**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 79-03-8 |Propionyl chloride | 98 | 201-170-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes
burns.Corrosive.Water-reactive.Lachrymator (substance which
increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. Use water spray to keep fire-exposed containers
cool. Containers may explode in the heat of a fire. Flammable liquid
and vapor. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. May ignite or explode on
contact with steam or moist air.
Extinguishing Media:
Use dry sand or earth to smother fire. Use water spray to cool
fire-exposed containers. Use foam, dry chemical, or carbon dioxide.
DO NOT USE WATER! Contact professional fire-fighters immediately.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not expose spill to water. A vapor suppressing foam may be used to
reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not allow water to get into the container because of violent
reaction. Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Keep away from heat, sparks and
flame. Do not get on skin or in eyes. Do not ingest or inhale. Use
with adequate ventilation. Do not allow contact with water. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a cool,
dry, well-ventilated area away from incompatible substances. Keep
away from water. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 79-03-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: Colorless - Slightly Yellow Liquid
Odor: pungent odor
pH: Not available.
Vapor Pressure: 81 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 77 - 79 deg C @ 760.00mm Hg
Freezing/Melting Point: -94 deg C
Autoignition Temperature: 270 deg C ( 518.00 deg F)
Flash Point: 11 deg C ( 51.80 deg F)
Explosion Limits, lower: 3.60 vol %
Explosion Limits, upper: 11.90 vol %
Decomposition Temperature:
Solubility in water: Reacts with water.
Specific Gravity/Density: 1.0650g/cm3
Molecular Formula: C3H5ClO
Molecular Weight: 92.52
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Combines vigorously or explosively with water.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, alcohols, water.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 79-03-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Propionyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PROPIONYL CHLORIDE
Hazard Class: 3 (8)
UN Number: 1815
Packing Group: II
IMO
Shipping Name: PROPIONYL CHLORIDE
Hazard Class: 3.2 (8)
UN Number: 1815
Packing Group: II
RID/ADR
Shipping Name: PROPIONYL CHLORIDE
Hazard Class: 3
UN Number: 1815
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 79-03-8: No information available.
Canada
CAS# 79-03-8 is listed on Canada's DSL List.
CAS# 79-03-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 79-03-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/08/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| 64399-27-5 |
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| 109-94-4 |
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| 13494-90-1 |
|
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| 4195-17-9 |
|
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| 5872-08-2 |
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| 120-12-7 |
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| 527-69-5 |
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Trans-3-Chloroacrylic Acid, 99%
| 2345-61-1 |
|
2-Thiouracil, 99% (UV-Vis)
| 141-90-2 |
|
Dl-threonine, 99.5%
| 80-68-2 |
|
4-Phenyl-1,3-Dioxane, 99+%
| 772-00-9 |
|
N-Methylanilinium Trifluoroacetate, 99%
| 29885-95-8 |
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| 108-73-6 |
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| 129-00-0 |
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| 615-37-2 |
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