78-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 71172-78-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 7/30/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
alpha-Acetamidocinnamic acid, 98%
| 5469-45-4 |
|
4-(4-Nitrophenyl)-butyric acid, 99%
| 5600-62-4 |
|
Perinaphthenone
| 548-39-0 |
|
4-Bromo-2-Chloroaniline, 99%
| 38762-41-3 |
|
Malonic-d2 acid-d2, 99+ atom % d
| 813-56-9 |
|
Brefeldin A, Natural
| 20350-15-6 |
|
Thymol blue, sodium salt, indicator
| 81012-93-3 |
|
Tropinone, 99%
| 532-24-1 |
|
1-(4-Methylphenyl)-1-cyclopropanecarbonitrile, 95%
| 71172-78-6 |
|
9-Phenanthrol, Tech.
| 484-17-3 |
|
3,4,5,2',3',4'-Hexahydroxybenzophenone, 99%
| 52479-85-3 |
|
Trifluoroacetic Acid-D, 99 Atom % D
| 599-00-8 |
|
N'-benzyl-N,N-dimethylethylenediamine tech.
| 103-55-9 |
|
2,2,4,5,5-Pentamethyl-3-Imidazoline-1-Oxyl Free Radical, 98%
| 39753-74-7 |
|
Cyanogen iodide
| 506-78-5 |
|
Potassium Cyanate
| 590-28-3 |
|
Polymethylhydrosiloxane, ca.99.5% silicon
| 9004-73-3 |
|
1-(2,4-Dichlorophenyl)-1-Cyclopropyl Cyanide
| 71463-55-3 |
|
4-Pentylbenzoic acid, 99%
| 26311-45-5 |
|
Terbium(iii) nitrate pentahydrate, 99.999%
| 57584-27-7 |
|
Dimethyl Fumarate, 99%
| 624-49-7 |
|
2,6-Dibromophenol, 99+%
| 608-33-3 |
|
Carbostyril 124, Laser Grade
| 19840-99-4 |
|
3-(Hydroxymethyl)pyridine, 98%
| 100-55-0 |
|
Cyanoethyl Cellulose
| 9004-41-5 |
|
Methyl Enanthate, 99%
| 106-73-0 |
|
L-Alanyl-L-Alanine
| 1948-31-8 |
|
Methyl-12-doxyl-stearate, free radical
| 29639-21-2 |
|
4-(4-Fluorobenzoyl)Piperidine P-Toluenesulfonate, Contains HCl Salt,
| 132442-43-4 |
|
4-Hydroxy-3-methoxybenzyl alcohol, 99%
| 498-00-0 |
|
Alpha-Phenylcinnamic Acid, 98%
| 91-48-5 |
|
Methyl methoxyacetate, 99%
| 6290-49-9 |
|
Naringin, 97%
| 10236-47-2 |
|
Chlorotitanium triisopropoxide, 1.0 M solution in hexanes
| 110-54-3 |
|
3-Bromoquinoline, 98%
| 5332-24-1 |
|
Glutaric anhydride, 97%
| 108-55-4 |
|
3-endo-Hydroxymethylbicyclo[2.2.1]hept-5-enyl-2-endo-amine
| 0-01-1 |
|
5-Dimethylamino-1-Naphthalenesulfonic Acid, Monohydrate, 99% (Titr.)
| 4272-77-9 |
|
N-Methylpyrrole, 99+% (gc)
| 96-54-8 |
|
3,4-Dichlorobenzotrifluoride, 97%
| 328-84-7 |
|
1-(1-Naphthyl)-2-thiourea, 97%
| 86-88-4 |
|
2-Nitrobenzyl alcohol, 97%
| 612-25-9 |
|
5-Chloro-2-Pyridinol, 99%
| 4214-79-3 |
|
4-Pyridylacetic Acid Hydrochloride, 98%
| 28356-58-3 |
|
(4s,2rs)-2-phenylthiazolidine-4-carboxylic acid, 98%
| |
|
1,3-Dichloro-4-fluorobenzene, 99%
| 1435-48-9 |
|
Heptanoic anhydride, 99%
| 626-27-7 |
|
Catecholborane, 1m solution in tetrahydrofuran
| 109-99-9 |
|
(+)-beta-Pinene oxide, tech. 75%
| 6931-54-0 |
|
5-Ethyl-3-Hydroxy-4-Methyl-2(5H)-Furanone, 98%
| 698-10-2 |
|
|