**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-80-5 |Ethylene glycol monoethyl ether | > 99 | 203-804-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 10 20/21/22 60 61
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. May impair fertility. May cause harm to the unborn child.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause mild skin irritation. Prolonged and/or repeated contact
may cause irritation and/or dermatitis. If absorbed, causes symptoms
similar to those of ingestion. May be harmful if absorbed through the
skin. Substance is readily absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause liver and
kidney damage. Exposure may cause anemia and other blood
abnormalities. May be harmful if swallowed. May cause central
nervous system depression.
Inhalation:
May cause respiratory tract irritation. Inhalation overexposure may
lead to central nervous system depression, producing effects such as
dizziness, headache, confusion, incoordination, nausea, weakness, and
loss of consciousness. Extreme exposures may cause other CNS effects
including death.
Chronic:
2-Ethoxyethanol may be a teratogen in humans since it has been shown
to be a teratogen in animals. It may damage the testes and decrease
fertility in males.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Flammable liquid and vapor. Containers may explode when heated.
Vapors are heavier than air and may travel to a source of ignition
and flash back. Vapors can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
Use dry chemical, carbon dioxide, or appropriate foam. Solid streams
of water may be ineffective and spread material.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation. Approach spill from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Use only with
adequate ventilation. Avoid breathing vapor or mist.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Do not store in aluminum
containers. Store protected from light and air. Containers should be
dated when opened and tested periodically for the presence of
peroxides. Should crystals form in a peroxidizable liquid,
peroxidation may have occurred and the product should be considered
extremely dangerous. In this instance, the container should only be
opened remotely by professionals. All peroxidizable substances should
be stored away from heat and light and be protected from ignition
sources.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 110-80-5:
United Kingdom, WEL - TWA: 10 ppm TWA; 37 mg/m3 TWA
United Kingdom, WEL - STEL: 30 ppm STEL; 111 mg/m3 STEL
United States OSHA: 200 ppm TWA; 740 mg/m3 TWA
Belgium - TWA: 5 ppm VLE; 18 mg/m3 VLE
France - VME: 5 ppm VME; 19 mg/m3 VME
Germany: 5 ppm TWA; 19 mg/m3 TWA
Germany: Skin absorber
Japan: 5 ppm OEL; 18 mg/m3 OEL
Malaysia: 5 ppm TWA; 18 mg/m3 TWA
Netherlands: 5 ppm MAC; 19 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 18 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: mild odor - pleasant odor - ethereal odor - sweetish
pH: Not available.
Vapor Pressure: 3.8 mm Hg @ 20 deg C
Viscosity: 2.1 cps @ 20 deg C
Boiling Point: 135 deg C
Freezing/Melting Point: -90 deg C
Autoignition Temperature: 235 deg C ( 455.00 deg F)
Flash Point: 43 deg C ( 109.40 deg F)
Explosion Limits, lower: 1.7% @ 93C
Explosion Limits, upper: 15.6% @ 93C
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 0.9300
Molecular Formula: C4H10O2
Molecular Weight: 90.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form
and accumulate peroxides which may explode when subjected to heat or
shock. This material is most hazardous when peroxide levels are
concentrated by distillation or evaporation.
Conditions to Avoid:
Light, ignition sources, excess heat, exposure to flame, prolonged
exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, aluminum.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, peroxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-80-5: KK8050000
LD50/LC50:
CAS# 110-80-5: Draize test, rabbit, eye: 50 mg Moderate; Draize
test, rabbit, eye: 500 mg/24H Mild; Inhalation, mouse: LC50 = 1820
ppm/7H; Inhalation, rat: LC50 = 2000 ppm/7H; Oral, mouse: LD50 = 2451
mg/kg; Oral, mouse: LD50 = 4000 mg/kg; Oral, rabbit: LD50 = 1275
mg/kg; Oral, rabbit: LD50 = 1275 mg/kg; Oral, rat: LD50 = 2125
mg/kg; Oral, rat: LD50 = 2125 mg/kg; Skin, rabbit: LD50 = 3.6 mg/kg;
Skin, rat: LD50 = 3900 mg/kg.
Carcinogenicity:
Ethylene glycol monoethyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = >10000 mg/L; 96 Hr.; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 5400 mg/L; 24 Hr.; Modified ASTM D1345Water
flea Daphnia: EC50 = >10000 mg/L; 24 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 430 mg/L; 30 minutes; Microtox
test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ETHYLENE GLYCOL MONOETHYL ETHER
Hazard Class: 3
UN Number: 1171
Packing Group: III
IMO
Shipping Name: ETHYLENE GLYCOL MONOETHYL ETHER
Hazard Class: 3.3
UN Number: 1171
Packing Group: III
RID/ADR
Shipping Name: ETHYLENE GLYCOL MONOETHYL ETHER
Hazard Class: 3
UN Number: 1171
Packing group: III
USA RQ: CAS# 110-80-5: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 61 May cause harm to the unborn child.
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 60 May impair fertility.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 110-80-5: 1
Canada
CAS# 110-80-5 is listed on Canada's DSL List.
CAS# 110-80-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-80-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/04/1999 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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