**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2757-18-8 |Thallous Malonate | 98 | 220-414-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 26/28 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation and if swallowed. Danger of cumulative
effects.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis.
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
Prolonged and/or repeated contact may cause irritation and/or
dermatitis. Absorption into the body may cause cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Ingestion:
May be fatal if swallowed. May cause gastrointestinal irritation
with nausea, vomiting and diarrhea. May cause liver and kidney
damage. May cause hemorrhaging of the digestive tract. May cause
alopecia (loss of hair). May cause cardiopulmonary system effects.
Human fatalities have been reported from acute poisoning. Ingested
thallium compounds are extremely toxic, causing convulsions, coma,
conjunctivitis, runny nose, polyneuritis, motor and sensory
peripheral neuropathy, encephalopathy, arterial hypertension, rapid
heart rate, and skin eruptions
Inhalation:
Causes respiratory tract irritation. May cause dyspnea (difficult or
labored breathing). May cause corneal irritation, dyspnea (labored
breathing), bronchospasm, chest pain, and pulmonary edema, which may
be fatal.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
liver and kidney damage. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
For large fires, use water spray, fog or regular foam. For small
fires, use dry chemical, carbon dioxide, water spray or regular
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Poison room
locked.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2757-18-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: almost white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C3H2O4Tl2
Molecular Weight: 510.80
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, air.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, fluoride fumes, thallium fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2757-18-8: OO1770000
LD50/LC50:
CAS# 2757-18-8: Oral, rat: LD50 = 18800 ug/kg; Skin, rat: LD50 =
57700 ug/kg.
Carcinogenicity:
Thallous Malonate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
IMO
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
RID/ADR
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/28 Very toxic by inhalation and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2757-18-8: No information available.
Canada
CAS# 2757-18-8 is listed on Canada's NDSL List.
CAS# 2757-18-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2757-18-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/27/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Melamine, P.A.
| 108-78-1 |
|
Chlorodifluoroacetic Acid, 98%
| 76-04-0 |
|
O-Anisic Acid, 99%
| 579-75-9 |
|
3,4'-Dichloropropiophenone, 95%
| 3946-29-0 |
|
cis-3-Hexen-1-ol, 98%
| 928-96-1 |
|
2,4,6-Tribromophenol, 98%
| 118-79-6 |
|
1-Ethyl-3-Piperidone Hydrochloride, 97%
| 41361-28-8 |
|
Propionyl chloride, 98%
| 79-03-8 |
|
n-Methylhippuric acid, 99%
| 2568-34-5 |
|
2-Hydroxybenzyl Alcohol, 97%
| 90-01-7 |
|
3-Acetamidophenol, 99+%
| 621-42-1 |
|
2-(4-Chlorobenzyl)pyridine
| 4350-41-8 |
|
2,5-Diaminopyridine dihydrochloride, 98%
| 26878-35-3 |
|
1-(4-Chlorophenyl)-1-Cyclopropanemethanol, 98%
| 80866-81-5 |
|
Ethyl dichlorophosphate, 97%
| 1498-51-7 |
|
Merocyanine 540, 99% (UV-Vis)
| 62796-23-0 |
|
Thallous Malonate, 98% (Titr.)
| 2757-18-8 |
|
Thiofluorescein, 99% (uv-vis)
| 25319-73-3 |
|
N,N-Diethyl-P-Toluidine, 99% (GC)
| 613-48-9 |
|
Hexyl isocyanate, 99% (GC)
| 2525-62-4 |
|
1-(4-Chlorophenyl)-1-Cyclopropane- Carbonitrile 98%
| 64399-27-5 |
|
(-)-2,3-o-isopropylidene-2,3-dihydroxy-
| 32305-98-9 |
|
1-(4-Methylphenyl)-1-Cyclopropane Carboxylic Acid, 98%
| 0-00-1 |
|
Palladium(ii) bromide
| 13444-93-4 |
|
2,5-Dimethoxytetrahydrofuran, 99%, mixture of cis- and trans- isomers
| 696-59-3 |
|
Ethyl formate, 98+%
| 109-94-4 |
|
Gallium(iii) nitrate hydrate, 99.9998%,
| 13494-90-1 |
|
4-Nitrophenyl trimethylacetate, 98+%
| 4195-17-9 |
|
DL-10-Camphorsulfonic Acid, 98%
| 5872-08-2 |
|
Anthracene, 98%
| 120-12-7 |
|
4-Cyanophenyl Isocyanate, 95% (HPLC)
| 40465-45-0 |
|
2-Furoyl chloride, 98+% (gc)
| 527-69-5 |
|
Nitron, 95% (UV-VIS)
| 2218-94-2 |
|
Benzyltriphenylphosphonium chloride, 98%
| 1100-88-5 |
|
4-Chloro-2-Fluorobenzonitrile, 99.5+%
| 57381-51-8 |
|
Trans-3-Chloroacrylic Acid, 99%
| 2345-61-1 |
|
2-Thiouracil, 99% (UV-Vis)
| 141-90-2 |
|
Dl-threonine, 99.5%
| 80-68-2 |
|
4-Phenyl-1,3-Dioxane, 99+%
| 772-00-9 |
|
N-Methylanilinium Trifluoroacetate, 99%
| 29885-95-8 |
|
Phloroglucinol anhydr., min. 99%(gc)
| 108-73-6 |
|
Pyrene, 98+%(gc)
| 129-00-0 |
|
2-Iodotoluene, 98%
| 615-37-2 |
|
4,4' -Azoxyanisole, 98+%
| 1562-94-3 |
|
2-Fluorobenzyl alcohol, 98%
| 446-51-5 |
|
Bbd
| 18378-20-6 |
|
Ethylene glycol monoethyl ether
| 110-80-5 |
|
4',5'-Dibromofluorescein
| 596-03-2 |
|
Ethylene Glycol Monoethyl Ether Acetate
| 111-15-9 |
|
1-[(3-Nitrobenzyloxy)methyl] pyridinium chloride, 99% (titr.)
| 3009-13-0 |
|
|