**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13494-90-1 |Gallium(III) nitrate hydrate | 99.9998 | 236-815-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI O
Risk Phrases: 36/38 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin. Contact with combustible material may
cause fire.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis.
Skin:
Causes severe skin irritation.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea,
vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. May cause acute pulmonary
edema, asphyxia, chemical pneumonitis, and upper airway obstruction
caused by edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Runoff to sewer may create fire or
explosion hazard.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately. Do
NOT use dry chemicals, CO2, Halon or foams.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Cover with
sand, dry lime or soda ash and place in a closed container for
disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Keep container tightly
closed. Avoid contact with clothing and other combustible materials.
Do not get on skin or in eyes. Avoid ingestion and inhalation. Use
only in a chemical fume hood. Wash clothing before reuse.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store
under nitrogen. Store in a cool, dry area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 13494-90-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 110 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 110 deg C
Solubility in water: Soluble.
Specific Gravity/Density: Not available.
Molecular Formula: GaN3O9.xH2O
Molecular Weight: 255.74
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Strong reducing agents, strong acids, acids, isocyanates, cyanides
(e.g. potassium cyanide, sodium cyanide), hypophosphites, moisture,
thiocyanates, aluminum powder + water, alkyl esters, phosphinates +
heat, heavy metals.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13494-90-1: LW9625000
LD50/LC50:
CAS# 13494-90-1: Oral, mouse: LD50 = 4360 mg/kg; Oral, mouse: LD50 =
4400 mg/kg.
Carcinogenicity:
Gallium(III) nitrate hydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
IMO
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
RID/ADR
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 13494-90-1: No information available.
Canada
CAS# 13494-90-1 is listed on Canada's NDSL List.
CAS# 13494-90-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13494-90-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/21/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Melamine, P.A.
| 108-78-1 |
|
Chlorodifluoroacetic Acid, 98%
| 76-04-0 |
|
O-Anisic Acid, 99%
| 579-75-9 |
|
3,4'-Dichloropropiophenone, 95%
| 3946-29-0 |
|
cis-3-Hexen-1-ol, 98%
| 928-96-1 |
|
2,4,6-Tribromophenol, 98%
| 118-79-6 |
|
1-Ethyl-3-Piperidone Hydrochloride, 97%
| 41361-28-8 |
|
Propionyl chloride, 98%
| 79-03-8 |
|
n-Methylhippuric acid, 99%
| 2568-34-5 |
|
2-Hydroxybenzyl Alcohol, 97%
| 90-01-7 |
|
3-Acetamidophenol, 99+%
| 621-42-1 |
|
2-(4-Chlorobenzyl)pyridine
| 4350-41-8 |
|
2,5-Diaminopyridine dihydrochloride, 98%
| 26878-35-3 |
|
1-(4-Chlorophenyl)-1-Cyclopropanemethanol, 98%
| 80866-81-5 |
|
Ethyl dichlorophosphate, 97%
| 1498-51-7 |
|
Merocyanine 540, 99% (UV-Vis)
| 62796-23-0 |
|
Thallous Malonate, 98% (Titr.)
| 2757-18-8 |
|
Thiofluorescein, 99% (uv-vis)
| 25319-73-3 |
|
N,N-Diethyl-P-Toluidine, 99% (GC)
| 613-48-9 |
|
Hexyl isocyanate, 99% (GC)
| 2525-62-4 |
|
1-(4-Chlorophenyl)-1-Cyclopropane- Carbonitrile 98%
| 64399-27-5 |
|
(-)-2,3-o-isopropylidene-2,3-dihydroxy-
| 32305-98-9 |
|
1-(4-Methylphenyl)-1-Cyclopropane Carboxylic Acid, 98%
| 0-00-1 |
|
Palladium(ii) bromide
| 13444-93-4 |
|
2,5-Dimethoxytetrahydrofuran, 99%, mixture of cis- and trans- isomers
| 696-59-3 |
|
Ethyl formate, 98+%
| 109-94-4 |
|
Gallium(iii) nitrate hydrate, 99.9998%,
| 13494-90-1 |
|
4-Nitrophenyl trimethylacetate, 98+%
| 4195-17-9 |
|
DL-10-Camphorsulfonic Acid, 98%
| 5872-08-2 |
|
Anthracene, 98%
| 120-12-7 |
|
4-Cyanophenyl Isocyanate, 95% (HPLC)
| 40465-45-0 |
|
2-Furoyl chloride, 98+% (gc)
| 527-69-5 |
|
Nitron, 95% (UV-VIS)
| 2218-94-2 |
|
Benzyltriphenylphosphonium chloride, 98%
| 1100-88-5 |
|
4-Chloro-2-Fluorobenzonitrile, 99.5+%
| 57381-51-8 |
|
Trans-3-Chloroacrylic Acid, 99%
| 2345-61-1 |
|
2-Thiouracil, 99% (UV-Vis)
| 141-90-2 |
|
Dl-threonine, 99.5%
| 80-68-2 |
|
4-Phenyl-1,3-Dioxane, 99+%
| 772-00-9 |
|
N-Methylanilinium Trifluoroacetate, 99%
| 29885-95-8 |
|
Phloroglucinol anhydr., min. 99%(gc)
| 108-73-6 |
|
Pyrene, 98+%(gc)
| 129-00-0 |
|
2-Iodotoluene, 98%
| 615-37-2 |
|
4,4' -Azoxyanisole, 98+%
| 1562-94-3 |
|
2-Fluorobenzyl alcohol, 98%
| 446-51-5 |
|
Bbd
| 18378-20-6 |
|
Ethylene glycol monoethyl ether
| 110-80-5 |
|
4',5'-Dibromofluorescein
| 596-03-2 |
|
Ethylene Glycol Monoethyl Ether Acetate
| 111-15-9 |
|
1-[(3-Nitrobenzyloxy)methyl] pyridinium chloride, 99% (titr.)
| 3009-13-0 |
|
|