**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 129-00-0 |Pyrene, ca | 96.0 | 204-927-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause cancer.The toxicological properties of this material have
not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause
irritation and/or dermatitis. Dermal applications may cause
hyperemia (an excess of blood in a part), weight loss, and
hematopoietic changes.
Ingestion:
May cause digestive tract disturbances. The toxicological properties
of this substance have not been fully investigated. May be harmful if
swallowed.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation.
Inhalation of dust may cause respiratory tract irritation.
Chronic:
May cause cancer according to animal studies. Chronic effects may
include leukocytosis and lengthened chronaxy of the leg muscle
flexors.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Do not let this chemical
enter the environment.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 129-00-0:
United States OSHA: 0.2 mg/m3 TWA (as benzene soluble fraction)
(listed under Coal tar pitches).
Belgium - TWA: (listed as coal tar pitches): 0.2 mg/m3 VLE
France - VME: (listed as coal tar pitches): 0.2 mg/m3 VME (vapors
mists, benzene-soluble fraction)
Germany: (listed as coal tar pitches): 0.2 mg/m3 VME (vapors and
mists, benzene-soluble fraction)
Malaysia: (listed as coal tar pitches): 0.2 mg/m3 TWA (as benzene
solubles)
Russia: 0.03 mg/m3 TWA
Spain: (listed as coal tar pitches): 0.2 mg/m3 VLA-ED (benzene
soluble fraction)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: < 1 mm Hg @20C
Viscosity: Not available.
Boiling Point: 404 deg C @ 760.00mmHg
Freezing/Melting Point: 156 deg C
Autoignition Temperature: Not available.
Flash Point: 210 deg C ( 410.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 1.271
Specific Gravity/Density:
Molecular Formula: C16H10
Molecular Weight: 202.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 129-00-0: UR2450000 UR2450100
LD50/LC50:
CAS# 129-00-0: Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, rat: LC50 = 170 mg/m3; Inhalation, rat: LC50 = 170 mg/m3;
Oral, mouse: LD50 = 800 mg/kg; Oral, rat: LD50 = 2700 mg/kg.
Carcinogenicity:
Pyrene, ca -
NTP: Known carcinogen (listed as Coal tar pitches).
IARC: Group 1 carcinogen (listed as Coal tar pitches).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Water flea Daphnia: EC50 = 1.8 mg/L; 48 Hr.; Unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 129-00-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 45 May cause cancer.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 129-00-0: No information available.
Canada
CAS# 129-00-0 is listed on Canada's DSL List.
CAS# 129-00-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 129-00-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/21/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Melamine, P.A.
| 108-78-1 |
|
Chlorodifluoroacetic Acid, 98%
| 76-04-0 |
|
O-Anisic Acid, 99%
| 579-75-9 |
|
3,4'-Dichloropropiophenone, 95%
| 3946-29-0 |
|
cis-3-Hexen-1-ol, 98%
| 928-96-1 |
|
2,4,6-Tribromophenol, 98%
| 118-79-6 |
|
1-Ethyl-3-Piperidone Hydrochloride, 97%
| 41361-28-8 |
|
Propionyl chloride, 98%
| 79-03-8 |
|
n-Methylhippuric acid, 99%
| 2568-34-5 |
|
2-Hydroxybenzyl Alcohol, 97%
| 90-01-7 |
|
3-Acetamidophenol, 99+%
| 621-42-1 |
|
2-(4-Chlorobenzyl)pyridine
| 4350-41-8 |
|
2,5-Diaminopyridine dihydrochloride, 98%
| 26878-35-3 |
|
1-(4-Chlorophenyl)-1-Cyclopropanemethanol, 98%
| 80866-81-5 |
|
Ethyl dichlorophosphate, 97%
| 1498-51-7 |
|
Merocyanine 540, 99% (UV-Vis)
| 62796-23-0 |
|
Thallous Malonate, 98% (Titr.)
| 2757-18-8 |
|
Thiofluorescein, 99% (uv-vis)
| 25319-73-3 |
|
N,N-Diethyl-P-Toluidine, 99% (GC)
| 613-48-9 |
|
Hexyl isocyanate, 99% (GC)
| 2525-62-4 |
|
1-(4-Chlorophenyl)-1-Cyclopropane- Carbonitrile 98%
| 64399-27-5 |
|
(-)-2,3-o-isopropylidene-2,3-dihydroxy-
| 32305-98-9 |
|
1-(4-Methylphenyl)-1-Cyclopropane Carboxylic Acid, 98%
| 0-00-1 |
|
Palladium(ii) bromide
| 13444-93-4 |
|
2,5-Dimethoxytetrahydrofuran, 99%, mixture of cis- and trans- isomers
| 696-59-3 |
|
Ethyl formate, 98+%
| 109-94-4 |
|
Gallium(iii) nitrate hydrate, 99.9998%,
| 13494-90-1 |
|
4-Nitrophenyl trimethylacetate, 98+%
| 4195-17-9 |
|
DL-10-Camphorsulfonic Acid, 98%
| 5872-08-2 |
|
Anthracene, 98%
| 120-12-7 |
|
4-Cyanophenyl Isocyanate, 95% (HPLC)
| 40465-45-0 |
|
2-Furoyl chloride, 98+% (gc)
| 527-69-5 |
|
Nitron, 95% (UV-VIS)
| 2218-94-2 |
|
Benzyltriphenylphosphonium chloride, 98%
| 1100-88-5 |
|
4-Chloro-2-Fluorobenzonitrile, 99.5+%
| 57381-51-8 |
|
Trans-3-Chloroacrylic Acid, 99%
| 2345-61-1 |
|
2-Thiouracil, 99% (UV-Vis)
| 141-90-2 |
|
Dl-threonine, 99.5%
| 80-68-2 |
|
4-Phenyl-1,3-Dioxane, 99+%
| 772-00-9 |
|
N-Methylanilinium Trifluoroacetate, 99%
| 29885-95-8 |
|
Phloroglucinol anhydr., min. 99%(gc)
| 108-73-6 |
|
Pyrene, 98+%(gc)
| 129-00-0 |
|
2-Iodotoluene, 98%
| 615-37-2 |
|
4,4' -Azoxyanisole, 98+%
| 1562-94-3 |
|
2-Fluorobenzyl alcohol, 98%
| 446-51-5 |
|
Bbd
| 18378-20-6 |
|
Ethylene glycol monoethyl ether
| 110-80-5 |
|
4',5'-Dibromofluorescein
| 596-03-2 |
|
Ethylene Glycol Monoethyl Ether Acetate
| 111-15-9 |
|
1-[(3-Nitrobenzyloxy)methyl] pyridinium chloride, 99% (titr.)
| 3009-13-0 |
|
|